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Atom transfer radical polymerization initiated from a surface of various substrates (SI-ATRP) has become a progressively popular technique for obtaining thin polymer films with predetermined properties. The present work addresses the main features of SI-ATRP with respect to the controllability, rates of polymerization, suitable monomers, reaction mixture compositions etc. An alternative potential-driven polymerization approach is discussed, although to a smaller extent.

Produktbeschreibung
Atom transfer radical polymerization initiated from a surface of various substrates (SI-ATRP) has become a progressively popular technique for obtaining thin polymer films with predetermined properties. The present work addresses the main features of SI-ATRP with respect to the controllability, rates of polymerization, suitable monomers, reaction mixture compositions etc. An alternative potential-driven polymerization approach is discussed, although to a smaller extent.
Autorenporträt
Sergey Chernyy obtained his MSc degree in polymer chemistry from Saint Petersburg State University, Russia in 2009 and shortly thereafter started his PhD program in Aarhus University, Denmark (2009-2012). S. Chernyy is currently working as a Postdoc at Technical University of Denmark.