C F H Allen
Six Membered Heterocyclic Nitrogen Compounds with Three Condensed Rings, Volume 12
C F H Allen
Six Membered Heterocyclic Nitrogen Compounds with Three Condensed Rings, Volume 12
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The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects - properties, synthesis, reactions, physiological and industrial significance - of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors…mehr
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The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects - properties, synthesis, reactions, physiological and industrial significance - of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.
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Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Produktdetails
- Produktdetails
- Verlag: Wiley
- Volume 12 edition
- Seitenzahl: 648
- Erscheinungstermin: 15. Januar 1958
- Englisch
- Abmessung: 235mm x 157mm x 42mm
- Gewicht: 1190g
- ISBN-13: 9780470378519
- ISBN-10: 0470378514
- Artikelnr.: 23539737
- Verlag: Wiley
- Volume 12 edition
- Seitenzahl: 648
- Erscheinungstermin: 15. Januar 1958
- Englisch
- Abmessung: 235mm x 157mm x 42mm
- Gewicht: 1190g
- ISBN-13: 9780470378519
- ISBN-10: 0470378514
- Artikelnr.: 23539737
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Preface vii
Introduction 1
By C. V. Wilson
Mechanism of Ring Closure 7
By G. A. Reynolds
I. Azaanthracenes 14
By C. V. Wilson
1. Monoazaanthracenes 14
A. 1-Azaanthracene 14
B. 2-Azaanthracene 55
2. Diazaanthracenes 72
A. 1,2-Diazaanthracene 73
B. 1,3-Diazaanthracene 74
C. 1,4-Diazaanthracene 79
D. 1,5-Diazaanthracene 81
E. 1,8-Diazaanthracene 85
F. 1,9-Diazaanthracene 91
G. 1,10-Diazaanthracene 98
H. 2,3-Diazaanthracene 101
I. 2,6-Diazaanthracene 103
J. 2,9-Diazaanthracene 103
K. 2,10-Diazaanthracene 104
3. Triazaanthracenes 118
Nomenclature 118
A. 1,2,3-Triazaanthracene 118
B. 1,2,4-Triazaanthracene 119
C. 1,3,9-Triazaanthracene 119
D. 1,8,9-Triazaanthracene 122
E. 1,9,10-Triazaanthracene 123
F. 2,3,9-Triazaanthracene 124
G. 2,9,10-Triazaanthracene 125
4. Tetrazaanthracenes 130
Nomenclature 130
A. 1,2,7,8-Tetrazaanthracene 130
B. 1,3,5,7-Tetrazaanthracene 131
C. 1,3,6,8-Tetrazaanthracene 133
D. 1,4,5,8-Tetrazaanthracene 135
E. 1,4,9,10-Tetrazaanthracene 136
F. 2,3,6,7-Tetrazaanthracene 139
G. 2,7,9,10-Tetrazaanthracenc 141
5. Pentazaanthracenes 147
A. 1,3,8,9,10-Pentazaanthracene 147
6. Hexazaanthracenes 151
A. 1,3,6,8 9,10-Hexazaanthracene 151
B. 1,3,5,7,9,10-Hexazaanthracene 157
C. 1,2,4,5,7,8-Hexazaanthracene 158
References 161
II. Azaphenanthrenes 165
By John R. Thirtle
1. Monoazaphenanthrenes 165
A. I-Azaphenanthrene 165
B. 2-Azaphenanthrene 206
C. 3-Azaphenanthrene 209
References 211
III. 4-Azaphenanthrenes 216
By J. A. Van Allan
A. Nomenclature 216
B. Synthesis of the 4-Azaphenanthrene System 217
C. Derivatives 237
D. Reactions of the Ring 243
E. Properties 254
F. Uses 255
References 266
IV. 5-Azaphenanthrenes 271
By J. A. Van Allan
A. Nomenclature 271
B. Methods of Synthesis 272
C. Phenanthridinium Salts 287
D. Aminoalkylphenanthridines 292
E. Plant Alkaloids of the Phenanthridine Group 294
F. Reactions of Phenanthridine Derivatives 297
G. Oxidation 301
H. Direct Substitution 302
I. Properties 303
J. Tables 305
References 316
V. Diazaphenanthrenes (except Phenanthrolines) 320
By John R.Thirtle
A. 1,2-Diazaphenanthrene 320
B. 1,3-Diazaphenanthrene 322
C. 1,4-Diazaphenanthrene 328
D. 1,6-Diazaphenanthrene 356
E. 1,8-Diazaphenanthrene 358
F. 2,3-Diazaphenanthrene 359
G. 2,4-Diazaphenanthrene 360
H. 3,5-Diazaphcnanthrene 362
I. 3,6-Diazaphenanthrene 364
J. 3,8-Diazaphenanthrene 369
K. 4,5-Diazaphenanthrene 370
L. 5,6-Diazaphenanthrene 371
References 382
VI. 1,10-, 1,7-, and 4,7-Diazaphenanthrenes 386
By Bruce Graham
Introduction 386
A. 1,10-Diazaphenanthrene 387
B. 1,7-Diazaphenanthrene 409
C. 4,7-Diazaphenanthrene 435
References 454
VII. Other Polyazaphenanthrenes 457
By John R. Thirtle
A. 1,2,3-Triazaphenanthrene 457
B. 1,2,4-Triazaphenanthrene 458
C. 1,2,10-Triazaphenanthrene 464
D. 1,3,4-Triazaphenanthrene 465
E. 1,3,7-Triazaphenanthrene 470
F. 1,4,7-Triazaphenanthrene 472
G. 1,5,7-Triazaphenanthrene 474
H. 1,6,7-Triazaphenanthrene 474
I. 2,4,6-Triazaphenanthrene 475
J. 2,5,6-Triazaphenanthrene 476
K. 4,5,7-Triazaphenanthrene 477
L. 1,2,3,4-Tetrazaphenanthrene 478
M. 1,4,7,10-Tetrazaphenanthrene 479
N. 2,3,4,6-Tetrazaphenanthrene 480
O. 2,3,5,6-Tetrazaphenanthrene 481
P. 1,3,5,6,8,10-Hexazaphenanthrene 482
References 482
VIII. Azabenzonaphthenes 484
By James H. Richmond
1. Historical 484
2. Nomenclature 485
3. Monoazabenzonaphthenes 485
4. Polyazabenzonaphthenes 517
References 546
IX. The Ultraviolet Absorption Spectra of Polycyclic Heterocyclic Aromatic
Compounds 551
By G. M. Badger
1. Aromatic Hydrocarbons and Azahydrocarbons 551
2. The Color of Aromatic Azahydrocarbons 558
3. Absorption Spectra of Diazines and Related Compounds 559
4. The Effect of Substituents 561
References 566
Naphthalimides: Addendum 567
By C. F. H. Allen
Index 571
Introduction 1
By C. V. Wilson
Mechanism of Ring Closure 7
By G. A. Reynolds
I. Azaanthracenes 14
By C. V. Wilson
1. Monoazaanthracenes 14
A. 1-Azaanthracene 14
B. 2-Azaanthracene 55
2. Diazaanthracenes 72
A. 1,2-Diazaanthracene 73
B. 1,3-Diazaanthracene 74
C. 1,4-Diazaanthracene 79
D. 1,5-Diazaanthracene 81
E. 1,8-Diazaanthracene 85
F. 1,9-Diazaanthracene 91
G. 1,10-Diazaanthracene 98
H. 2,3-Diazaanthracene 101
I. 2,6-Diazaanthracene 103
J. 2,9-Diazaanthracene 103
K. 2,10-Diazaanthracene 104
3. Triazaanthracenes 118
Nomenclature 118
A. 1,2,3-Triazaanthracene 118
B. 1,2,4-Triazaanthracene 119
C. 1,3,9-Triazaanthracene 119
D. 1,8,9-Triazaanthracene 122
E. 1,9,10-Triazaanthracene 123
F. 2,3,9-Triazaanthracene 124
G. 2,9,10-Triazaanthracene 125
4. Tetrazaanthracenes 130
Nomenclature 130
A. 1,2,7,8-Tetrazaanthracene 130
B. 1,3,5,7-Tetrazaanthracene 131
C. 1,3,6,8-Tetrazaanthracene 133
D. 1,4,5,8-Tetrazaanthracene 135
E. 1,4,9,10-Tetrazaanthracene 136
F. 2,3,6,7-Tetrazaanthracene 139
G. 2,7,9,10-Tetrazaanthracenc 141
5. Pentazaanthracenes 147
A. 1,3,8,9,10-Pentazaanthracene 147
6. Hexazaanthracenes 151
A. 1,3,6,8 9,10-Hexazaanthracene 151
B. 1,3,5,7,9,10-Hexazaanthracene 157
C. 1,2,4,5,7,8-Hexazaanthracene 158
References 161
II. Azaphenanthrenes 165
By John R. Thirtle
1. Monoazaphenanthrenes 165
A. I-Azaphenanthrene 165
B. 2-Azaphenanthrene 206
C. 3-Azaphenanthrene 209
References 211
III. 4-Azaphenanthrenes 216
By J. A. Van Allan
A. Nomenclature 216
B. Synthesis of the 4-Azaphenanthrene System 217
C. Derivatives 237
D. Reactions of the Ring 243
E. Properties 254
F. Uses 255
References 266
IV. 5-Azaphenanthrenes 271
By J. A. Van Allan
A. Nomenclature 271
B. Methods of Synthesis 272
C. Phenanthridinium Salts 287
D. Aminoalkylphenanthridines 292
E. Plant Alkaloids of the Phenanthridine Group 294
F. Reactions of Phenanthridine Derivatives 297
G. Oxidation 301
H. Direct Substitution 302
I. Properties 303
J. Tables 305
References 316
V. Diazaphenanthrenes (except Phenanthrolines) 320
By John R.Thirtle
A. 1,2-Diazaphenanthrene 320
B. 1,3-Diazaphenanthrene 322
C. 1,4-Diazaphenanthrene 328
D. 1,6-Diazaphenanthrene 356
E. 1,8-Diazaphenanthrene 358
F. 2,3-Diazaphenanthrene 359
G. 2,4-Diazaphenanthrene 360
H. 3,5-Diazaphcnanthrene 362
I. 3,6-Diazaphenanthrene 364
J. 3,8-Diazaphenanthrene 369
K. 4,5-Diazaphenanthrene 370
L. 5,6-Diazaphenanthrene 371
References 382
VI. 1,10-, 1,7-, and 4,7-Diazaphenanthrenes 386
By Bruce Graham
Introduction 386
A. 1,10-Diazaphenanthrene 387
B. 1,7-Diazaphenanthrene 409
C. 4,7-Diazaphenanthrene 435
References 454
VII. Other Polyazaphenanthrenes 457
By John R. Thirtle
A. 1,2,3-Triazaphenanthrene 457
B. 1,2,4-Triazaphenanthrene 458
C. 1,2,10-Triazaphenanthrene 464
D. 1,3,4-Triazaphenanthrene 465
E. 1,3,7-Triazaphenanthrene 470
F. 1,4,7-Triazaphenanthrene 472
G. 1,5,7-Triazaphenanthrene 474
H. 1,6,7-Triazaphenanthrene 474
I. 2,4,6-Triazaphenanthrene 475
J. 2,5,6-Triazaphenanthrene 476
K. 4,5,7-Triazaphenanthrene 477
L. 1,2,3,4-Tetrazaphenanthrene 478
M. 1,4,7,10-Tetrazaphenanthrene 479
N. 2,3,4,6-Tetrazaphenanthrene 480
O. 2,3,5,6-Tetrazaphenanthrene 481
P. 1,3,5,6,8,10-Hexazaphenanthrene 482
References 482
VIII. Azabenzonaphthenes 484
By James H. Richmond
1. Historical 484
2. Nomenclature 485
3. Monoazabenzonaphthenes 485
4. Polyazabenzonaphthenes 517
References 546
IX. The Ultraviolet Absorption Spectra of Polycyclic Heterocyclic Aromatic
Compounds 551
By G. M. Badger
1. Aromatic Hydrocarbons and Azahydrocarbons 551
2. The Color of Aromatic Azahydrocarbons 558
3. Absorption Spectra of Diazines and Related Compounds 559
4. The Effect of Substituents 561
References 566
Naphthalimides: Addendum 567
By C. F. H. Allen
Index 571
Preface vii
Introduction 1
By C. V. Wilson
Mechanism of Ring Closure 7
By G. A. Reynolds
I. Azaanthracenes 14
By C. V. Wilson
1. Monoazaanthracenes 14
A. 1-Azaanthracene 14
B. 2-Azaanthracene 55
2. Diazaanthracenes 72
A. 1,2-Diazaanthracene 73
B. 1,3-Diazaanthracene 74
C. 1,4-Diazaanthracene 79
D. 1,5-Diazaanthracene 81
E. 1,8-Diazaanthracene 85
F. 1,9-Diazaanthracene 91
G. 1,10-Diazaanthracene 98
H. 2,3-Diazaanthracene 101
I. 2,6-Diazaanthracene 103
J. 2,9-Diazaanthracene 103
K. 2,10-Diazaanthracene 104
3. Triazaanthracenes 118
Nomenclature 118
A. 1,2,3-Triazaanthracene 118
B. 1,2,4-Triazaanthracene 119
C. 1,3,9-Triazaanthracene 119
D. 1,8,9-Triazaanthracene 122
E. 1,9,10-Triazaanthracene 123
F. 2,3,9-Triazaanthracene 124
G. 2,9,10-Triazaanthracene 125
4. Tetrazaanthracenes 130
Nomenclature 130
A. 1,2,7,8-Tetrazaanthracene 130
B. 1,3,5,7-Tetrazaanthracene 131
C. 1,3,6,8-Tetrazaanthracene 133
D. 1,4,5,8-Tetrazaanthracene 135
E. 1,4,9,10-Tetrazaanthracene 136
F. 2,3,6,7-Tetrazaanthracene 139
G. 2,7,9,10-Tetrazaanthracenc 141
5. Pentazaanthracenes 147
A. 1,3,8,9,10-Pentazaanthracene 147
6. Hexazaanthracenes 151
A. 1,3,6,8 9,10-Hexazaanthracene 151
B. 1,3,5,7,9,10-Hexazaanthracene 157
C. 1,2,4,5,7,8-Hexazaanthracene 158
References 161
II. Azaphenanthrenes 165
By John R. Thirtle
1. Monoazaphenanthrenes 165
A. I-Azaphenanthrene 165
B. 2-Azaphenanthrene 206
C. 3-Azaphenanthrene 209
References 211
III. 4-Azaphenanthrenes 216
By J. A. Van Allan
A. Nomenclature 216
B. Synthesis of the 4-Azaphenanthrene System 217
C. Derivatives 237
D. Reactions of the Ring 243
E. Properties 254
F. Uses 255
References 266
IV. 5-Azaphenanthrenes 271
By J. A. Van Allan
A. Nomenclature 271
B. Methods of Synthesis 272
C. Phenanthridinium Salts 287
D. Aminoalkylphenanthridines 292
E. Plant Alkaloids of the Phenanthridine Group 294
F. Reactions of Phenanthridine Derivatives 297
G. Oxidation 301
H. Direct Substitution 302
I. Properties 303
J. Tables 305
References 316
V. Diazaphenanthrenes (except Phenanthrolines) 320
By John R.Thirtle
A. 1,2-Diazaphenanthrene 320
B. 1,3-Diazaphenanthrene 322
C. 1,4-Diazaphenanthrene 328
D. 1,6-Diazaphenanthrene 356
E. 1,8-Diazaphenanthrene 358
F. 2,3-Diazaphenanthrene 359
G. 2,4-Diazaphenanthrene 360
H. 3,5-Diazaphcnanthrene 362
I. 3,6-Diazaphenanthrene 364
J. 3,8-Diazaphenanthrene 369
K. 4,5-Diazaphenanthrene 370
L. 5,6-Diazaphenanthrene 371
References 382
VI. 1,10-, 1,7-, and 4,7-Diazaphenanthrenes 386
By Bruce Graham
Introduction 386
A. 1,10-Diazaphenanthrene 387
B. 1,7-Diazaphenanthrene 409
C. 4,7-Diazaphenanthrene 435
References 454
VII. Other Polyazaphenanthrenes 457
By John R. Thirtle
A. 1,2,3-Triazaphenanthrene 457
B. 1,2,4-Triazaphenanthrene 458
C. 1,2,10-Triazaphenanthrene 464
D. 1,3,4-Triazaphenanthrene 465
E. 1,3,7-Triazaphenanthrene 470
F. 1,4,7-Triazaphenanthrene 472
G. 1,5,7-Triazaphenanthrene 474
H. 1,6,7-Triazaphenanthrene 474
I. 2,4,6-Triazaphenanthrene 475
J. 2,5,6-Triazaphenanthrene 476
K. 4,5,7-Triazaphenanthrene 477
L. 1,2,3,4-Tetrazaphenanthrene 478
M. 1,4,7,10-Tetrazaphenanthrene 479
N. 2,3,4,6-Tetrazaphenanthrene 480
O. 2,3,5,6-Tetrazaphenanthrene 481
P. 1,3,5,6,8,10-Hexazaphenanthrene 482
References 482
VIII. Azabenzonaphthenes 484
By James H. Richmond
1. Historical 484
2. Nomenclature 485
3. Monoazabenzonaphthenes 485
4. Polyazabenzonaphthenes 517
References 546
IX. The Ultraviolet Absorption Spectra of Polycyclic Heterocyclic Aromatic
Compounds 551
By G. M. Badger
1. Aromatic Hydrocarbons and Azahydrocarbons 551
2. The Color of Aromatic Azahydrocarbons 558
3. Absorption Spectra of Diazines and Related Compounds 559
4. The Effect of Substituents 561
References 566
Naphthalimides: Addendum 567
By C. F. H. Allen
Index 571
Introduction 1
By C. V. Wilson
Mechanism of Ring Closure 7
By G. A. Reynolds
I. Azaanthracenes 14
By C. V. Wilson
1. Monoazaanthracenes 14
A. 1-Azaanthracene 14
B. 2-Azaanthracene 55
2. Diazaanthracenes 72
A. 1,2-Diazaanthracene 73
B. 1,3-Diazaanthracene 74
C. 1,4-Diazaanthracene 79
D. 1,5-Diazaanthracene 81
E. 1,8-Diazaanthracene 85
F. 1,9-Diazaanthracene 91
G. 1,10-Diazaanthracene 98
H. 2,3-Diazaanthracene 101
I. 2,6-Diazaanthracene 103
J. 2,9-Diazaanthracene 103
K. 2,10-Diazaanthracene 104
3. Triazaanthracenes 118
Nomenclature 118
A. 1,2,3-Triazaanthracene 118
B. 1,2,4-Triazaanthracene 119
C. 1,3,9-Triazaanthracene 119
D. 1,8,9-Triazaanthracene 122
E. 1,9,10-Triazaanthracene 123
F. 2,3,9-Triazaanthracene 124
G. 2,9,10-Triazaanthracene 125
4. Tetrazaanthracenes 130
Nomenclature 130
A. 1,2,7,8-Tetrazaanthracene 130
B. 1,3,5,7-Tetrazaanthracene 131
C. 1,3,6,8-Tetrazaanthracene 133
D. 1,4,5,8-Tetrazaanthracene 135
E. 1,4,9,10-Tetrazaanthracene 136
F. 2,3,6,7-Tetrazaanthracene 139
G. 2,7,9,10-Tetrazaanthracenc 141
5. Pentazaanthracenes 147
A. 1,3,8,9,10-Pentazaanthracene 147
6. Hexazaanthracenes 151
A. 1,3,6,8 9,10-Hexazaanthracene 151
B. 1,3,5,7,9,10-Hexazaanthracene 157
C. 1,2,4,5,7,8-Hexazaanthracene 158
References 161
II. Azaphenanthrenes 165
By John R. Thirtle
1. Monoazaphenanthrenes 165
A. I-Azaphenanthrene 165
B. 2-Azaphenanthrene 206
C. 3-Azaphenanthrene 209
References 211
III. 4-Azaphenanthrenes 216
By J. A. Van Allan
A. Nomenclature 216
B. Synthesis of the 4-Azaphenanthrene System 217
C. Derivatives 237
D. Reactions of the Ring 243
E. Properties 254
F. Uses 255
References 266
IV. 5-Azaphenanthrenes 271
By J. A. Van Allan
A. Nomenclature 271
B. Methods of Synthesis 272
C. Phenanthridinium Salts 287
D. Aminoalkylphenanthridines 292
E. Plant Alkaloids of the Phenanthridine Group 294
F. Reactions of Phenanthridine Derivatives 297
G. Oxidation 301
H. Direct Substitution 302
I. Properties 303
J. Tables 305
References 316
V. Diazaphenanthrenes (except Phenanthrolines) 320
By John R.Thirtle
A. 1,2-Diazaphenanthrene 320
B. 1,3-Diazaphenanthrene 322
C. 1,4-Diazaphenanthrene 328
D. 1,6-Diazaphenanthrene 356
E. 1,8-Diazaphenanthrene 358
F. 2,3-Diazaphenanthrene 359
G. 2,4-Diazaphenanthrene 360
H. 3,5-Diazaphcnanthrene 362
I. 3,6-Diazaphenanthrene 364
J. 3,8-Diazaphenanthrene 369
K. 4,5-Diazaphenanthrene 370
L. 5,6-Diazaphenanthrene 371
References 382
VI. 1,10-, 1,7-, and 4,7-Diazaphenanthrenes 386
By Bruce Graham
Introduction 386
A. 1,10-Diazaphenanthrene 387
B. 1,7-Diazaphenanthrene 409
C. 4,7-Diazaphenanthrene 435
References 454
VII. Other Polyazaphenanthrenes 457
By John R. Thirtle
A. 1,2,3-Triazaphenanthrene 457
B. 1,2,4-Triazaphenanthrene 458
C. 1,2,10-Triazaphenanthrene 464
D. 1,3,4-Triazaphenanthrene 465
E. 1,3,7-Triazaphenanthrene 470
F. 1,4,7-Triazaphenanthrene 472
G. 1,5,7-Triazaphenanthrene 474
H. 1,6,7-Triazaphenanthrene 474
I. 2,4,6-Triazaphenanthrene 475
J. 2,5,6-Triazaphenanthrene 476
K. 4,5,7-Triazaphenanthrene 477
L. 1,2,3,4-Tetrazaphenanthrene 478
M. 1,4,7,10-Tetrazaphenanthrene 479
N. 2,3,4,6-Tetrazaphenanthrene 480
O. 2,3,5,6-Tetrazaphenanthrene 481
P. 1,3,5,6,8,10-Hexazaphenanthrene 482
References 482
VIII. Azabenzonaphthenes 484
By James H. Richmond
1. Historical 484
2. Nomenclature 485
3. Monoazabenzonaphthenes 485
4. Polyazabenzonaphthenes 517
References 546
IX. The Ultraviolet Absorption Spectra of Polycyclic Heterocyclic Aromatic
Compounds 551
By G. M. Badger
1. Aromatic Hydrocarbons and Azahydrocarbons 551
2. The Color of Aromatic Azahydrocarbons 558
3. Absorption Spectra of Diazines and Related Compounds 559
4. The Effect of Substituents 561
References 566
Naphthalimides: Addendum 567
By C. F. H. Allen
Index 571