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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Sodium thiosulfate (Na2S2O3), also spelled sodium thiosulphate, is a colorless crystalline compound that is more familiar as the pentahydrate, Na2S2O3 5H2O, an efflorescent, monoclinic crystalline substance also called sodium hyposulfite or hypo. The thiosulfate anion is tetrahedral in shape and is notionally derived by replacing one of the oxygen atoms by a sulfur atom in a sulfate anion. The S-S distance indicates a single bond, implying that the sulfur bears significant negative charge and the S-O interactions have more double bond character. The first protonation of thiosulfate occurs at sulfur.