Solubilization in Surfactant Aggregates

Herausgeber: Christian, Sherril D.; Scamehorn, John F.

• Gebundenes Buch

Produktbeschreibung

This work covers topics ranging from fundamental studies of solubilization to practical technological applications of the phenomenon. It reviews the solubilization of organic materials into surfactant aggregates, including micelles, vesicles and admicelles. The book also details methods of measuring solubilization that utilize both classical and newer instrumental techniques. It is intended for physical, surface, colloid and surfactant chemists; chemical, environmental and civil engineers; and upper-level undergraduate and graduate students in these disciplines.

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Produktdetails

• Verlag: CRC Press
• Seitenzahl: 564
• Erscheinungstermin: 10. April 1995
• Englisch
• Abmessung: 235mm x 157mm x 35mm
• Gewicht: 957g
• ISBN-13: 9780824790998
• ISBN-10: 0824790995
• Artikelnr.: 21620930

Autorenporträt

Sherril D. Christian, John F. Scamehorn

Inhaltsangabe

Part 1 Overview: overview and history of the study of solubilization. Part
2 Solubilization in micelles: solubilization of gases; thermodynamics of
solubilization of polar additives in micellar solutions; solubilization of
uncharged molecules in ionic micellar solutions - toward an understanding
at the molecular level; solubilization in mixed micelles; solubilization in
amphiphilic copolymer solutions; kinetics of solubilization in
surfactant-based systems. Part 3 Solubilization in nonmicellar surfactant
aggregates: adsolubilization; solubilization in micelles and vesicles
studied by fluorescence techniques, interplay between the microproperties
of the aggregates and the locus and extent of solubilization;
solubilization of organic compounds by vesicles. Part 4 Methods of
measuring solubilization: solubilization, as studied by nuclear spin
relaxation and NMR-based self-diffusion techniques; the partitioning of
neutral solutes between micelles and water as deduced from critical micelle
concentration determinations; vapor pressure studies of solubilization;
comparison of experimental methods for the determination of the partition
coefficients of n-alcohols in SDS and DTAB micelles. Part 5 Applications of
solubilization: solubilization and detergency; solubilization in micellar
separations.