Specific Ion Interaction Theory
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High Quality Content by WIKIPEDIA articles! Specific ion Interaction Theory (SIT theory) is a theory used to estimate single-ion activity coefficients in electrolyte solutions at relatively high concentrations.It does so by taking into consideration interaction coefficients between the various ions present in solution. Interaction coefficients are determined from equilibrium constant values obtained with solutions at various ionic strengths. The determination of SIT interaction coefficients also yields the value of the equilibrium constant at infinite dilution.The need for this theory arises f...
High Quality Content by WIKIPEDIA articles! Specific ion Interaction Theory (SIT theory) is a theory used to estimate single-ion activity coefficients in electrolyte solutions at relatively high concentrations.It does so by taking into consideration interaction coefficients between the various ions present in solution. Interaction coefficients are determined from equilibrium constant values obtained with solutions at various ionic strengths. The determination of SIT interaction coefficients also yields the value of the equilibrium constant at infinite dilution.The need for this theory arises from the need to derive activity coefficients of solutes when their concentrations are too high to be predicted accurately by the Debye-Huckel theory. These activity coefficients are needed because an equilibrium constant is defined in thermodynamics as a quotient of activities but is usually measured using concentrations.
