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In the present work, we have studied the spectroscopic properties for three newly synthesised pyridazin-3(2H)-one derivatives, using solvatochromic approaches. We have estimated the ground state dipole moments, experimentally using Guggenheim method and theoretically using the Gaussian-09 program. Excited state dipole moment was estimated using solvatochromic shift method. It is found that excited state dipole moments are larger than ground state dipole moments in all the three molecules. This may be due to the fact that, the excited states for all the three molecules are more polar than the…mehr

Produktbeschreibung
In the present work, we have studied the spectroscopic properties for three newly synthesised pyridazin-3(2H)-one derivatives, using solvatochromic approaches. We have estimated the ground state dipole moments, experimentally using Guggenheim method and theoretically using the Gaussian-09 program. Excited state dipole moment was estimated using solvatochromic shift method. It is found that excited state dipole moments are larger than ground state dipole moments in all the three molecules. This may be due to the fact that, the excited states for all the three molecules are more polar than the ground states.Furthermore, we have analysed the microscopic solvent polarity parameter and effect from empirical measurements of acidity (SA), basicity (SB), polarizability (SP) and dipolarity (SdP). In addition, we have estimated the fluorescence quantum yield for above said molecules using tryptophan as a standard reference in different solvents.
Autorenporträt
Prof J. S. Kadadevarmath has research and teaching experince of over 30 years. He did his PhD from Karnatak University, Dharwad. His area of reserach includes energy transfer studies in organic liquid scintillators, Dye sensitised solar cells and spectroscopic investigations in some organic molecules. There are about 50 research articles published.