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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In molecular geometry, square based pyramidal geometry describes the shape of certain compounds with the formula ML5 where L is a ligand. If the ligand atoms were connected, the resulting shape would be that of a pyramid with a square base. The geometry is common for certain main group compounds that have a stereochemically active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN)5]3 .