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Chemically tuned emission properties of luminescent
materials are important in sensing technology, such
as coatings on spectroscopic detectors. Copper(I),
Silver(I) and Gold(I) halide complexes are well known
as candidates for luminescence properties that are
dependent upon choice of ligand and more recently the
symmetry of the complex about the metal centers. This
book establishes and illustrates the systematic
energy changes in fluorescent properties of these
complexes with symmetry within a class of halide
ligands. Quantum mechanical calculations indicate the
energy and source of these luminescent properties as
well as the quenching phenomenon found in some higher
symmetry species.
materials are important in sensing technology, such
as coatings on spectroscopic detectors. Copper(I),
Silver(I) and Gold(I) halide complexes are well known
as candidates for luminescence properties that are
dependent upon choice of ligand and more recently the
symmetry of the complex about the metal centers. This
book establishes and illustrates the systematic
energy changes in fluorescent properties of these
complexes with symmetry within a class of halide
ligands. Quantum mechanical calculations indicate the
energy and source of these luminescent properties as
well as the quenching phenomenon found in some higher
symmetry species.