The electrochemical reactions began to attract much attention among synthetic chemists due to their high energy efficiency and cleanliness with its wide applications spread into all fields of organic chemistry. Strong emphasis on the elucidation of product compositions being replaced to some extent by greater investment in designing more acceptable electrolysis systems and optimizing the electrolysis conditions to obtain high yields of the desired products. In this sense, electroorganic synthesis in the 1970 s was able to emerge from its infancy and be more fully assimilated into routine synthetic organic chemistry.The electrochemical behavior of a series of triphenyl amine-containing organic compounds with varied oxidation potentials are designated as starting materials of the aromatic polyamides, which are thermally stable polymers. These are having applications in organic electroluminescent elements.