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This research was developed in four phases, the first phase is that the concerning gasoline and how to enhance its performance with respect to the environmental considerations concerning the air pollution issue due to the gasoline exhaust and the regulations that have been set up for limitation of toxic materials. The second phase is that the project will discuss the effect of composition study the effect of compositions (PIONA) on the octane numbers of environmental gasolines of reformate, isomerate, and hydrocracked naphtha blends by using gas chromatography analyses, six blends will be studied to produce environmental gasoline according to the European standards of Euro 3, 4, 5, and 6.