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Of central importance in personal care, food, pharmaceutics, and biotechnology, biomaterials and biosubstrates formed the subject of the fifth meeting of the Royal Society-Unilever Indo-uk Forum in Materials Science and Engineering. The programme for this meeting dwelt on two principal foci: (i) new advances in the measurement of the supramolecular and colloidal structures, and (ii) the relationship of these structures to the functional properties of the materials.