Surfactants from Renewable Resources
Herausgeber: Kjellin, Mikael; Johansson, Ingegärd
Surfactants from Renewable Resources
Herausgeber: Kjellin, Mikael; Johansson, Ingegärd
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Surfacants from Renewable Resources is a comprehensive text that meets scientists' demand for information on new biodegradable surfacants with safer properties for modern industrial formulations. This edited volume explores the current status of the research and applications of "green" surfactant chemistry. It provides an overview to the desired properties in different fields and focuses on bio-based products that have the potential to improve sustainability of natural resources and environmental quality. Aimed primarily at industrial researchers in companies producing surfacants, this book presents the arguments for green and sustainable materials.…mehr
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Surfacants from Renewable Resources is a comprehensive text that meets scientists' demand for information on new biodegradable surfacants with safer properties for modern industrial formulations. This edited volume explores the current status of the research and applications of "green" surfactant chemistry. It provides an overview to the desired properties in different fields and focuses on bio-based products that have the potential to improve sustainability of natural resources and environmental quality. Aimed primarily at industrial researchers in companies producing surfacants, this book presents the arguments for green and sustainable materials.
Produktdetails
- Produktdetails
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 352
- Erscheinungstermin: 29. März 2010
- Englisch
- Abmessung: 254mm x 177mm x 25mm
- Gewicht: 708g
- ISBN-13: 9780470760413
- ISBN-10: 0470760419
- Artikelnr.: 28162405
- Verlag: John Wiley & Sons / Wiley
- Seitenzahl: 352
- Erscheinungstermin: 29. März 2010
- Englisch
- Abmessung: 254mm x 177mm x 25mm
- Gewicht: 708g
- ISBN-13: 9780470760413
- ISBN-10: 0470760419
- Artikelnr.: 28162405
Dr Mikael Kjellin is based at the Institute for Surface Chemistry, Stockholm, Sweden, which works with many industrial branches including pharmaceuticals, personal care products, biotech, food, industrial chemicals, household products, engineering and materials industries, pulp and paper, coatings, adhesives, paints, and printing. In addition, Dr Kjellin is the coordinator of the research centre SNAP, which aims to build from an industrial need, long-term knowledge and experience relating to new environmentally safe surfactants derived entirely or partly from natural products. Ingegard.Johansson is a research scientists based at Akzo Nobel Surfactants Europe in Sweden.
Series Preface Preface Acknowledgements List of Contributors Part 1:
Renewable Hydrophobes 1. Surfactants based on natural fatty acids, Martin
Svensson 1.1 Introduction and History 1.2 Fats and Oils as Raw Materials
1.3 Fatty Acid Soaps 1.4 Polyethyleneglycol Fatty Acid Esters 1.5
Polyglycerol fatty acid esters 1.6 Conclusions References 2. Nitrogen
Derivatives of Natural Fats and Oils Ralph Franklin 2.1 Introduction 2.2
Manufacture of Fatty Nitrogen Derivatives 2.3 Production Data 2.4
Ecological Aspects 2.5 Biodegradation 2.6 Properties of Nitrogen-based
Surfactants 2.7 Applications 2.8 Conclusions References 3. Surface-Active
Compounds as Forest-Industry By-Products Bjarne Holmbom, Anna Sundberg and
Anders Strand 3.1 Introduction 3.2 Resin and Fatty Acids 3.3 Sterols and
Sterol Ethoxylates 3.4 Hemicelluloses Acknowledgement References Part 2:
Renewable Hydrophiles 4. Surfactants based on Carbohydrates and Proteins
for Consumer Products and Technical Applications Karlheinz Hill 4.1
Introduction 4.2 Raw materials 4.3 Products and Applications 4.4 Conclusion
5. Amino acids, lactic acid and ascorbic acid as raw materials for
biocompatible surfactants Carmen Moran, Lourdes Perez, Ramon Pons, Aurora
Pinazo and Mª Rosa Infante 5.1 Introduction 5.2 Production of raw materials
5.3 Lysine based surfactants 5.4 Lactic acid based surfactants 5.5 Ascorbic
acid based surfactants References Part 3: New ways of making renewable
building blocks 6. Synthesis of ethylene, propylene from ethanol or
methanol Anna Lundgren and Thomas Hjertberg 6.1 Introduction 6.2 Why
Produce Ethylene from Renewable Resources? 6.3 Production of Ethylene from
Renewable Feed Stock 6.4 Commercialization of Bioethylene 6.5 Environmental
Impact of Bioethylene 6.6 Certificate of Green Carbon Content 6.7
Concluding Remarks References 7. Fermentation based building blocks for
renewable resource based surfactants KrisArvid Berglund, Ulrika Rova, David
B. Hodge 7.1 Introduction 7.2 Existing and Potential Classes of Surfactants
from Biologically-Derived Metabolites 7.3 Fermentation-Based Building
Blocks with Large Existing Markets 7.4 New Fermentation-Based Building
Blocks Conclusion References Part 4: Biosurfactants 8. Enzymatic synthesis
of biosurfactants, Patrick Adlercreutzand Rajni Hatti-Kaul 8.1 Introduction
8.2 Enzymes as catalysts for synthesis of surfactants 8.3 Enzymatic
synthesis of polar lipids useful as surfactants 8.4 Carbohydrate esters 8.5
Fatty amide surfactants 8.6 Amino acid-based surfactants 8.7 Alkyl
glycosides 8.8 Future prospects Acknowledgement References 9. Surfactants
from waste biomass Flor Yunuen Garcia-Becerra, David Grant Allen, and Edgar
Joel Acosta 9.1 Introduction 9.2 Surfactants obtained from biological
transformation of waste biomass 9.3 Surfactants obtained from chemical
transformation of waste biomass 9.4 Summary and outlook 9.5 References 10.
Lecithin and Phospholipids Willem van Nieuwenhuyzen 10.1 Introduction 10.2
Sources and production 10.3 Composition 10.4 Quality and analysis of
lecithins 10.5 Modification 10.6 Emulsifying properties 10.7 Applications
10.8 Legislation and reach 10.9 Conclusion References 11. Sophorolipid and
rhamnolipid synthesis and their application in cleaning products Dirk
Develter and Steve Fleurackers 11.1 Sophorolipids 11.2 Derivatives of
native sophorolipids 11.3 Biosynthesis of novel sophorolipids 11.4
Rhamnolipids 11.5 Cleaning applications using sophorolipids and
rhamnolipids References 12. Saponin based surfactants Wieslaw Oleszek and
Arafa Hamed 12.1 Introduction 12.2 Molecular properties 12.3 Sources of
saponins 12.4 Saponins as emulsifiers and surfactants 12.5 Application of
saponins as surfactants and emulsifiers References Part 5: Polymeric
surfactants/Surface active polymers 13. Surface active polymers from
cellulose Leif Karlson 13.1 Introduction 13.2 Structure and synthesis of
cellulose ether 13.3 Cellulose ethers in aqueous solution 13.4 Interaction
with surfactants 13.5 Clouding References 14. New developments in the
commercial utilisation of lignosulfonates Rolf Andreas Lauten, Bernt O.
Myrvold and Stig Are Gundersen 14.1 Introduction 14.2 Lignosulfonates 14.3
Lignosulfonate production 14.4 Environmental issues 14.5 Lignosulfonates as
stabilisers for emulsions and suspoemulsions 14.6 Superplasticizers for
concrete 14.7 Summary Acknowledgements References 15. Dispersion
stabilizers based on inulin Tharwat F. Tadrosand Bart Levecke 15.1
Introduction 15.2 Solution Properties of long-chain inulin and
hydrophobically modified inulin (HMI) 15.3 Interfacial Aspects of HMI at
Various Interfaces 15.4 Emulsions Stabilized Using HMI 15.5 Emulsion
Polymerization Using Hydrophobically Modified Inulin (HMI) 15.6 Use of HMI
for Preparation and Stabilisation of Nano-Emulsions References
Renewable Hydrophobes 1. Surfactants based on natural fatty acids, Martin
Svensson 1.1 Introduction and History 1.2 Fats and Oils as Raw Materials
1.3 Fatty Acid Soaps 1.4 Polyethyleneglycol Fatty Acid Esters 1.5
Polyglycerol fatty acid esters 1.6 Conclusions References 2. Nitrogen
Derivatives of Natural Fats and Oils Ralph Franklin 2.1 Introduction 2.2
Manufacture of Fatty Nitrogen Derivatives 2.3 Production Data 2.4
Ecological Aspects 2.5 Biodegradation 2.6 Properties of Nitrogen-based
Surfactants 2.7 Applications 2.8 Conclusions References 3. Surface-Active
Compounds as Forest-Industry By-Products Bjarne Holmbom, Anna Sundberg and
Anders Strand 3.1 Introduction 3.2 Resin and Fatty Acids 3.3 Sterols and
Sterol Ethoxylates 3.4 Hemicelluloses Acknowledgement References Part 2:
Renewable Hydrophiles 4. Surfactants based on Carbohydrates and Proteins
for Consumer Products and Technical Applications Karlheinz Hill 4.1
Introduction 4.2 Raw materials 4.3 Products and Applications 4.4 Conclusion
5. Amino acids, lactic acid and ascorbic acid as raw materials for
biocompatible surfactants Carmen Moran, Lourdes Perez, Ramon Pons, Aurora
Pinazo and Mª Rosa Infante 5.1 Introduction 5.2 Production of raw materials
5.3 Lysine based surfactants 5.4 Lactic acid based surfactants 5.5 Ascorbic
acid based surfactants References Part 3: New ways of making renewable
building blocks 6. Synthesis of ethylene, propylene from ethanol or
methanol Anna Lundgren and Thomas Hjertberg 6.1 Introduction 6.2 Why
Produce Ethylene from Renewable Resources? 6.3 Production of Ethylene from
Renewable Feed Stock 6.4 Commercialization of Bioethylene 6.5 Environmental
Impact of Bioethylene 6.6 Certificate of Green Carbon Content 6.7
Concluding Remarks References 7. Fermentation based building blocks for
renewable resource based surfactants KrisArvid Berglund, Ulrika Rova, David
B. Hodge 7.1 Introduction 7.2 Existing and Potential Classes of Surfactants
from Biologically-Derived Metabolites 7.3 Fermentation-Based Building
Blocks with Large Existing Markets 7.4 New Fermentation-Based Building
Blocks Conclusion References Part 4: Biosurfactants 8. Enzymatic synthesis
of biosurfactants, Patrick Adlercreutzand Rajni Hatti-Kaul 8.1 Introduction
8.2 Enzymes as catalysts for synthesis of surfactants 8.3 Enzymatic
synthesis of polar lipids useful as surfactants 8.4 Carbohydrate esters 8.5
Fatty amide surfactants 8.6 Amino acid-based surfactants 8.7 Alkyl
glycosides 8.8 Future prospects Acknowledgement References 9. Surfactants
from waste biomass Flor Yunuen Garcia-Becerra, David Grant Allen, and Edgar
Joel Acosta 9.1 Introduction 9.2 Surfactants obtained from biological
transformation of waste biomass 9.3 Surfactants obtained from chemical
transformation of waste biomass 9.4 Summary and outlook 9.5 References 10.
Lecithin and Phospholipids Willem van Nieuwenhuyzen 10.1 Introduction 10.2
Sources and production 10.3 Composition 10.4 Quality and analysis of
lecithins 10.5 Modification 10.6 Emulsifying properties 10.7 Applications
10.8 Legislation and reach 10.9 Conclusion References 11. Sophorolipid and
rhamnolipid synthesis and their application in cleaning products Dirk
Develter and Steve Fleurackers 11.1 Sophorolipids 11.2 Derivatives of
native sophorolipids 11.3 Biosynthesis of novel sophorolipids 11.4
Rhamnolipids 11.5 Cleaning applications using sophorolipids and
rhamnolipids References 12. Saponin based surfactants Wieslaw Oleszek and
Arafa Hamed 12.1 Introduction 12.2 Molecular properties 12.3 Sources of
saponins 12.4 Saponins as emulsifiers and surfactants 12.5 Application of
saponins as surfactants and emulsifiers References Part 5: Polymeric
surfactants/Surface active polymers 13. Surface active polymers from
cellulose Leif Karlson 13.1 Introduction 13.2 Structure and synthesis of
cellulose ether 13.3 Cellulose ethers in aqueous solution 13.4 Interaction
with surfactants 13.5 Clouding References 14. New developments in the
commercial utilisation of lignosulfonates Rolf Andreas Lauten, Bernt O.
Myrvold and Stig Are Gundersen 14.1 Introduction 14.2 Lignosulfonates 14.3
Lignosulfonate production 14.4 Environmental issues 14.5 Lignosulfonates as
stabilisers for emulsions and suspoemulsions 14.6 Superplasticizers for
concrete 14.7 Summary Acknowledgements References 15. Dispersion
stabilizers based on inulin Tharwat F. Tadrosand Bart Levecke 15.1
Introduction 15.2 Solution Properties of long-chain inulin and
hydrophobically modified inulin (HMI) 15.3 Interfacial Aspects of HMI at
Various Interfaces 15.4 Emulsions Stabilized Using HMI 15.5 Emulsion
Polymerization Using Hydrophobically Modified Inulin (HMI) 15.6 Use of HMI
for Preparation and Stabilisation of Nano-Emulsions References
Series Preface Preface Acknowledgements List of Contributors Part 1:
Renewable Hydrophobes 1. Surfactants based on natural fatty acids, Martin
Svensson 1.1 Introduction and History 1.2 Fats and Oils as Raw Materials
1.3 Fatty Acid Soaps 1.4 Polyethyleneglycol Fatty Acid Esters 1.5
Polyglycerol fatty acid esters 1.6 Conclusions References 2. Nitrogen
Derivatives of Natural Fats and Oils Ralph Franklin 2.1 Introduction 2.2
Manufacture of Fatty Nitrogen Derivatives 2.3 Production Data 2.4
Ecological Aspects 2.5 Biodegradation 2.6 Properties of Nitrogen-based
Surfactants 2.7 Applications 2.8 Conclusions References 3. Surface-Active
Compounds as Forest-Industry By-Products Bjarne Holmbom, Anna Sundberg and
Anders Strand 3.1 Introduction 3.2 Resin and Fatty Acids 3.3 Sterols and
Sterol Ethoxylates 3.4 Hemicelluloses Acknowledgement References Part 2:
Renewable Hydrophiles 4. Surfactants based on Carbohydrates and Proteins
for Consumer Products and Technical Applications Karlheinz Hill 4.1
Introduction 4.2 Raw materials 4.3 Products and Applications 4.4 Conclusion
5. Amino acids, lactic acid and ascorbic acid as raw materials for
biocompatible surfactants Carmen Moran, Lourdes Perez, Ramon Pons, Aurora
Pinazo and Mª Rosa Infante 5.1 Introduction 5.2 Production of raw materials
5.3 Lysine based surfactants 5.4 Lactic acid based surfactants 5.5 Ascorbic
acid based surfactants References Part 3: New ways of making renewable
building blocks 6. Synthesis of ethylene, propylene from ethanol or
methanol Anna Lundgren and Thomas Hjertberg 6.1 Introduction 6.2 Why
Produce Ethylene from Renewable Resources? 6.3 Production of Ethylene from
Renewable Feed Stock 6.4 Commercialization of Bioethylene 6.5 Environmental
Impact of Bioethylene 6.6 Certificate of Green Carbon Content 6.7
Concluding Remarks References 7. Fermentation based building blocks for
renewable resource based surfactants KrisArvid Berglund, Ulrika Rova, David
B. Hodge 7.1 Introduction 7.2 Existing and Potential Classes of Surfactants
from Biologically-Derived Metabolites 7.3 Fermentation-Based Building
Blocks with Large Existing Markets 7.4 New Fermentation-Based Building
Blocks Conclusion References Part 4: Biosurfactants 8. Enzymatic synthesis
of biosurfactants, Patrick Adlercreutzand Rajni Hatti-Kaul 8.1 Introduction
8.2 Enzymes as catalysts for synthesis of surfactants 8.3 Enzymatic
synthesis of polar lipids useful as surfactants 8.4 Carbohydrate esters 8.5
Fatty amide surfactants 8.6 Amino acid-based surfactants 8.7 Alkyl
glycosides 8.8 Future prospects Acknowledgement References 9. Surfactants
from waste biomass Flor Yunuen Garcia-Becerra, David Grant Allen, and Edgar
Joel Acosta 9.1 Introduction 9.2 Surfactants obtained from biological
transformation of waste biomass 9.3 Surfactants obtained from chemical
transformation of waste biomass 9.4 Summary and outlook 9.5 References 10.
Lecithin and Phospholipids Willem van Nieuwenhuyzen 10.1 Introduction 10.2
Sources and production 10.3 Composition 10.4 Quality and analysis of
lecithins 10.5 Modification 10.6 Emulsifying properties 10.7 Applications
10.8 Legislation and reach 10.9 Conclusion References 11. Sophorolipid and
rhamnolipid synthesis and their application in cleaning products Dirk
Develter and Steve Fleurackers 11.1 Sophorolipids 11.2 Derivatives of
native sophorolipids 11.3 Biosynthesis of novel sophorolipids 11.4
Rhamnolipids 11.5 Cleaning applications using sophorolipids and
rhamnolipids References 12. Saponin based surfactants Wieslaw Oleszek and
Arafa Hamed 12.1 Introduction 12.2 Molecular properties 12.3 Sources of
saponins 12.4 Saponins as emulsifiers and surfactants 12.5 Application of
saponins as surfactants and emulsifiers References Part 5: Polymeric
surfactants/Surface active polymers 13. Surface active polymers from
cellulose Leif Karlson 13.1 Introduction 13.2 Structure and synthesis of
cellulose ether 13.3 Cellulose ethers in aqueous solution 13.4 Interaction
with surfactants 13.5 Clouding References 14. New developments in the
commercial utilisation of lignosulfonates Rolf Andreas Lauten, Bernt O.
Myrvold and Stig Are Gundersen 14.1 Introduction 14.2 Lignosulfonates 14.3
Lignosulfonate production 14.4 Environmental issues 14.5 Lignosulfonates as
stabilisers for emulsions and suspoemulsions 14.6 Superplasticizers for
concrete 14.7 Summary Acknowledgements References 15. Dispersion
stabilizers based on inulin Tharwat F. Tadrosand Bart Levecke 15.1
Introduction 15.2 Solution Properties of long-chain inulin and
hydrophobically modified inulin (HMI) 15.3 Interfacial Aspects of HMI at
Various Interfaces 15.4 Emulsions Stabilized Using HMI 15.5 Emulsion
Polymerization Using Hydrophobically Modified Inulin (HMI) 15.6 Use of HMI
for Preparation and Stabilisation of Nano-Emulsions References
Renewable Hydrophobes 1. Surfactants based on natural fatty acids, Martin
Svensson 1.1 Introduction and History 1.2 Fats and Oils as Raw Materials
1.3 Fatty Acid Soaps 1.4 Polyethyleneglycol Fatty Acid Esters 1.5
Polyglycerol fatty acid esters 1.6 Conclusions References 2. Nitrogen
Derivatives of Natural Fats and Oils Ralph Franklin 2.1 Introduction 2.2
Manufacture of Fatty Nitrogen Derivatives 2.3 Production Data 2.4
Ecological Aspects 2.5 Biodegradation 2.6 Properties of Nitrogen-based
Surfactants 2.7 Applications 2.8 Conclusions References 3. Surface-Active
Compounds as Forest-Industry By-Products Bjarne Holmbom, Anna Sundberg and
Anders Strand 3.1 Introduction 3.2 Resin and Fatty Acids 3.3 Sterols and
Sterol Ethoxylates 3.4 Hemicelluloses Acknowledgement References Part 2:
Renewable Hydrophiles 4. Surfactants based on Carbohydrates and Proteins
for Consumer Products and Technical Applications Karlheinz Hill 4.1
Introduction 4.2 Raw materials 4.3 Products and Applications 4.4 Conclusion
5. Amino acids, lactic acid and ascorbic acid as raw materials for
biocompatible surfactants Carmen Moran, Lourdes Perez, Ramon Pons, Aurora
Pinazo and Mª Rosa Infante 5.1 Introduction 5.2 Production of raw materials
5.3 Lysine based surfactants 5.4 Lactic acid based surfactants 5.5 Ascorbic
acid based surfactants References Part 3: New ways of making renewable
building blocks 6. Synthesis of ethylene, propylene from ethanol or
methanol Anna Lundgren and Thomas Hjertberg 6.1 Introduction 6.2 Why
Produce Ethylene from Renewable Resources? 6.3 Production of Ethylene from
Renewable Feed Stock 6.4 Commercialization of Bioethylene 6.5 Environmental
Impact of Bioethylene 6.6 Certificate of Green Carbon Content 6.7
Concluding Remarks References 7. Fermentation based building blocks for
renewable resource based surfactants KrisArvid Berglund, Ulrika Rova, David
B. Hodge 7.1 Introduction 7.2 Existing and Potential Classes of Surfactants
from Biologically-Derived Metabolites 7.3 Fermentation-Based Building
Blocks with Large Existing Markets 7.4 New Fermentation-Based Building
Blocks Conclusion References Part 4: Biosurfactants 8. Enzymatic synthesis
of biosurfactants, Patrick Adlercreutzand Rajni Hatti-Kaul 8.1 Introduction
8.2 Enzymes as catalysts for synthesis of surfactants 8.3 Enzymatic
synthesis of polar lipids useful as surfactants 8.4 Carbohydrate esters 8.5
Fatty amide surfactants 8.6 Amino acid-based surfactants 8.7 Alkyl
glycosides 8.8 Future prospects Acknowledgement References 9. Surfactants
from waste biomass Flor Yunuen Garcia-Becerra, David Grant Allen, and Edgar
Joel Acosta 9.1 Introduction 9.2 Surfactants obtained from biological
transformation of waste biomass 9.3 Surfactants obtained from chemical
transformation of waste biomass 9.4 Summary and outlook 9.5 References 10.
Lecithin and Phospholipids Willem van Nieuwenhuyzen 10.1 Introduction 10.2
Sources and production 10.3 Composition 10.4 Quality and analysis of
lecithins 10.5 Modification 10.6 Emulsifying properties 10.7 Applications
10.8 Legislation and reach 10.9 Conclusion References 11. Sophorolipid and
rhamnolipid synthesis and their application in cleaning products Dirk
Develter and Steve Fleurackers 11.1 Sophorolipids 11.2 Derivatives of
native sophorolipids 11.3 Biosynthesis of novel sophorolipids 11.4
Rhamnolipids 11.5 Cleaning applications using sophorolipids and
rhamnolipids References 12. Saponin based surfactants Wieslaw Oleszek and
Arafa Hamed 12.1 Introduction 12.2 Molecular properties 12.3 Sources of
saponins 12.4 Saponins as emulsifiers and surfactants 12.5 Application of
saponins as surfactants and emulsifiers References Part 5: Polymeric
surfactants/Surface active polymers 13. Surface active polymers from
cellulose Leif Karlson 13.1 Introduction 13.2 Structure and synthesis of
cellulose ether 13.3 Cellulose ethers in aqueous solution 13.4 Interaction
with surfactants 13.5 Clouding References 14. New developments in the
commercial utilisation of lignosulfonates Rolf Andreas Lauten, Bernt O.
Myrvold and Stig Are Gundersen 14.1 Introduction 14.2 Lignosulfonates 14.3
Lignosulfonate production 14.4 Environmental issues 14.5 Lignosulfonates as
stabilisers for emulsions and suspoemulsions 14.6 Superplasticizers for
concrete 14.7 Summary Acknowledgements References 15. Dispersion
stabilizers based on inulin Tharwat F. Tadrosand Bart Levecke 15.1
Introduction 15.2 Solution Properties of long-chain inulin and
hydrophobically modified inulin (HMI) 15.3 Interfacial Aspects of HMI at
Various Interfaces 15.4 Emulsions Stabilized Using HMI 15.5 Emulsion
Polymerization Using Hydrophobically Modified Inulin (HMI) 15.6 Use of HMI
for Preparation and Stabilisation of Nano-Emulsions References