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The pure phase of Bi1-xPrxFeO3 (x = 0 - 0.1) ceramics were fabricated using the powders obtained via sol-gel route at very low temperature. X-ray powder diffraction studies confirmed that these crystallize in rhombohedral perovskite structure associated with R3c space group. Frequency and temperature dependence of the dielectric, impedance, electric modulus spectra of these samples were investigated.