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High Quality Content by WIKIPEDIA articles! High Quality Content by WIKIPEDIA articles! Tantalum(V) fluoride is the inorganic compound with the formula TaF5. It is one of the principal molecular compounds of tantalum. Characteristic of some other pentafluorides, the compound is volatile but exists as an oligomer in the solid state. Solid and molten TaF5 is tetrameric, consisting of four TaF4 centers linked together via bridging fluoride centers. Gaseous TaF5 adopts the trigonal pyramidal structure with D3h symmetry.