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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In a tetrahedral molecular geometry a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are cos 1( 1/3) 109.5° when all four substituents are the same, as in CH4. This molecular geometry is common throughout the first half of the periodic table. The perfectly symmetrical tetrahedron belongs to point group Td, but most tetrahedral molecules are not of such high symmetry. Tetrahedral molecules can be chiral.