The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years…mehr
The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues.
The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here.
As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.Hinweis: Dieser Artikel kann nur an eine deutsche Lieferadresse ausgeliefert werden.
Professor Alexander Greer, Department of Chemistry, Brooklyn College, The City University of New York, New York, NY, USA. Professor Joel F. Liebman, Department of Chemistry & Biochemistry, University of Maryland (UMBC), Baltimore, MD, USA,
Inhaltsangabe
Part 1 1 An introduction to the consequences of spin and bond strength in the chemistry of diatomic oxygen, peroxides, and related species 1 Alexander Greer Alexandru T. Balaban Joel F. Liebman 2 Applications of endoperoxides derived from acenes and singlet oxygen 21 Werner Fudickar Torsten Linker 3 1,1-Dihydroperoxides 87 Chris Schwartz Patrick H. Dussault 4 Peroxide intermediates of oxidation processes: Organic trioxides 125 Sergey L. Khursan 5 Organic tetroxides and mechanism of peroxy radical recombination 197 Sergey L. Khursan 6 1,2-Dioxatrisulfane (thiaperoxide) intermediates in type I and II photooxygenation reactions 231 Edward L. Clennan 7 Sulfoxylic and thiosulfurous acids and their dialkoxy derivatives 265 Sergei V. Makarov Anna S. Makarova Radu Silaghi-Dumitrescu 8 Reactions of metal complexes with singlet oxygen 307 Matthias Selke 9 The chemistry of nitroso oxides 357 Ekaterina M. Chainikova Sergey L. Khursan Rustam L. Safiullin 10 Single-molecule reactive oxygen species detection in photocatalytic reactions 421 Takashi Tachikawa Tetsuro Majima 11 Reactions of peroxides on solid surfaces 437 Rossella Mello Maria Elena Gonzalez Nunez 12 Peroxide explosives 503 Thomas M. Klapotke Thomas Wloka 13 Gas-phase ion chemistry of organic peroxides 531 Shuji Kato Stephen J. Blanksby 14 Quantum chemical studies of carbonyl oxide chemistry in combustion and in the lower atmosphere 585 Keith T. Kuwata 15 Computational treatments of peroxy radicals in combustion and atmospheric reactions 633 Keith T. Kuwata 16 Heteroatom-substituted dioxetanes and their emerging biomedical applications 683 Gregory Nkepang Youngjae You 17 The use of hydrogen peroxide for disinfection and sterilization applications 713 Gerald McDonnell 18 Generation and reactivity of lipid hydroperoxides in biological systems 747 Albert W. Girotti Witold Korytowski 19 [ 18O]-Peroxides: Synthesis and biological applications 769 Paolo Di Mascio Sayuri Miyamoto Marisa H. G. Medeiros Glaucia R. Martinez Jean Cadet 20 Copper peroxide bioinorganic chemistry: From metalloenzymes to bioinspired synthetic systems 805 Isaac Garcia-Bosch Kenneth D. Karlin Subject Index 857
Part 1 1 An introduction to the consequences of spin and bond strength in the chemistry of diatomic oxygen, peroxides, and related species 1 Alexander Greer Alexandru T. Balaban Joel F. Liebman 2 Applications of endoperoxides derived from acenes and singlet oxygen 21 Werner Fudickar Torsten Linker 3 1,1-Dihydroperoxides 87 Chris Schwartz Patrick H. Dussault 4 Peroxide intermediates of oxidation processes: Organic trioxides 125 Sergey L. Khursan 5 Organic tetroxides and mechanism of peroxy radical recombination 197 Sergey L. Khursan 6 1,2-Dioxatrisulfane (thiaperoxide) intermediates in type I and II photooxygenation reactions 231 Edward L. Clennan 7 Sulfoxylic and thiosulfurous acids and their dialkoxy derivatives 265 Sergei V. Makarov Anna S. Makarova Radu Silaghi-Dumitrescu 8 Reactions of metal complexes with singlet oxygen 307 Matthias Selke 9 The chemistry of nitroso oxides 357 Ekaterina M. Chainikova Sergey L. Khursan Rustam L. Safiullin 10 Single-molecule reactive oxygen species detection in photocatalytic reactions 421 Takashi Tachikawa Tetsuro Majima 11 Reactions of peroxides on solid surfaces 437 Rossella Mello Maria Elena Gonzalez Nunez 12 Peroxide explosives 503 Thomas M. Klapotke Thomas Wloka 13 Gas-phase ion chemistry of organic peroxides 531 Shuji Kato Stephen J. Blanksby 14 Quantum chemical studies of carbonyl oxide chemistry in combustion and in the lower atmosphere 585 Keith T. Kuwata 15 Computational treatments of peroxy radicals in combustion and atmospheric reactions 633 Keith T. Kuwata 16 Heteroatom-substituted dioxetanes and their emerging biomedical applications 683 Gregory Nkepang Youngjae You 17 The use of hydrogen peroxide for disinfection and sterilization applications 713 Gerald McDonnell 18 Generation and reactivity of lipid hydroperoxides in biological systems 747 Albert W. Girotti Witold Korytowski 19 [ 18O]-Peroxides: Synthesis and biological applications 769 Paolo Di Mascio Sayuri Miyamoto Marisa H. G. Medeiros Glaucia R. Martinez Jean Cadet 20 Copper peroxide bioinorganic chemistry: From metalloenzymes to bioinspired synthetic systems 805 Isaac Garcia-Bosch Kenneth D. Karlin Subject Index 857
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