The Origin of Life and Evolutionary Biochemistry

Herausgegeben:Dose, K.

• Broschiertes Buch

Produktbeschreibung

The primary metabolism of protobionts was probably based on the electron transfer reactions regulated by catalysts or photo sensitizing pigments. The action of photoreceptive pigments was inevitable in the case of electron transfer leading to light energy storage in the reaction products. The primitive tetrapyrrolic pig ments formed abiogenically (porphin, chlorin) as well as their more complicated biogenic analogs (chlorophylls) are capable of photo sensitizing electron transfer in systems, having various degrees of molecular complexity. The inorganic photosensitizers (titanium dioxide. zinc oxide. etc.). being excited in the near ultraviolet. are able to perform the same reactions as porphyrins--electron transfer from donor to acceptor molecule (including photoreduction of viologens) or water molecule photooxidation (oxygen liberation). coupled with reduction of ferric compounds and quinones. The in organic photosensitizers are not used in biological evolution; actually the inorganic ions entered into tetrapyrrolic cycle. form ing effective photocatalysts. Inclusion of pigments into primary membranes led to elaborated coupling between pigments and enzymatic systems. The involvement of the excited pigments into the biocata lytic electron transfer chain was prerequisite to effective func tion of photosynthetic organisms. REFERENCES 1. Oparin. A. I., "Origin of Life on Earth," Izd. AN SSSR. Moscow. 1957. 2. Gaffron, H., in: "Horizons in Biochemistry" (Kasha. M and Pullmann, B eds.), p. 59. Academic Press, New York. 1962. 3. Calvin. M "Chemical Evolution," C1arendon Press, Oxford. 1969. 4. Pasynsky. A. G . and Pav1ovskaya. T. E . Uspekhii khimii 33, 1198 (1964).

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Produktdetails

• Verlag: Springer / Springer US / Springer, Berlin
• Artikelnr. des Verlages: 978-1-4684-2117-0
• Softcover reprint of the original 1st ed. 1974
• Seitenzahl: 488
• Erscheinungstermin: 14. März 2012
• Englisch
• Abmessung: 254mm x 178mm x 27mm
• Gewicht: 918g
• ISBN-13: 9781468421170
• ISBN-10: 1468421174
• Artikelnr.: 39506124

Inhaltsangabe

Historical Introduction: A. I. Oparin and the Origin of Life.- Chapters in Honor of "Proiskhozhdenie Zhizni" and A. I, Oparin.- Protein Structure and the Molecular Evolution of Biological Energy Conversion.- Condensation Reactions of Lysine in the Presence of Polyadenylic Acid.- Considerations of the Origin of Spontaneous Mutations.- Pre-Enzymic Emergence of Biochemical Metabolism.- The Methods of Science and the Origins of Life.- Phospholipid Monolayers-As a Prototype of Biological Membranes.- Peptides and Amino Acids in the Primordial Hydrosphere.- Amino Acids and Carbohydrates in Precambrian Rocks.- The Surfaces of Coacervate Drops and the Formation of Colonies.- On Some Problems of Evolution of the Photosynthetic Pigment Apparatus.- Ammonia: Did it have a Role in Chemical Evolution?.- Coacervate Droplets, Proteinoid Microspheres, and the Genetic Apparatus.- Aspects of the Evolution of Some Systems and Processes of Self-Regulation of Plant Metabolism.- Photochemical Formation of Organic Compounds from Mixtures of Simple Gases Simulating the Primitive Atmosphere of the Earth.- The Iron-Sulphur Proteins: Evolution of a Ubiquitous Protein from the Origin of Life to Higher Organisms.- Evolution and Ecology of Phosphorus Metabolism.- Amino Acid Synthesis by Glow Discharge Electrolysis: A Possible Route for Prebiotic Synthesis of Amino Acids.- Prefigured Ordering and Protoselection in the Origin of Life.- Life's Beginnings - Origin or Evolution?.- Chemical Evolution of Photosynthesis: Models and Hypotheses.- Comparative Study of Plant Organism Glutamine Synthetase.- The Light Dependent Processes in Fungi: A Possible Approach to Some Problems of Photobiological Evolution.- The Role of Inorganic Polyphosphates in Chemical and Biological Evolution.- SucroseSynthetase and its Physiological Role in the Storage Tissues.- Amino and Fatty Acids in Carbonaceous Meteorites.- Isolated Microsystems in Evolution.- The Search for Remnants of Early Evolution in Present-Day Metabolism.- Primitive Control of Cellular Metabolism.- On the Evolution of Macromolecules.- The Coacervate-In-Coacervate Theory of the Origin of Life.- Sedimentary Minerals under Reducing Conditions.- Micelles and Solid Surfaces as Amino Acid Polymerization Propagators.- Possible Ways of Identifying the Abiogenesis of Biochemically Important Compounds.- Evolution of Models for Evolution.- Photosynthesis and Some Problems of Evolution of Biological Systems.- The Oparin Theory and Some Problems of Evolution of Bioenergetic Systems.- An Evolutionary Model for Prebiotic Phosphorylation.- The Role of Shock Waves in the Chemical Evolution of Earth's Primitive Atmosphere.- Alexander Ivanovitch Oparin and the Origin of Life: A Recollection and Appreciation.- The Origin and Evolution of Enzyme Catalysis.- Oparin and the Origin of Life: Cosmological Considerations.- List of Contributors.