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This text book focuses on the uses of systemic approach to teaching and learning in heterocyclic chemistry [SATLHC] .The material in this book is divided into two chapters: First contains the description of the new general strategy of converting linear traditional unites into systemic unites. Then it makes use of this general strategy in building unite of five-member heterocyclic compounds [Pyrolle, Furan, and Thiophene]. The scenario of teaching this unite helps teachers to teach and learners to go in a deep learning. This unite was introduced as applicable model to convert any linear unites to systemic unites in heterocyclic chemistry. The second chapter presents the new systemic assessment [SA] strategy which changes the assessment from traditional linear bothering exams to enjoyable puzzle games in the form of systemics. Systemic assessment (SA) of learners is a new effective tool for assessing student s' meaningful understanding of heterocyclic chemistry. The book is suitable for students in the tertiary level.