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High Quality Content by WIKIPEDIA articles! Thermal decomposition, also called thermolysis, is defined as a chemical reaction in which a chemical substance breaks up into at least two chemical substances when heated. The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. The decomposition temperature of a substance is the temperature at which the substance decomposes into smaller substances or into its constituent atoms.For example, calcium carbonate decomposes into calcium oxide and carbon dioxide: CaCO3 CaO + CO2 ;Some compounds, on the other hand, simply decompose into their constituent elements. Water, when heated to well over 2000 °C, breaks up into its components - hydrogen and oxygen: 2 H2O 2 H2 + O2.