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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In classical mechanics (CM), at the molecular level, one can define a potential energy surface. This is a purely classical construct and does not hold for QM. In QM an adiabatic state (i.e. not resonant with other states) will remain occupied. For example in a diatomic, the classical interpretation of the stretch mode is a periodic vibration. Here CM agrees with QM and the system is perfectly adiabatic (all the energy remains in the vib mode).

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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. In classical mechanics (CM), at the molecular level, one can define a potential energy surface. This is a purely classical construct and does not hold for QM. In QM an adiabatic state (i.e. not resonant with other states) will remain occupied. For example in a diatomic, the classical interpretation of the stretch mode is a periodic vibration. Here CM agrees with QM and the system is perfectly adiabatic (all the energy remains in the vib mode).