Zirconium Tungstate
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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Zr(WO4)2, or zirconium tungstate is a metal oxide with unusual properties. The phase formed at ambient pressure by reaction of ZrO2 and WO3 is a metastable cubic phase, which has negative thermal expansion characteristics, namely it shrinks over a wide range of temperatures when heated. A number of other phases are formed at high pressures. Cubic zirconium tungstate (alpha-ZrW2O8), one of the several known phases of zirconium tungstate (ZrW2O8) is perhaps one of the…mehr

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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Zr(WO4)2, or zirconium tungstate is a metal oxide with unusual properties. The phase formed at ambient pressure by reaction of ZrO2 and WO3 is a metastable cubic phase, which has negative thermal expansion characteristics, namely it shrinks over a wide range of temperatures when heated. A number of other phases are formed at high pressures. Cubic zirconium tungstate (alpha-ZrW2O8), one of the several known phases of zirconium tungstate (ZrW2O8) is perhaps one of the most studied materials to exhibit negative thermal expansion. It has been shown to contract continuously over a previously unprecedented temperature range of 0.3 to 1050 K (at higher temperatures the material decomposes).