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Catalytic non-oxidative dehydrogenation of C3 ¿ C4 alkanes is of increasing importance due to the growing demand for the corresponding olefins. Commercial catalysts with supported CrOx or Pt-Sn species have, however, shortcomings of being toxic or limited availability. Against this background, the present work was focused on the development of alternative dehydrogenation catalysts on the basis of metal oxides with usually unchangeable metal oxidation state but with high ability for lattice oxygen removal. The working hypothesis was that catalytically active sites can be lattice defects on the surface of such materials.…mehr

Produktbeschreibung
Catalytic non-oxidative dehydrogenation of C3 ¿ C4 alkanes is of increasing importance due to the growing demand for the corresponding olefins. Commercial catalysts with supported CrOx or Pt-Sn species have, however, shortcomings of being toxic or limited availability. Against this background, the present work was focused on the development of alternative dehydrogenation catalysts on the basis of metal oxides with usually unchangeable metal oxidation state but with high ability for lattice oxygen removal. The working hypothesis was that catalytically active sites can be lattice defects on the surface of such materials.
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Autorenporträt
Dr. Tatiana Otroshchenko was born in Nikolaew. She studied chemistry in Moscow State University (2007 ¿ 2012). She obtained her PhD at the Leibniz Institute for Catalysis at the University of Rostock (2014 ¿ 2017). She is currently a postdoctoral fellow at the same institute.