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2D Monoelements: Properties and Applications explores the challenges, research progress and future developments of the basic idea of two-dimensional monoelements, classifications, and application in field-effect transistors for sensing and biosensing. The thematic topics include investigations such as: * Recent advances in phosphorene * The diverse properties of two-dimensional antimonene, of graphene and its derivatives * The molecular docking simulation study used to analyze the binding mechanisms of graphene oxide as a cancer drug carrier * Metal-organic frameworks (MOFs)-derived carbon…mehr
2D Monoelements: Properties and Applications explores the challenges, research progress and future developments of the basic idea of two-dimensional monoelements, classifications, and application in field-effect transistors for sensing and biosensing. The thematic topics include investigations such as: * Recent advances in phosphorene * The diverse properties of two-dimensional antimonene, of graphene and its derivatives * The molecular docking simulation study used to analyze the binding mechanisms of graphene oxide as a cancer drug carrier * Metal-organic frameworks (MOFs)-derived carbon (graphene and carbon nanotubes) and MOF-carbon composite materials, with a special emphasis on the use of these nanostructures for energy storage devices (supercapacitors) * Two-dimensional monoelements classification like graphene application in field-effect transistors for sensing and biosensing * Graphene-based ternary materials as a supercapacitor electrode * Rise of silicene and its applications in gas sensing
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Autorenporträt
Inamuddin, PhD, is an assistant professor at King Abdulaziz University, Jeddah, Saudi Arabia and is also an assistant professor in the Department of Applied Chemistry, Aligarh Muslim University, Aligarh, India. He has extensive research experience in multidisciplinary fields of analytical chemistry, materials chemistry, electrochemistry, renewable energy and environmental science. He has published about 150 research articles in various international scientific journals, 18 book chapters, and 60 edited books with multiple well-known publishers. Rajender Boddula, PhD, is currently working for the Chinese Academy of Sciences President's International Fellowship Initiative (CAS-PIFI) at the National Center for Nanoscience and Technology (NCNST, Beijing). His academic honors include multiple fellowships and scholarships, and he has published many scientific articles in international peer-reviewed journals, edited books with numerous publishers and has authored twenty book chapters. Mohd Imran Ahamed received his Ph.D on the topic "Synthesis and characterization of inorganic-organic composite heavy metals selective cation-exchangers and their analytical applications", from Aligarh Muslim University, India in 2019. He has published several research and review articles in SCI journals. His research focusses on ion-exchange chromatography, wastewater treatment and analysis, actuators and electrospinning. Abdullah M. Asiri is the Head of the Chemistry Department at King Abdulaziz University and the founder and Director of the Center of Excellence for Advanced Materials Research (CEAMR). He is the Editor-in-Chief of the King Abdulaziz University Journal of Science. He has received numerous awards, including the first prize for distinction in science from the Saudi Chemical Society in 2012. He holds multiple patents, has authored ten books and more than one thousand publications in international journals.
Inhaltsangabe
Preface xiii
1 Phosphorene: A 2D New Derivative of Black Phosphorous 1 Lalla Btissam Drissi, Siham Sadki and El Hassan Saidi
1.1 Introduction 1
1.2 Pristine 2D BP 3
1.2.1 Synthesis and Characterization 3
1.2.1.1 Top-Down Approaches 3
1.2.1.2 Bottom-Up Methods 4
1.2.1.3 Geometric Structure and Raman Spectroscopy 4
1.2.2 Physical Properties 5
1.2.2.1 Anisotropic Eectronic Behavior 5
1.2.2.2 Optical Properties 6
1.2.2.3 Elastic Parameters 8
1.2.3 Applications 9
1.2.3.1 Gas Sensors 9
1.2.3.2 Battery Applications 9
1.2.3.3 FETs 10
1.3 Phosphorene Oxides 10
1.3.1 Challenges: Degradation of Phosphorene 11
1.3.1.1 Light Exposure 11
1.3.1.2 Phosphorene vs Air 12
1.3.1.3 Functionalized Phosphorene 12
1.3.2 Half-Oxided Phosphorene 13
1.3.2.1 Electronic Structure 14
1.3.2.2 Optical Response 15
1.3.2.3 Strain Effect 16
1.3.3 Surface Oxidation on Phosphorene 18
1.3.3.1 Optoelectronic Features 18
1.3.3.2 Stress vs Strain 20
1.3.3.3 Thermal Conductivity 21
1.4 Conclusion 22
Acknowledgment 22
References 22
2 Antimonene: A Potential 2D Material 27 Shuai Liu, Tianle Zhang and Shengxue Yang
2.1 Introduction 27
2.2 Fundamental Characteristics 29
2.2.1 Structure 29
2.2.2 Electronic Band Structure 30
2.3 Experimental Preparation 30
2.3.1 Mechanical Exfoliation 30
2.3.2 Liquid Phase Exfoliation 32
2.3.3 Epitaxial Growth 35
2.3.4 Other Methods 40
2.4 Applications of Antimonene 40
2.4.1 Nonlinear Optics 40
2.4.2 Optoelectronic Device 42
2.4.3 Electrocatalysis 44
2.4.4 Energy Storage 45
2.4.5 Biomedicine 47
2.4.6 Magneto-Optic Storage 50
2.5 Conclusion and Outlook 50
References 52
3 Synthesis and Properties of Graphene-Based Materials 57 U. Naresh, N. Suresh Kumar, D. Baba Basha, Prasun Benerjee, K. Chandra Babu Naidu, R. Jeevan Kumar, Ramyakrishna Pothu and Rajender Boddula
3.1 Introduction 58
3.2 Applications 60
3.3 Structure 62
3.3.1 Graphene-Related Materials 63
3.3.2 Synthesis Techniques 64
3.3.3 Mechanical Exfoliation of Graphene Layers 64
3.3.4 Chemical Vapor Deposition of Graphene Layers 65
3.3.5 Hummer Method of Graphene 65
3.3.6 Plasma-Enhanced Chemical Vapor Deposition of Graphene Layers 65
3.4 Physical Properties 66
3.4.1 Thermal Stability 66
3.4.2 Electronic Properties 67
3.5 Conclusions 68
References 69
4 Theoretical Study on Graphene Oxide as a Cancer Drug Carrier 73 Satya Narayan Sahu, Saraswati Soren, Shanta Chakrabarty and Rojalin Sahu
4.1 Introduction 74
4.2 Molecular Interaction of Biomolecules and Graphene Oxide 76
4.2.1 Molecular Interaction of DNA with Graphene Oxide 76
4.2.2 Molecular Interaction of Protein with Graphene Oxide 77
4.3 Computational Method 78
4.4 Results and Discussion 79
4.4.1 Binding Behavior Between Graphene Oxide With Cancer Drugs (5-Flourouracil, Ibuprofen, Camptothecine, and Doxorubicin) 79
4.5 Conclusion 83
References 83
5 High-Quality Carbon Nanotubes and Graphene Produced from MOFs and Their Supercapacitor Application 87 Mandira Majumder, Ram B. Choudhary, Anukul K. Thakur, Rabah Boukherroub and Sabine Szunerits <
1 Phosphorene: A 2D New Derivative of Black Phosphorous 1 Lalla Btissam Drissi, Siham Sadki and El Hassan Saidi
1.1 Introduction 1
1.2 Pristine 2D BP 3
1.2.1 Synthesis and Characterization 3
1.2.1.1 Top-Down Approaches 3
1.2.1.2 Bottom-Up Methods 4
1.2.1.3 Geometric Structure and Raman Spectroscopy 4
1.2.2 Physical Properties 5
1.2.2.1 Anisotropic Eectronic Behavior 5
1.2.2.2 Optical Properties 6
1.2.2.3 Elastic Parameters 8
1.2.3 Applications 9
1.2.3.1 Gas Sensors 9
1.2.3.2 Battery Applications 9
1.2.3.3 FETs 10
1.3 Phosphorene Oxides 10
1.3.1 Challenges: Degradation of Phosphorene 11
1.3.1.1 Light Exposure 11
1.3.1.2 Phosphorene vs Air 12
1.3.1.3 Functionalized Phosphorene 12
1.3.2 Half-Oxided Phosphorene 13
1.3.2.1 Electronic Structure 14
1.3.2.2 Optical Response 15
1.3.2.3 Strain Effect 16
1.3.3 Surface Oxidation on Phosphorene 18
1.3.3.1 Optoelectronic Features 18
1.3.3.2 Stress vs Strain 20
1.3.3.3 Thermal Conductivity 21
1.4 Conclusion 22
Acknowledgment 22
References 22
2 Antimonene: A Potential 2D Material 27 Shuai Liu, Tianle Zhang and Shengxue Yang
2.1 Introduction 27
2.2 Fundamental Characteristics 29
2.2.1 Structure 29
2.2.2 Electronic Band Structure 30
2.3 Experimental Preparation 30
2.3.1 Mechanical Exfoliation 30
2.3.2 Liquid Phase Exfoliation 32
2.3.3 Epitaxial Growth 35
2.3.4 Other Methods 40
2.4 Applications of Antimonene 40
2.4.1 Nonlinear Optics 40
2.4.2 Optoelectronic Device 42
2.4.3 Electrocatalysis 44
2.4.4 Energy Storage 45
2.4.5 Biomedicine 47
2.4.6 Magneto-Optic Storage 50
2.5 Conclusion and Outlook 50
References 52
3 Synthesis and Properties of Graphene-Based Materials 57 U. Naresh, N. Suresh Kumar, D. Baba Basha, Prasun Benerjee, K. Chandra Babu Naidu, R. Jeevan Kumar, Ramyakrishna Pothu and Rajender Boddula
3.1 Introduction 58
3.2 Applications 60
3.3 Structure 62
3.3.1 Graphene-Related Materials 63
3.3.2 Synthesis Techniques 64
3.3.3 Mechanical Exfoliation of Graphene Layers 64
3.3.4 Chemical Vapor Deposition of Graphene Layers 65
3.3.5 Hummer Method of Graphene 65
3.3.6 Plasma-Enhanced Chemical Vapor Deposition of Graphene Layers 65
3.4 Physical Properties 66
3.4.1 Thermal Stability 66
3.4.2 Electronic Properties 67
3.5 Conclusions 68
References 69
4 Theoretical Study on Graphene Oxide as a Cancer Drug Carrier 73 Satya Narayan Sahu, Saraswati Soren, Shanta Chakrabarty and Rojalin Sahu
4.1 Introduction 74
4.2 Molecular Interaction of Biomolecules and Graphene Oxide 76
4.2.1 Molecular Interaction of DNA with Graphene Oxide 76
4.2.2 Molecular Interaction of Protein with Graphene Oxide 77
4.3 Computational Method 78
4.4 Results and Discussion 79
4.4.1 Binding Behavior Between Graphene Oxide With Cancer Drugs (5-Flourouracil, Ibuprofen, Camptothecine, and Doxorubicin) 79
4.5 Conclusion 83
References 83
5 High-Quality Carbon Nanotubes and Graphene Produced from MOFs and Their Supercapacitor Application 87 Mandira Majumder, Ram B. Choudhary, Anukul K. Thakur, Rabah Boukherroub and Sabine Szunerits <
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