Applications of Metal-Organic Frameworks and Their Derived Materials (eBook, PDF)
Redaktion: Inamuddin; Asiri, Abdullah M.; Ahamed, Mohd Imran; Boddula, Rajender
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Applications of Metal-Organic Frameworks and Their Derived Materials (eBook, PDF)
Redaktion: Inamuddin; Asiri, Abdullah M.; Ahamed, Mohd Imran; Boddula, Rajender
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Metal-organic frameworks (MOFs) are porous crystalline polymers con-structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual…mehr
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- Produktdetails
- Verlag: John Wiley & Sons
- Seitenzahl: 496
- Erscheinungstermin: 23. April 2020
- Englisch
- ISBN-13: 9781119651161
- Artikelnr.: 59371750
- Verlag: John Wiley & Sons
- Seitenzahl: 496
- Erscheinungstermin: 23. April 2020
- Englisch
- ISBN-13: 9781119651161
- Artikelnr.: 59371750
- Herstellerkennzeichnung Die Herstellerinformationen sind derzeit nicht verfügbar.
SPE) 225 9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-
SPE) 232 9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-
SPE) 239 9.5 Concluding Remarks 249 Acknowledgments 249 References 249 10 Anticancer and Antimicrobial MOFs and Their Derived Materials 263 Nasser Mohammed Hosny 10.1 Introduction 263 10.2 Anticancer MOFs 264 10.2.1 MOFs as Drug Carriers 264 10.2.2 MOFs in Phototherapy 269 10.3 Antibacterial MOFs 272 10.4 Antifungal MOFs 278 References 280 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Personal Care Products 287 Jagannath Panda, Satya Narayan Sahu, Tejaswini Sahoo, Biswajit Mishra, Subrat Kumar Pattanayak and Rojalin Sahu 11.1 Introduction 288 11.2 General Synthesis Routes 290 11.2.1 Hydrothermal Synthesis 295 11.2.2 Solvothermal Synthesis of MOFs 296 11.2.3 Room Temperature Synthesis 296 11.2.4 Microwave Assisted Synthesis 296 11.2.5 Mechanochemical Synthesis 297 11.2.6 Electrochemical Synthesis 297 11.3 Postsynthetic Modification in MOF 297 11.4 Computational Method 297 11.5 Results and Discussion 299 11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) 299 11.6 Conclusion 303 References 304 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds 313 Shella Permatasari Santoso, Artik Elisa Angkawijaya, Vania Bundjaja, Felycia Edi Soetaredjo and Suryadi Ismadji 12.1 Introduction 314 12.2 VOCs and Their Potential Hazards 315 12.2.1 Other Sources of VOCs 319 12.3 VOCs Removal Techniques 320 12.4 Fabricated MOF for VOC Removal 324 12.4.1 MIL Series MOFs 325 12.4.2 Isoreticular MOFs 327 12.4.2.1 Adsorption Comparison of the Isoreticular MOFs 330 12.4.3 NENU Series MOFs 332 12.4.4 MOF-5, Eu-MOF, and MOF-199 333 12.4.5 Amine-Impregnated MIL-100 334 12.4.6 Biodegradable MOFs MIL-88 Series 335 12.4.7 Catalytic MOFs 335 12.4.8 Photo-Degradating MOFs 336 12.4.9 Some Other Studied MOFs 337 12.5 MOF Composites 338 12.5.1 MIL-101 Composite With Graphene Oxide 338 12.5.2 MIL-101 Composite With Graphite Oxide 338 12.6 Generalization Adsorptive Removal of VOCs by MOFs 340 12.7 Simple Modeling the Adsorption 340 12.7.1 Thermodynamic Parameters 340 12.7.2 Dynamic Sorption Methods 341 12.8 Factor Affecting VOCs Adsorption 344 12.8.1 Breathing Phenomena 344 12.8.2 Activation of MOFs 345 12.8.3 Applied Pressure 346 12.8.4 Relative Humidity 347 12.8.5 Breakthrough Conditions 347 12.8.6 Functional Group of MOFs 347 12.8.7 Concentration, Molecular Size, and Type of VOCs 348 12.9 Future Perspective 349 References 350 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis 357 Gopalram Keerthiga, Peramaiah Karthik and Bernaurdshaw Neppolian List of Abbreviations 358 13.1 Introduction 358 13.2 Perspective Synthesis of MOF , and Their Derived Materials 360 13.3 MOF for Hydrogen Evolution Reaction 362 13.4 MOF for Oxygen Evolution Reaction 363 13.5 MOF for Oxygen Reduction Reaction 365 13.6 MOF for CO2 Electrochemical Reduction Reaction 366 13.6.1 Electrosynthesis of MOF for CO2 Reduction 366 13.6.2 Composite Electrodes as MOF for CO2 Reduction 367 13.6.3 Continuous Flow Reduction of CO2 369 13.6.4 CO2 Electrochemical Reduction in Ionic Liquid 369 13.7 MOF for Electrocatalytic Sensing 370 13.8 Electrocatalytic Features of MOF 371 13.9 Conclusion 372 Acknowledgment 372 References 372 14 Applications of MOFs and Their Composite Materials in Light-Driven Redox Reactions 377 Elizabeth Rojas-García, José M. Barrera-Andrade, Elim Albiter, A. Marisela Maubert and Miguel A. Valenzuela 14.1 Introduction 378 14.1.1 MOFs as Photocatalysts 381 14.1.2 Charge Transfer Mechanisms 382 14.1.3 Methods of Synthesis 385 14.2 Pristine MOFs and Their Application in Photocatalysis 387 14.2.1 Group 4 Metallic Clusters 387 14.2.2 Groups 8, 9, and 10 Metallic Clusters 393 14.2.3 Group 11 Metallic Clusters 393 14.2.4 Group 12 Metallic Clusters 403 14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis 413 14.3.1 Ag-MOF Composites 415 14.3.2 Au-MOF Composites 417 14.3.3 Cu-MOF Composites 417 14.3.4 Pd-MOF Composites 418 14.3.5 Pt-MOF Composites 419 14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis 421 14.4.1 TiO2-MOF Composites 422 14.4.2 Graphitic Carbon Nitride-MOF Composites 426 14.4.3 Bismuth-Based Semiconductors 429 14.4.4 Reduced Graphene Oxide-MOF Composites 430 14.4.5 Silver-Based Semiconductors 436 14.4.6 Other Semiconductors 438 14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis 442 14.5.1 Semiconductor-Semiconductor-MOF Composites 442 14.5.2 Semiconductor-Metal-MOF Composites 443 14.6 Conclusions 446 References 448 Index 463
SPE) 225 9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-
SPE) 232 9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-
SPE) 239 9.5 Concluding Remarks 249 Acknowledgments 249 References 249 10 Anticancer and Antimicrobial MOFs and Their Derived Materials 263 Nasser Mohammed Hosny 10.1 Introduction 263 10.2 Anticancer MOFs 264 10.2.1 MOFs as Drug Carriers 264 10.2.2 MOFs in Phototherapy 269 10.3 Antibacterial MOFs 272 10.4 Antifungal MOFs 278 References 280 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Personal Care Products 287 Jagannath Panda, Satya Narayan Sahu, Tejaswini Sahoo, Biswajit Mishra, Subrat Kumar Pattanayak and Rojalin Sahu 11.1 Introduction 288 11.2 General Synthesis Routes 290 11.2.1 Hydrothermal Synthesis 295 11.2.2 Solvothermal Synthesis of MOFs 296 11.2.3 Room Temperature Synthesis 296 11.2.4 Microwave Assisted Synthesis 296 11.2.5 Mechanochemical Synthesis 297 11.2.6 Electrochemical Synthesis 297 11.3 Postsynthetic Modification in MOF 297 11.4 Computational Method 297 11.5 Results and Discussion 299 11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) 299 11.6 Conclusion 303 References 304 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds 313 Shella Permatasari Santoso, Artik Elisa Angkawijaya, Vania Bundjaja, Felycia Edi Soetaredjo and Suryadi Ismadji 12.1 Introduction 314 12.2 VOCs and Their Potential Hazards 315 12.2.1 Other Sources of VOCs 319 12.3 VOCs Removal Techniques 320 12.4 Fabricated MOF for VOC Removal 324 12.4.1 MIL Series MOFs 325 12.4.2 Isoreticular MOFs 327 12.4.2.1 Adsorption Comparison of the Isoreticular MOFs 330 12.4.3 NENU Series MOFs 332 12.4.4 MOF-5, Eu-MOF, and MOF-199 333 12.4.5 Amine-Impregnated MIL-100 334 12.4.6 Biodegradable MOFs MIL-88 Series 335 12.4.7 Catalytic MOFs 335 12.4.8 Photo-Degradating MOFs 336 12.4.9 Some Other Studied MOFs 337 12.5 MOF Composites 338 12.5.1 MIL-101 Composite With Graphene Oxide 338 12.5.2 MIL-101 Composite With Graphite Oxide 338 12.6 Generalization Adsorptive Removal of VOCs by MOFs 340 12.7 Simple Modeling the Adsorption 340 12.7.1 Thermodynamic Parameters 340 12.7.2 Dynamic Sorption Methods 341 12.8 Factor Affecting VOCs Adsorption 344 12.8.1 Breathing Phenomena 344 12.8.2 Activation of MOFs 345 12.8.3 Applied Pressure 346 12.8.4 Relative Humidity 347 12.8.5 Breakthrough Conditions 347 12.8.6 Functional Group of MOFs 347 12.8.7 Concentration, Molecular Size, and Type of VOCs 348 12.9 Future Perspective 349 References 350 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis 357 Gopalram Keerthiga, Peramaiah Karthik and Bernaurdshaw Neppolian List of Abbreviations 358 13.1 Introduction 358 13.2 Perspective Synthesis of MOF , and Their Derived Materials 360 13.3 MOF for Hydrogen Evolution Reaction 362 13.4 MOF for Oxygen Evolution Reaction 363 13.5 MOF for Oxygen Reduction Reaction 365 13.6 MOF for CO2 Electrochemical Reduction Reaction 366 13.6.1 Electrosynthesis of MOF for CO2 Reduction 366 13.6.2 Composite Electrodes as MOF for CO2 Reduction 367 13.6.3 Continuous Flow Reduction of CO2 369 13.6.4 CO2 Electrochemical Reduction in Ionic Liquid 369 13.7 MOF for Electrocatalytic Sensing 370 13.8 Electrocatalytic Features of MOF 371 13.9 Conclusion 372 Acknowledgment 372 References 372 14 Applications of MOFs and Their Composite Materials in Light-Driven Redox Reactions 377 Elizabeth Rojas-García, José M. Barrera-Andrade, Elim Albiter, A. Marisela Maubert and Miguel A. Valenzuela 14.1 Introduction 378 14.1.1 MOFs as Photocatalysts 381 14.1.2 Charge Transfer Mechanisms 382 14.1.3 Methods of Synthesis 385 14.2 Pristine MOFs and Their Application in Photocatalysis 387 14.2.1 Group 4 Metallic Clusters 387 14.2.2 Groups 8, 9, and 10 Metallic Clusters 393 14.2.3 Group 11 Metallic Clusters 393 14.2.4 Group 12 Metallic Clusters 403 14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis 413 14.3.1 Ag-MOF Composites 415 14.3.2 Au-MOF Composites 417 14.3.3 Cu-MOF Composites 417 14.3.4 Pd-MOF Composites 418 14.3.5 Pt-MOF Composites 419 14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis 421 14.4.1 TiO2-MOF Composites 422 14.4.2 Graphitic Carbon Nitride-MOF Composites 426 14.4.3 Bismuth-Based Semiconductors 429 14.4.4 Reduced Graphene Oxide-MOF Composites 430 14.4.5 Silver-Based Semiconductors 436 14.4.6 Other Semiconductors 438 14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis 442 14.5.1 Semiconductor-Semiconductor-MOF Composites 442 14.5.2 Semiconductor-Metal-MOF Composites 443 14.6 Conclusions 446 References 448 Index 463