David John Ager, Michael B. East

Asymmetric Synthetic Methodology (eBook, PDF)

• Format: PDF

Produktbeschreibung

This comprehensive text presents a critical discussion of the scopes and limitations of various organic synthetic methodologies that are available for performing asymmetric transformations. In addition to purely chemical methods, the book covers applications of new enzymes and other biological systems that are increasingly useful in asymmetric methodology.

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Produktdetails

• Verlag: Taylor & Francis
• Seitenzahl: 512
• Erscheinungstermin: 18. August 2020
• Englisch
• ISBN-13: 9781000098495
• Artikelnr.: 59950852

Autorenporträt

David John Ager and Michael B. East

Inhaltsangabe

IntroductionNomenclatureWhy Asymmetric Synthesis?Methods to Achieve
Asymmetric SynthesisResolutionA Question of ScaleGeneral RulesCarbonyl
AdditionsHouk's RuleAllylic StrainBaldwin's RulesPericyclic Transition
StatesOne-Carbon TransformationsInversions at a Single Carbon CenterChiral
Organometallic ReagentsOther ReactionsReactions With Carbonyl
CompoundsReactions of Carbonyl Compounds With NucleophilesAcetal
ReactionsOther ElectrophilesOther ReactionsReductionsEnolate Reactions of
Carbonyl CompoundsEnol Ethers and Enolate FormationReactions of Enol Ethers
and EnolatesUse of Nitrogen DerivativesAsymmetric Deprotonations and
ProtonationsReactions of Functionalized Carbonyl SystemsAlkylations of
1,2-Functionalized Carbonyl CompoundsReductions of 1,2-Functionalized
Carbonyl CompoundsAlkylations of 1,3-Functionalized Carbonyl
CompoundsReductions of 1,3-Functionalized Carbonyl CompoundsOther
SystemsAldol and Related ReactionsThe Aldol Reaction: Methods of ControlThe
Aldol Reaction: The Role of Enolate Geometry and Metal CounterionThe
Formose ReactionPreparation and Reactions of AlkenesAlkene
SynthesisReactions of AlkenesReactions of Functionalized
AlkenesHydrogenationsOther Transition Metal Catalyzed ReactionsHydride
Delivery AgentsReactions of Some Functionalized AlkenesConjugate
AdditionsAllyl AlkylationsOther ReactionsAsymmetric Oxidations of Isolated
AlkenesEpoxidationsReactions of Epoxides1,2-DiolsFormation and Reactions of
Cyclic SulfatesPreparation and Reactions of AziridinesOxidations of
Functionalized AlkenesEpoxidation of Allyl AlcoholsReactions of 2,3-Epoxy
Alcohols and Related SystemsEpoxidations and Reactions of Other Unsaturated
SystemsOther OxidationsOther SystemsPericyclic ReactionsThe Diels-Alder
ReactionClaisen