Catalysis for a Sustainable Environment (eBook, PDF)

Reactions, Processes and Applied Technologies, 3 Volume Set
Redaktion: Pombeiro, Armando J. L.; Alegria, Elisabete C. B. A.; Sutradhar, Manas

• Format: PDF

Produktbeschreibung

Interdisciplinary approach to sustainability, illustrating current catalytic approaches in applied chemistry, chemical engineering, and materials science Catalysis for a Sustainable Environment covers the use of catalysis in its various approaches, including homogeneous, supported, and heterogeneous catalysis, and photo- and electrocatalysis, towards sustainable environmental benefits. The text fosters interdisciplinarity in sustainability by illustrating modern perspectives in catalysis, from fields including inorganic, organic, organometallic, bioinorganic, pharmacological, and analytical chemistry, along with chemical engineering and materials science. The chapters are grouped in seven sections on (i) Carbon Dioxide Utilization, (ii) Volatile Organic Compounds (VOCs) Transformation, (iii) Carbon-based Catalysis, (iv) Coordination, Inorganic, and Bioinspired Catalysis, (v) Organocatalysis, (vi) Catalysis for Water and Liquid Fuels Purification, and (vii) Hydrogen Formation/Storage. Sample topics covered in Catalysis for a Sustainable Environment include: * Activation of relevant small molecules with strong environmental impact and carbon-based catalysts for sustainable chemical processes * Catalytic synthesis of important added value organic compounds, in both commodity and fine chemistries (large and small scale productions, respectively) * Development of catalytic systems operating under environmentally benign and mild conditions towards the establishment of sustainable energy processes * Catalysis by coordination, metal and metal-free compounds, MOFs (metal-organic frameworks) and nanoparticles, and their contribution to environmental and sustainable processes Employing the latest approaches that impact global and circular economies, Catalysis for a Sustainable Environment serves as an excellent starting point for innovative catalytic approaches, and will appeal to professionals in engineering, academia, and industry who wish to improve existing processes and materials.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 928
• Erscheinungstermin: 16. Februar 2024
• Englisch
• ISBN-13: 9781119870623
• Artikelnr.: 70057487

Autorenporträt

Armando Pombeiro is Full Professor Jubilado at Instituto Superior Técnico, Universidade de Lisboa, member of the Academy of Sciences of Lisbon, of the European Academy of Sciences (EURASC) and of the Academia Europaea. His research addresses activation of small molecules with industrial, environmental or biological significance. Manas Sutradhar is an Assistant Professor at the Universidade Lusófona, Lisbon and an integrated researcher at the Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal. Elisabete C.B.A. Alegria is Adjunct Professor at the Chemical Engineering Department of Instituto Superior de Engenharia de Lisboa (ISEL) from Polytechnic Institute of Lisbon.

Inhaltsangabe

About the Editors xiii

Preface xv

Volume 1

1 Introduction 1
Armando J.L. Pombeiro, Manas Sutradhar, and Elisabete C.B.A. Alegria

Structure of the Book 2

Final Remarks 4

Part I Carbon Dioxide Utilization 5

2 Transition from Fossil-C to Renewable-C (Biomass and CO2) Driven by Hybrid Catalysis 7
Michele Aresta and Angela Dibenedetto

2.1 Introduction 7

2.2 The Dimension of the Problem 8

2.3 Substitutes for Fossil-C 8

2.4 Hybrid Catalysis: A New World 11

2.5 Hybrid Catalysis and Biomass Valorization 13

2.6 Hybrid Catalysis and CO2 Conversion 16

2.6.1 CO2 as Building Block 16

2.6.2 CO2 Conversion to Value-added Chemical and Fuels via Hybrid Systems 17

2.7 Conclusions 21

References 21

3 Synthesis of Acetic Acid Using Carbon Dioxide 25
Philippe Kalck

3.1 Introduction 25

3.2 Synthesis of Methanol from CO2 and H2 26

3.3 Carbonylation of Methanol Using CO2 28

3.4 Carbonylation of Methane Using CO2 31

3.5 Miscellaneous Reactions, Particularly Biocatalysis 31

3.6 Conclusions 32

References 32

4 New Sustainable Chemicals and Materials Derived from CO2 and Bio-based Resources: A New Catalytic Challenge 35
Ana B. Paninho, Malgorzata E. Zakrzewska, Leticia R.C. Correa, Fátima Guedes da Silva, Luís C. Branco, and Ana V.M. Nunes

4.1 Introduction 35

4.2 Cyclic Carbonates from Bio-based Epoxides 37

4.2.1 Bio-based Epoxides Derived from Terpenes 39

4.2.2 Bio-based Vinylcyclohexene Oxide Derived from Butanediol 41

4.2.3 Bio-based Epichlorohydrin Derived from Glycerol 42

4.2.4 Epoxidized Vegetable Oils and Fatty Acids 42

4.3 Cyclic Carbonates Derived from Carbohydrates 44

4.4 Cyclic Carbonates Derived from Bio-based Diols 46

4.5 Conclusions 50

Acknowledgements 50

References 50

5 Sustainable Technologies in CO 2 Utilization: The Production of Synthetic Natural Gas 55
M. Carmen Bacariza, José M. Lopes, and Carlos Henriques

5.1 CO 2 Valorization Strategies 55

5.1.1 CO 2 to CO via Reverse Water-Gas Shift (RWGS) Reaction 56

5.1.2 CO2 to CH 4 56

5.1.3 Co2 to C X H Y 57

5.1.4 CO2 to CH 3 OH 58

5.1.5 CO2 to CH 3 OCH 3 58

5.1.6 CO2 to R-OH 59

5.1.7 CO2 to HCOOH, R-COOH, and R-CONH 2 60

5.1.8 Target Products Analysis Based on Thermodynamics 60

5.2 Power-to-Gas: Sabatier Reaction Suitability for Renewable Energy Storage 61

5.3 CO 2 Methanation Catalysts 63

5.4 Zeolites: Suitable Supports with Tunable Properties to Assess Catalysts's Performance 64

5.5 Final Remarks 68

References 69

6 Catalysis for Sustainable Aviation Fuels: Focus on Fischer-Tropsch Catalysis 73
Denzil Moodley, Thys Botha, Renier Crous, Jana Potgieter, Jacobus Visagie, Ryan Walmsley, and Cathy Dwyer

6.1 Introduction 73

6.1.1 Sustainable Aviation Fuels (SAF) via Fischer-Tropsch-based Routes 73

6.1.2 Introduction to FT Chemistry 75

6.1.3 FT Catalysts for SAF Production 79

6.1.4 Reactor Technology for SAF Production Using FTS 81

6.2 State-of-the-art Cobalt Catalysts 82

6.2.1 Catalyst Preparation Routes for Cobalt-based Catalysts 85

6.2.1.1 Precipitation Methodology - a Short Summary 85

6.2.1.2 Preparation Methods Using Pre-shaped Supports 85

6.2.1.2.1 Support Modification 85

6.2.1.2.2 Cobalt Impregnation 85

6.2.1.2.3 Calcination 86

6.2.1.2