Andrew Williams

Concerted Organic and Bio-Organic Mechanisms (eBook, PDF)

• Format: PDF

Produktbeschreibung

This book presents an encyclopedic comparison of more than 7,000 commercially available enzymes, restriction endonucleases, DNA methyltransferases and enzyme mixtures, blends, and complexes. It lists the general and unique properties of each enzyme so readers can directly compare differences among products and offers a worldwide listing of nearly 1

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Dieser Download kann aus rechtlichen Gründen nur mit Rechnungsadresse in A, B, BG, CY, CZ, D, DK, EW, E, FIN, F, GR, HR, H, IRL, I, LT, L, LR, M, NL, PL, P, R, S, SLO, SK ausgeliefert werden.

Produktdetails

• Verlag: Taylor & Francis
• Seitenzahl: 296
• Erscheinungstermin: 25. November 2020
• Englisch
• ISBN-13: 9781000108545
• Artikelnr.: 60572670

Autorenporträt

Andrew Williams

Inhaltsangabe

DEFINITIONS
Origin of the Concept
Mechanism and its Description
The Definition of Concertedness
Bond Order and Coupling
Potential energy or Free Energy?
Classes of Concerted Reactions
TECHNIQUES
Detection of Intermediates
Exclusion of Stepwise Mechanisms
Transition State Structure
PROTON TRANSFER
Proton Transfer between Bases
Proton Transfer and Displacement Reactions at Saturated Carbon Centers
Proton Transfer and Double Bond Changes
Non-Perfect Synchronization
NUCLEOPHILIC DISPLACEMENTS AT UNSATURATED CARBON
Displacements at the Carbonyl Group
Vinyl Group Transfer
Nucleophilic Aromatic Substitution
Nucleophilic Substitution at Diagonal Carbon
NUCLEOPHILIC DISPLACEMENTS AT SATURATED CARBON
Mechanisms
The Carbenium Ion
Ion-Pair Intermediates
The Concerted Mechanism
DISPLACEMENT REACTIONS AT HETEROATOMS
Electophilic Displacement at Hydrogen
Nucleophilic Displacement at Saturated Nitrogen
Nucleophilc Displacement at Silicon
Nuleophilic Displacement at Phosphorus(V)
Displacement at Sulfur
CYCLIC REACTIONS
Intermediates
Clock Reactions
Energetic Relationships
Nascent Products
Isotope Effects
Theoretical Methods
ENZYME REACTIONS
Proton Transfer
Theoretical Calculations
Isotopes
Carbohydrases
Aspartyl Proteases
Hydride Transfer
Amine Oxidases
Carbon-Carbon Bond Formation
Clocks
Cyclic Reactions