H. A. J. Oonk, M. T. Calvet

Equilibrium Between Phases of Matter (eBook, PDF)

Phenomenology and Thermodynamics

• Format: PDF

Produktbeschreibung

The phase behaviour of materials and their thermodynamic properties are a central subject in all fields of materials research. The first Volume of the work, meant for graduate students in chemistry, geology, physics, and metallurgy, and their engineering counterparts, is split up in three levels, such that from level to level the portion and importance of thermodynamics and mathematics are increased. In the ground level it is shown that the basic principles of phase equilibria can be understood without the use of thermodynamics - be it that the concept of chemical potential is introduced right from the beginning. The intermediate level is an introduction to thermodynamics; culminating in the Gibbs energy as the arbiter for equilibrium - demonstrated for systems where the phases in equilibrium are pure substances. In the third level the accent is on binary systems, where one or more phases are solutions of the components. Explicit relationships between the variables are derived for equilibria involving ideal mixtures and ideal dilute solutions. Non-ideal systems are treated from three different angles - geometrically, analytically, and numerically.

Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-chapter exercises and their solutions are included. The work is useful for scientists as an introduction and a reference book.

Audience:

Students, teachers, and scientists in chemistry, chemical engineering, geology and geophysics, metallurgy, and related branches of materials science

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Produktdetails

• Verlag: Springer Netherlands
• Seitenzahl: 404
• Erscheinungstermin: 23. Oktober 2007
• Englisch
• ISBN-13: 9781402064081
• Artikelnr.: 43732045

Autorenporträt

Harry A.J. Oonk, Utrecht University, The Netherlands / M. Teresa Calvet, University of Barcelona, Spain

Inhaltsangabe

From the contents

level 0: Equilibrium.- The variables.- The rules.- Pure substances.- Binary and Ternary Systems.- Partition and Separation.- Chemical Equilibrium.- level 1: Differential expressions.- Work, heat, energy.- Heat capacity and enthalpy.- Ideal gas, expansion and compression.- Chemical energy.- Entropy.- Characteristic functions.- Gibbs energy and equilibrium.- Tables.- Pure Substances.- Chemical reactions.- level 2: Mixtures and partial quantities.- The open system, chemical potentials.- Change to molar quantities.- The ideal mixture.- Non-ideal behaviour.- Magic formulae.- Dilute solutions.- The solvent laws.- The solute laws.- Ideal equilibria.- Non-ideal systems - geometrically.- Non-Ideal Systems - Analytically.- Non-Ideal Systems - Numerically.

Rezensionen

From the reviews:

"Equilibrium Between Phases of Matter: Phenomenology and Thermodynamics is a welcome addition to the literature. The text will be useful to advanced undergraduates and first-year graduates ... who want to extend their knowledge of phase diagrams and how those diagrams connect to thermodynamics. ... also be of value to more experienced practitioners who want to broaden their perspective. ... I heartily recommend Equilibrium Between Phases of Matter if you want to enrich your knowledge of phase equilibrium and phase diagrams and their relation to thermodynamics." (John C. Wheeler, Physics Today, February, 2009)

"Harry A.J. Oonk and M. Teresa Calvet's Equilibrium Between Phases of Matter is a welcome addition to the literature. The text will be useful to advanced undergraduates and first-year graduates who have had a solid course in physical chemistry and who want to extend their knowledge of phase diagrams and how those diagrams connect to thermodynamics. It will also be of value to more experienced practitioners who want to broaden their perspective. I have taught and done research on the thermodynamics and statistical mechanics of phase transitions and critical phenomena for more than 40 years; yet in reading through Oonk and Calvet's text, I have learned new things and relearned others that I had once known "in principle" but had not taught over the years.""... I heartily recommend Equilibrium Between Phases of Matter if you want to enrich your knowledge of phase equilibrium and phase diagrams and their relation to thermodynamics. You are remarkably knowledgeable about the subject if you do not learn something from this book."John C. Wheeler, Physics Today, February 2009 Endorsements:"Equilibrium Between Phases of Matter" is a beautiful book that will be recognized as an important contribution for many tens of years!".Larry Kaufman, Founding editor of Computer Coupling of Phase Diagrams and Thermochemistry "This is a remarkable book! It approaches the equilibrium between phases of matter in three levels, with a constant undercurrent of thermodynamics. In the first level the phenomenology of a rich variety of phase equilibria is introduced and rationalized by the use of thermodynamics, the formal underpinning of which is introduced in the second level. In the third level the relevant thermodynamics are further elaborated allowing the understanding of subtle details of phase behavior. This is a rich book with many worked and workable examples. The reader will benefit from the consistent use of the correct variables and units for each problem. These days, where sustainability and the role of natural processes in achieving this are key to our future, true understanding of phenomenology and thermodynamics is more relevant than ever. It is a rewarding book which I recommend to chemists and geologists alike."Henk Lekkerkerker, Utrecht University "Equilibrium between phases of matter, written by H.A.J. Oonk and T. Calvet, is a very nice book which can be used and read with ease by any student or researcher who wants to understand the real basis of thermodynamics applied to phase equilibria. In short, a sound introduction, well in the thread of the Dutch thermodynamic school established more than a century ago by van der Waals and Bakhuis-Roozeboom."René Céolin, Professor of physical chemistry at the Paris-Descartes University