Andrew Williams

Free Energy Relationships in Organic and Bio-Organic Chemistry (eBook, PDF)

• Format: PDF

Produktbeschreibung

Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.

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Produktdetails

• Verlag: Royal Society of Chemistry
• Seitenzahl: 290
• Erscheinungstermin: 31. Oktober 2007
• Englisch
• ISBN-13: 9781847550927
• Artikelnr.: 44764022

Inhaltsangabe

Free Energy Relationships
The Equations
Effective Charge
Multiple Interactions to the Reaction Centre
Anomalies and Special Cases
Coupling Between Bonds in Transition States of Displacement Reactions
Applications
Answers to Problems
Summary of Equations
Tables of Constants
Some Linear Free Energy Equations.