Jean-Louis Burgot

General Analytical Chemistry (eBook, ePUB)

Electrochemical Analysis Methods

• Format: ePub

Produktbeschreibung

This book is devoted to the quantitative electrochemical methods of analysis in solution. A theoretical knowledge of each method is discussed. The methods are illustrated with several examples covering a wide range of types of analysis.

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Produktdetails

• Verlag: Taylor & Francis
• Erscheinungstermin: 13. September 2024
• Englisch
• ISBN-13: 9781040135174
• Artikelnr.: 72288323

Autorenporträt

Jean-Louis Burgot, Pharmacist, PhD in organic chemistry and PhD in analytical chemistry - thermometric titrimetry, formerly Professor in Analytical Chemistry, Faculty of Pharmaceutical and Biological Sciences of University of Rennes 1. His research interests and publications involve the synthesis and study of the physico-chemical properties of 1,2-Dithiole-3-thiones and derivatives, and the determination of thermodynamic and kinetic constants of pharmacologically active compounds. He has published seven books in French and English.

Inhaltsangabe

Preface. Acknowledgment. GENERALITIES. Thermodynamics and Equilibrium.
Recallings and Definitions Concerning the Electrochemical Cells. Present
Views on the Interface Metal/Solution. More on the Potential of an
Electrode. Kinetics of the Electrode Reaction. A Qualitative Study of the
Current-Potential Curves. Nernst's Equation-Electrode
Potentials-Electrochemical Potentials. Equation of Butler-Volmer. Transport
Phenomena in Solution: Diffusion. Limiting-Intensity-Real Current-Potential
Curves-Consequences of the Stationary State of Activation-Diffusion.
Reversible and Irreversible Systems. Electrochemical Indicators.
Forecasting Electrochemical Reactions at the Electrodes. Forecasting
Electrochemical Reactions in an Electrochemical Cell: Conditions of
Electrolysis. Transports by Migration. Current-Potential Curves During a
Chemical Reaction. Techniques Based on Concept of Impedance: Impedance
Spectroscopy. ELECTROCHEMICAL METHODS OF ANALYSIS. Conventional
Polarography. Pulse Voltammetry. Chronoamperometry. Cyclic Voltammetry.
Voltammetric Methods by Redissolution: Stripping Analysis. Voltammetry at
Ultramicroelectrodes. Amperometry. Conductometry. Generalities on
Potentiometry. Definitions and PH Determination. Potentiometry with
Chemical Sensors: Ion Selective Electrodes (I.S.E). Potentiometric
Titrations. Chronopotentiometry. Electrogravimetry-Separation by
Electrolysis. Coulometry. Chemical Sensors (Following). Electrochemical
Biosensors. Electrochemical Detectors in Liquid Chromatography.
APPENDICES. Voltage Measurements. Obtention of the Butler-Volmer' S
Equation. Laplace Transforms. Fick's Laws of Diffusion. Fresnel's Rule.
Cottrell's Equation and Extensions. Polarography: Ilkowic's Equation.
Quantitative Relationships in Pulse Differential Polarography.
Electrochemical Methods of Analysis Grounded on the Linear Sweeping of
Potential Equation of Randles-Sevcik. Elimination of the Migration Current.
Potential of Liquid Junction: Eisenmann-Nikolskii's Relation. Henderson's
Equation. Equation of Michaelis-Menten. Quantitative Aspects Applying to
the Amperometric and Potentiometric Enzymatic Biosensors. General
Bibliography. Glossary Electrochemical. Index.