Handbook of Aggregation-Induced Emission, Volume 2 (eBook, ePUB)

Typical AIEgens Design
Redaktion: Tang, Youhong; Tang, Ben Zhong

• Format: ePub

Produktbeschreibung

The second volume of the ultimate reference on the science and applications of aggregation-induced emission The Handbook of Aggregation-Induced Emission explores foundational and advanced topics in aggregation-induced emission, as well as cutting-edge developments in the field, celebrating twenty years of progress and achievement in this important and interdisciplinary field. The three volumes combine to offer readers a comprehensive and insightful interpretation accessible to both new and experienced researchers working on aggregation-induced emission. In Volume 2: Typical AIEgens Design, the editors address the design and synthesis of typical AIEgens that have made significant contributions to aggregation-induced emission research. Recent advances in the development of aggregation-induced emission systems are discussed and the book covers novel aggregation-induced emission systems in small molecule organogels, polymersomes, metal-organic coordination complexes and metal nanoclusters. Readers will also discover: * A thorough introduction to the synthesis and applications of tetraphenylpyrazine-based AIEgens, AIEgens based on 9,10-distyrylanthracene , and the Salicylaldehyde Schiff base * Practical discussions of aggregation-induced emission from the sixth main group and fluorescence detection of dynamic aggregation processes using AIEgens * Coverage of cyclic triimidazole derivatives and the synthesis of multi-phenyl-substituted pyrrole based materials and their applications Perfect for academic researchers working on aggregation-induced emission, this set of volumes is also ideal for professionals and students in the fields of photophysics, photochemistry, materials science, optoelectronic materials, synthetic organic chemistry, macromolecular chemistry, polymer science, and biological sciences.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 624
• Erscheinungstermin: 4. April 2022
• Englisch
• ISBN-13: 9781119642961
• Artikelnr.: 63731082

Autorenporträt

Youhong Tang is a Professor at Flinders University, Australia and actively works in aggregation-induced emission areas. Ben Zhong Tang is a Chair Professor at the Chinese University of Hong Kong, Shenzhen. He is widely known as the pioneer of the study of aggregation-induced emission.

Inhaltsangabe

List of Contributors xvii

Preface to Handbook of Aggregation-Induced Emission xxiii

Preface to Volume 2: Typical AIEgens Design xxv

1 Tetraphenylpyrazine-based AIEgens: Synthesis and Applications 1
Ming Chen, Anjun Qin, and Ben Zhong Tang

1.1 Introduction 1

1.2 Synthesis of TPP-based AIEgens 3

1.2.1 Cyclization Reaction 3

1.2.2 Suzuki-Miyaura Reaction 7

1.3 Functionalities of TPP-based AIEgens 8

1.3.1 Organic Light-emitting Diodes 8

1.3.2 Fluorescent Sensors 9

1.3.3 Chiral Cage for Self-assembly to Achieve White-light Emission 13

1.3.4 Metal-organic Framework 15

1.4 Conclusion 17

References 18

2 AIEgens Based on 9,10-Distyrylanthracene (DSA): From Small Molecules to Macromolecules 23
Leijing Liu, Bin Xu, and Wenjing Tian

2.1 Introduction 23

2.2 Application of AIE Luminogens Based on 9,10-Distyrylanthracene 24

2.2.1 Smart Materials with Stimulus Response 24

2.2.1.1 Piezofluorochromic Materials 24

2.2.1.2 Photochromic Materials 27

2.2.1.3 Thermochromic Materials 27

2.2.1.4 Acidichromic Materials 27

2.2.1.5 Multistimuli-responsive Materials 30

2.2.2 High Solid-state Luminescent Materials 30

2.2.3 Fluorescent Materials for Bioimaging 35

2.2.4 Fluorescent Probes for Chemical and Biological Sensing 41

2.2.4.1 Fluorescent Probes for Chemical Sensing 41

2.2.4.2 Fluorescent Probes for Biological Sensing 44

2.3 Conclusions and Outlook 46

Acknowledgments 47

References 47

3 Typical AIEgens Design: Salicylaldehyde Schiff Base 53
Yue Zheng and Aijun Tong

3.1 Introduction 53

3.1.1 AIE and ESIPT of Salicylaldehyde Schiff Base 53

3.1.2 Universal Design of SSB-based AIEgens 55

3.2 Fluorescent Probes 55

3.2.1 Metal Ion Detection and Imaging 55

3.2.2 Biologically and Environmentally Related Molecular Detection and Imaging 63

3.2.3 Ratiometric pH Probes 76

3.2.4 Bioimaging 76

3.3 Fluorescent Materials 81

3.3.1 Solid Fluorescence Emitting and Stimuli-Responsive Materials 81

3.3.2 Nanoparticles 88

3.4 Summary and Perspectives 91

References 92

4 Diaminodicyanoquinodimethanes: Fluorescence Emission Enhancement in Aggregates and Solids 97
N. Senthilnathan and T. P. Radhakrishnan

4.1 Introduction 97

4.1.1 Molecular Materials 97

4.1.2 'Push-Pull' Molecules 97

4.1.3 Diaminodicyanoquinodimethanes 98

4.2 Nonlinear Optical Materials based on DADQs 100

4.2.1 Molecular Hyperpolarizability 100

4.2.2 SHG Materials 100

4.2.3 Structure-Property Correlations 101

4.3 Enhanced Fluorescence in Aggregates and Solids Based on DADQs 102

4.3.1 Remote Functionalized Systems 102

4.3.2 Color Tuning, Nanocrystals, and Colloids 103

4.3.3 Ultrathin Films 105

4.3.4 New Directions 105

4.4 Mechanistic Insights into the Enhanced Fluorescence 106

4.4.1 Relevance of Intramolecular Effects 106

4.4.2 Role of Intermolecular Effects 106

4.5 Impact of Crystallinity on the Fluorescence Response 108

4.5.1 Amorphous-to-Crystalline Transformation: Fluorescence Switching and Tuning 108

4.5.2 Reversible Amorphous-Crystalline Transformations: Phase Change Materials 108

4.5.3 Impact of External Stimuli 110

4.6 Emergent and Potential Applications of DADQs 110

4.6.1 Electroluminescence and Nonlinear Optics 110