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This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene produced from metallocene catalysts. With these…mehr
This handbook provides an exhaustive description of polyethylene. The 50+ chapters are written by some of the most experienced and prominent authors in the field, providing a truly unique view of polyethylene. The book starts with a historical discussion on how low density polyethylene was discovered and how it provided unique opportunities in the early days. New catalysts are presented and show how they created an expansion in available products including linear low density polyethylene, high density polyethylene, copolymers, and polyethylene produced from metallocene catalysts. With these different catalysts systems a wide range of structures are possible with an equally wide range of physical properties. Numerous types of additives are presented that include additives for the protection of the resin from the environment and processing, fillers, processing aids, anti-fogging agents, pigments, and flame retardants. Common processing methods including extrusion, blown film, cast film, injection molding, and thermoforming are presented along with some of the more specialized processing techniques such as rotational molding, fiber processing, pipe extrusion, reactive extrusion, wire and cable, and foaming processes. The business of polyethylene including markets, world capacity, and future prospects are detailed. This handbook provides the most current and complete technology assessments and business practices for polyethylene resins.
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Autorenporträt
Mark A. Spalding is a Fellow in the Materials & Parts Processing Group at The Dow Chemical Company, Midland, MI. He joined Dow in 1985 after completing a BS from The University of Toledo and a MS and PhD from Purdue University, all in Chemical Engineering. He has performed fundamental research in single-screw extrusion, developed methods to measure resin physical properties that are important to polymer processing, developed numerous techniques to troubleshoot and increase the rates of extrusion lines, and has developed new mathematical models for extrusion simulation. He co-authored the book "Analyzing and Troubleshooting Single-Screw Extruders" with Gregory A. Campbell. Dr. Spalding is a Fellow and Honored Service Member of the Society of Plastics Engineers (SPE). Ananda M. Chatterjee started his career at Celanese Plastics (1978) and worked for Shell Development, Union Carbide, Dow Chemical, Kaneka Texas, and Ingenia Polymers. He had extensive and in-depth experience in polymer research and development, product commercialization, polymer film processing and products technology, polymer additives technology, additive blends technology and processing, customer technical service, intellectual property (patent) invention and licensing and technology transfer of UNIPOL polypropylene technology worldwide. He was a Fellow and Honored Service Member of the Society of Plastics Engineers (SPE). Dr. Chatterjee held a PhD from the University of Massachusetts Amherst and held over 25 U.S. patents. Dr. Chatterjee passed away in 2016 during the development of this book.
Inhaltsangabe
Foreword by Barry Morris xi Preface xiii List of Contributors xv Part 1: Principles and Properties of Polyethylene 1 An Industrial Chronology of Polyethylene 3 Christopher Dobbin 2 Catalysts for the Manufacture of Polyethylene 25 Yury V. Kissin 3 Ethylene Polymerization Processes and Manufacture of Polyethylene 61 Ian D. Burdett and Ronald S. Eisinger 4 Types and Basics of Polyethylene 105 Rajen M. Patel 5 Molecular Structural Characterization of Polyethylene 139 A. Willem deGroot, David Gillespie, Rongjuan Cong, Zhe Zhou and Rajesh Paradkar 6 Thermal Analysis of Polyethylene 217 Kevin Menard and Noah Menard 7 Rheology of Polyethylene 239 Gregory W. Kamykowski 8 Processing-Structure-Property Relationships in Polyethylene 283 Rajen M. Patel 9 Mechanical Properties of Polyethylene: Deformation and Fracture Behavior 309 Alexander Chudnovsky, and Kalyan Sehanobish Part 2: Processing and Fabrication of Polyethylene 10 Single-Screw Extrusion of Polyethylene Resins 339 Mark A. Spalding 11 Twin-Screw Extrusion of Polyethylene 357 Yoshitaka Kumura, Amit K. Chaudhary and Mark A. Spalding 12 Blown Film Processing 381 Thomas I. Butler 13 Cast Film Extrusion of Polyethylene 411 Hyunwoo Kim, Mark A. Spalding, Kurt A. Koppi, Wes Hobson and Joseph Dooley 14 Extrusion Coating and Laminating 429 Thomas Bezigian 15 Injection Molding 443 Jon Ratzlaff and Thomas Giovannetti 16 Blow Molding of Polyethylene 475 Mohammad Usman and Abdul Sami Siddiqui 17 Rotational Molding 535 Jon Ratzlaff and Glenn E. Larkin, Jr. 18 Thermoforming Polyethylene 573 Roger C. Kipp 19 Polyethylene Pipe Extrusion 591 Pam Maeger, V. Rohatgi, D. Hukill, N. Koganti and B. Martinez 20 Polyethylene Foam Extrusion 603 N. S. Ramesh 21 Expanded Polyethylene Bead Foam Technology 637 Steven R. Sopher 22 Polyethylene Fiber Extrusion 669 Johannes Fink 23 Polyethylene Compounding Technologies 695 Charles D. Park II and Steven Blazey 24 Polyethylene Modification by Reactive Extrusion 715 Adriana I. Moncada, Wenyi Huang and Nicholas Horstman Part 3: Additives for Polyethylene 25 Degradation and Stabilization of Polyethylene 753 Joseph J. Fay and Roswell E. King, III 26 Light Stabilization of Polyethylene 771 Feng Zuo and Tad Finnegan 27 Acid Scavengers for Polyethylene 793 Robert L. Sherman Jr. and Kimberly E. Kern 28 Slip Agents 821 John Gray and Thomas Breuer 29 Antiblocking Additives 833 Johannes Fink 30 Antistatic Additives for Polyethylene 853 Gina Butuc, Gea Spijkerman, Sue te Hofstee and Ted Kampen 31 Antifogging Agents for Polyethylene Films 865 Michele Potenza and Bjarne Nielsen 32 Lubricants for Polyethylene 877 Johannes Fink 33 Fluorinated Polymer Processing Aids for Polyethylene 889 David A. Seiler, Francois Beaume, Samuel Devisme and Jason A. Pomante 34 Chemical Blowing Agents for Polyethylene 909 Peter Schroeck, Randy Minton, Theresa Healy and Larry Keefe 35 Flame Retardants for Polyethylene 921 Rudolf Pfaendner 36 Nucleating Agents for Polyethylene 935 Darin L. Dotson 37 Antimicrobial Agents for Polyethylene 967 Ivan Ong 38 Pigments and Colorants for Polyethylene 985 Roger Reinicker Part 4: Applications of Polyethylene 39 Fillers and Reinforcing Agents for Polyethylene 1035 Janos Moczo and Bela Pukanszky 40 Flexible Packaging Applications of Polyethylene 1071 Jeff Wooster and Jill Martin 41 Rigid Packaging Applications 1091 Cliff R. Mure 42 Pipe and Tubing Applications of Polyethylene 1109 Bryan E. Hauger 43 Wire and Cable Applications of Polyethylene 1125 Scott H. Wasserman, Bharat I. Chaudhary, Jeffrey M. Cogen, Mohamed Esseghir and Timothy J. Person 44 Medical Applications of Polyethylene 1155 Benjamin Poon and Len Czuba 45 Automotive Applications for Polyethylene 1169 Kalyan Sehanobish 46 Textile, Hygiene, Health, and Geosynthetic Applications of Polyethylene 1179 Sanjiv R. Malkan 47 Applications of Polyethylene Elastomers and Plastomers 1197 Kim L. Walton, Tim Clayfield, Jim Hemphill and Lisa Madenjian Part 5: The Business of Polyethylene 48 Product Regulatory Considerations for Polyethylene 1221 Tor H. Palmgren 49 Sustainability and Recycling of Polyethylene 1245 Thomas Nosker and Jennifer Lynch 50 Bio-Polyethylene and Polyethylene-Biopolymer Blends 1253 Johannes Fink 51 The Business of Polyethylene 1297 Jorge O. Buhler-Vidal Appendix A1: Polymer Abbreviation Definitions 1331 Index 1333
Foreword by Barry Morris xi Preface xiii List of Contributors xv Part 1: Principles and Properties of Polyethylene 1 An Industrial Chronology of Polyethylene 3 Christopher Dobbin 2 Catalysts for the Manufacture of Polyethylene 25 Yury V. Kissin 3 Ethylene Polymerization Processes and Manufacture of Polyethylene 61 Ian D. Burdett and Ronald S. Eisinger 4 Types and Basics of Polyethylene 105 Rajen M. Patel 5 Molecular Structural Characterization of Polyethylene 139 A. Willem deGroot, David Gillespie, Rongjuan Cong, Zhe Zhou and Rajesh Paradkar 6 Thermal Analysis of Polyethylene 217 Kevin Menard and Noah Menard 7 Rheology of Polyethylene 239 Gregory W. Kamykowski 8 Processing-Structure-Property Relationships in Polyethylene 283 Rajen M. Patel 9 Mechanical Properties of Polyethylene: Deformation and Fracture Behavior 309 Alexander Chudnovsky, and Kalyan Sehanobish Part 2: Processing and Fabrication of Polyethylene 10 Single-Screw Extrusion of Polyethylene Resins 339 Mark A. Spalding 11 Twin-Screw Extrusion of Polyethylene 357 Yoshitaka Kumura, Amit K. Chaudhary and Mark A. Spalding 12 Blown Film Processing 381 Thomas I. Butler 13 Cast Film Extrusion of Polyethylene 411 Hyunwoo Kim, Mark A. Spalding, Kurt A. Koppi, Wes Hobson and Joseph Dooley 14 Extrusion Coating and Laminating 429 Thomas Bezigian 15 Injection Molding 443 Jon Ratzlaff and Thomas Giovannetti 16 Blow Molding of Polyethylene 475 Mohammad Usman and Abdul Sami Siddiqui 17 Rotational Molding 535 Jon Ratzlaff and Glenn E. Larkin, Jr. 18 Thermoforming Polyethylene 573 Roger C. Kipp 19 Polyethylene Pipe Extrusion 591 Pam Maeger, V. Rohatgi, D. Hukill, N. Koganti and B. Martinez 20 Polyethylene Foam Extrusion 603 N. S. Ramesh 21 Expanded Polyethylene Bead Foam Technology 637 Steven R. Sopher 22 Polyethylene Fiber Extrusion 669 Johannes Fink 23 Polyethylene Compounding Technologies 695 Charles D. Park II and Steven Blazey 24 Polyethylene Modification by Reactive Extrusion 715 Adriana I. Moncada, Wenyi Huang and Nicholas Horstman Part 3: Additives for Polyethylene 25 Degradation and Stabilization of Polyethylene 753 Joseph J. Fay and Roswell E. King, III 26 Light Stabilization of Polyethylene 771 Feng Zuo and Tad Finnegan 27 Acid Scavengers for Polyethylene 793 Robert L. Sherman Jr. and Kimberly E. Kern 28 Slip Agents 821 John Gray and Thomas Breuer 29 Antiblocking Additives 833 Johannes Fink 30 Antistatic Additives for Polyethylene 853 Gina Butuc, Gea Spijkerman, Sue te Hofstee and Ted Kampen 31 Antifogging Agents for Polyethylene Films 865 Michele Potenza and Bjarne Nielsen 32 Lubricants for Polyethylene 877 Johannes Fink 33 Fluorinated Polymer Processing Aids for Polyethylene 889 David A. Seiler, Francois Beaume, Samuel Devisme and Jason A. Pomante 34 Chemical Blowing Agents for Polyethylene 909 Peter Schroeck, Randy Minton, Theresa Healy and Larry Keefe 35 Flame Retardants for Polyethylene 921 Rudolf Pfaendner 36 Nucleating Agents for Polyethylene 935 Darin L. Dotson 37 Antimicrobial Agents for Polyethylene 967 Ivan Ong 38 Pigments and Colorants for Polyethylene 985 Roger Reinicker Part 4: Applications of Polyethylene 39 Fillers and Reinforcing Agents for Polyethylene 1035 Janos Moczo and Bela Pukanszky 40 Flexible Packaging Applications of Polyethylene 1071 Jeff Wooster and Jill Martin 41 Rigid Packaging Applications 1091 Cliff R. Mure 42 Pipe and Tubing Applications of Polyethylene 1109 Bryan E. Hauger 43 Wire and Cable Applications of Polyethylene 1125 Scott H. Wasserman, Bharat I. Chaudhary, Jeffrey M. Cogen, Mohamed Esseghir and Timothy J. Person 44 Medical Applications of Polyethylene 1155 Benjamin Poon and Len Czuba 45 Automotive Applications for Polyethylene 1169 Kalyan Sehanobish 46 Textile, Hygiene, Health, and Geosynthetic Applications of Polyethylene 1179 Sanjiv R. Malkan 47 Applications of Polyethylene Elastomers and Plastomers 1197 Kim L. Walton, Tim Clayfield, Jim Hemphill and Lisa Madenjian Part 5: The Business of Polyethylene 48 Product Regulatory Considerations for Polyethylene 1221 Tor H. Palmgren 49 Sustainability and Recycling of Polyethylene 1245 Thomas Nosker and Jennifer Lynch 50 Bio-Polyethylene and Polyethylene-Biopolymer Blends 1253 Johannes Fink 51 The Business of Polyethylene 1297 Jorge O. Buhler-Vidal Appendix A1: Polymer Abbreviation Definitions 1331 Index 1333
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