Handbook of Metathesis, Volume 1 (eBook, ePUB)

Catalyst Development and Mechanism
Redaktion: Grubbs, Robert H.; Wenzel, Anna G.

• Format: ePub

Produktbeschreibung

The second edition of the Handbook of Metathesis, edited by Nobel Prize Winner Robert H. Grubbs and his team, is available as a 3 Volume set as well as individual volumes.

Volume 1, edited by R. H. Grubbs together with A. G. Wenzel focusses on Catalyst Development and Mechanism.

The new edition of this set is completely updated (more than 80% new content) and expanded, with a special focus on industrial applications. Written by the "Who-is-Who" of metathesis, this book gives a comprehensive and high-quality overview. It is the perfect and ultimate one-stop-reference source in this field and indispensable for chemists in academia and industry alike. View the set here - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527334246.html

Other available volumes:

Volume 2: Applications in Organic Synthesis, Editors: R. H. Grubbs and D. J. O¿Leary - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339493.html

Volume 3: Polymer Synthesis, Editors: R. H. Grubbs and E. Khosravi - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339507.html

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Produktdetails

• Verlag: Wiley-VCH
• Erscheinungstermin: 23. Februar 2015
• Englisch
• ISBN-13: 9783527693993
• Artikelnr.: 42477967

Autorenporträt

Robert H. Grubbs received his Ph.D. from Columbia University for work with Ron Breslow. After a postdoctoral year with Jim Collman at Stanford University, he joined the faculty at Michigan State University. In 1978, he moved to the California Institute of Technology, where he is now the Victor and Elizabeth Atkins Professor of Chemistry. Among many other awards, he received the Nobel Prize in 2005 for his research on the metathesis reaction. His research interests include polymer chemistry, organometallic catalysis, and the development of new synthetic organic methodology. Anna G. Wenzel received her PhD at Harvard University under the guidance of Prof. E. N. Jacobsen. From 2003 to 2006, she joined the group of Prof. R. H. Grubbs as an NIH Postdoctoral Scholar. In 2006, she joined the faculty as an Assistant Professor at the W. M. Keck Science Department in Claremont, California. In 2012, she was promoted to Associate Professor. Her research topics are asymmetric catalysis, organometallic chemistry, and organic synthesis.

Inhaltsangabe

Preface HIGH-OXIDATION ON STATE MOLYBDENUM AND TUNGSTEN COMPLEXES RELEVANT
TO OLEFIN METATHESIS Introduction New Imido Ligands and Synthetic
Approaches Bispyrrolide and Related Complexes Monoalkoxide Pyrrolide (MAP)
Complexes Reactions of Alkylidenes with Olefins Olefin and
Metallacyclopentane Complexes Tungsten Oxo Complexes Bisaryloxides Other
Constructs Conclusions ALKANE METATHESIS Introduction Alkane Metathesis by
Single-Catalyst Systems Alkane Metathesis by Tandem, Dual-Catalytic Systems
Conclusion DIASTEREOCONTROL IN OLEFIN METATHESIS: THE DEVELOPMENT OF
Z-SELECTIVE RUTHENIUM CATAYLSTS Introduction The Challenge of Z-Selective
Olefin Metathesis Previous Strategies A Serendipitous Discovery Catalyst
Studies Applications of Z-Selective Ru Metathesis Catalysts Conclusion
RUTHENIUM OLEFIN METATHESIS CATALYSTS SUPPORTED BY CYCLIC ALKYL
AMINOCARBENES (CAACs) Introduction Properties and Preparation of CAAC
Ligands CAAC-Supported, Ruthenium Olefin Metathesis Catalysts Summary
SUPPORTED CATALYSTS AND NONTRADITIONAL REACTION MEDIA Introduction
Supported Catalyst Systems Olefin Metathesis in Nontraditional Media
Conclusions INSIGHTS FROM COMPUTATIONAL STUDIES ON d0 METAL-CATALYZED
ALKENE AND ALKYNE METATHESIS AND RELATED REACTIONS Introduction Alkene
Metathesis Alkyne Metathesis Alkane Metathesis Outlook COMPUTATIONAL
STUDIES OF RUTHENIUM-CATALYZED OLEFIN METATHESIS Introduction Computational
Investigations of Non-Chelated Ruthenium Catalysts Computational
Investigations of Chelated, Z-Selective Ruthenium Catalysts Accuray of the
Computational Methods INTERMEDIATES IN OLEFIN METATHESIS Introduction
Metathesis-Active, Early-Metal Metallacycles Intermediates in
Ruthenium-Catalyzed Olefin Metathesis Future Directions FACTORS AFFECTING
INITIATION RATES Introduction Grubbs Second-Generation Catalyst
Grubbs-Hoveyda-Type Precatalysts Pyridine Solvates Piers Catalysts
Indenylidene Carbene Precatalysts Z-Selective Catalysts Herrmann-Type,
BisNHCs Conclusions DEGENERATE METATHESIS Introduction Degenerate
Metathesis Mechanisms Degenerate Metathesis with Early Transition-Metal
Catalysts Degenerate Metathesis with Ruthenium Catalysts Beneficial Effects
of Degenerate Metathesis Conclusions MECHANISMS OF OLEFIN METATHESIS
CATALYST DECOMPOSITION AND METHODS OF CATALYST REACTIVATION Introduction
Decomposition of Mo and W Imido Alkylidene Catalysts and Related Complexes
Decomposition of Ru Alkylidene Catalysts and Related Complexes Conclusions
SOLVENT AND ADDITIVE EFFECTS ON OLEFIN METATHESIS General Introduction
Solvent Effects on Olefin Metathesis Additive Effects on Olefin Metathesis
Summary METATHESIS PRODUCT PURIFICATION Introduction Chromatographic and
Chemical Removal of Ruthenium Removal by Complexation Conclusion RUTHENIUM
INDENYLIDENE CATALYSTS FOR ALKENE METATHESIS Introduction The Initial
Development of Indenylidene Metal Complexes for Alkene Metathesis Binuclear
Indenylidene Ruthenium Catalysts Arising from Ruthenium(arene) Complexes
Preparation of Ruthenium Indenylidene Catalysts from RuCl2(PPh3)3 Ruthenium
Catalysts Bearing a Chelating Indenylidene Ligand Conclusion