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Helicenes A thorough introduction to everything there is to know about this fascinating compound class The intriguing nature of this highly interesting compound class has inspired much research over the last decade, and much of what has been produced is highly interdisciplinary, with applications found in catalysis, material science, and spectroscopy. Indeed, the field has reached maturity such that elegant synthetic methods are now available and novel applications in arenas such as enantioselective catalysis and optoelectronics are appearing. Helicenes provides not only an…mehr
A thorough introduction to everything there is to know about this fascinating compound class
The intriguing nature of this highly interesting compound class has inspired much research over the last decade, and much of what has been produced is highly interdisciplinary, with applications found in catalysis, material science, and spectroscopy. Indeed, the field has reached maturity such that elegant synthetic methods are now available and novel applications in arenas such as enantioselective catalysis and optoelectronics are appearing.
Helicenes provides not only an introduction to the synthesis of the fascinating compound class of helicenes, but also describes the properties and, most importantly, their applications. The book thoroughly explains several synthetic routes from classical to state-of-the-art methods. In addition, the different classes of helicene-based molecules - organic, organometallic, oligo-meric, and multidimensional - are covered.
Helicenes readers will also find:
Edited by world-leading experts in the field of chirality
A comprehensive and well-structured approach that deals with every aspect of this compound class
Discussions of the applications of helicenes in organic synthesis, photophysics, material science, optoelectronic devices, on-surface chemistry, and theoretical calculations
A special focus on the applications of helicenes in catalysis, optoelectronics, non-linear optics, and chiroptical spectroscopy
Chapters focusing on helicenes as theoretical helically chiral models
Helicenes is an essential reference for organic chemists, materials scientists, spectroscopists, polymer chemists, inorganic chemists, and catalytic chemists, as well as students in these fields and libraries supplying them.
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Autorenporträt
Dr. Jeanne Crassous (née Costante) is currently Director of Research at the CNRS (University of Rennes). In 2013, she became a distinguished member of French Chemical Society (Société Chimique de France, SCF). Her group is dealing with many fields related to chirality (organometallic and heteroatomic helicenes, fundamental aspects of chirality such as parity violation effects, chiroptical activity such as electronic and vibrational circular dichroism and circularly polarized luminescence). She has published more than 110 papers and a French monography on the Stereochemistry of Chiral Molecules. She is responsible for a National Network on "Chirality and Multifunctionality". Dr. Irena G. Stará is currently a senior scientist and project leader at the IOCB Prague, chair of the board of trustees of the Experientia Foundation, member of the International Advisory Board of the International Symposiums on Novel Aromatics and member of the Advisory Board for the French-Czech Vltava Chemistry Meetings. Her current research interests center on chiral aromatics and their application to catalysis, chiro-, and nanoscience. She published around 90 papers. Dr. Ivo Stary is a senior group leader at the IOCB Prague. Education: MSc (1984, Charles University Prague, Czechoslovakia), PhD (1990, Prof. P. Kocovsk?, Czechoslovak Academy of Sciences, Prague), postdoc (1993/1994, Prof. E. P. Kündig, University of Geneva, Switzerland). Awards: Alfred Bader Award for organic chemistry (1994), IOCF Yoshida Lectureship, Japan (2016), Elected member of the Learned Society of the Czech Republic (2017), Rudolf Lukes Award (2018). His current research interests center on the development of new synthetic methods, chirality, and molecular devices. He published around 100 papers.
Inhaltsangabe
Photochemical Approach to Helicenes Synthesis of Helicenes by [2+2+2] Cycloisomerization Enantioselective Synthesis of Helicenes Cationic Azahelicenes Organometallic and Coordination Chemistry of Helicenes Tetrathiahelicenes: An Infinite Source of Inspiration Synthesis and Properties of Helicenes with Small Numbers of Benzene Rings Halogenated Helicenes as Precursors for Multihelicenic Platforms Helical Nanographenes: Synthetic and Chiroptical Achievements Helicenic Electron Acceptors Chiroptical Properties of Helicenes - Historical Perspective and Structure-property Relationships Photophysical and Chiroptical Properties of Helicene-based Systems: Experiment vs. Theory Helicene Derivatives with Circularly Polarized Luminescence Helicenes and Nonlinear Optical Properties: A Good Match? Helicenes for Optoelectronic Devices and Applications Miscellaneous Applications of Helicenes: Surface Science and Asymmetric Catalysis
Photochemical Approach to Helicenes Synthesis of Helicenes by [2+2+2] Cycloisomerization Enantioselective Synthesis of Helicenes Cationic Azahelicenes Organometallic and Coordination Chemistry of Helicenes Tetrathiahelicenes: An Infinite Source of Inspiration Synthesis and Properties of Helicenes with Small Numbers of Benzene Rings Halogenated Helicenes as Precursors for Multihelicenic Platforms Helical Nanographenes: Synthetic and Chiroptical Achievements Helicenic Electron Acceptors Chiroptical Properties of Helicenes - Historical Perspective and Structure-property Relationships Photophysical and Chiroptical Properties of Helicene-based Systems: Experiment vs. Theory Helicene Derivatives with Circularly Polarized Luminescence Helicenes and Nonlinear Optical Properties: A Good Match? Helicenes for Optoelectronic Devices and Applications Miscellaneous Applications of Helicenes: Surface Science and Asymmetric Catalysis
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