Inorganic Syntheses, Volume 31 (eBook, PDF)

• Format: PDF

Produktbeschreibung

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preperation of important inorganic solidsd, sutheses used in the development of pharamacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains calcuable information on transition organometallic compunds, including species with meta-metal cluster molecules. All syntheses presented here have been tested.

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Produktdetails

• Verlag: John Wiley & Sons
• Erscheinungstermin: 22. September 2009
• Englisch
• ISBN-13: 9780470132975
• Artikelnr.: 37290894

Autorenporträt

Alan Herbert Cowley FRS is a British chemist, and Robert A. Welch Chair at the University of Texas at Austin. He was a 1976 Guggenheim Fellow.

Inhaltsangabe

Chapter One MAIN GROUP COMPOUNDS. 1. Volatile
² Diketonate Complexes of Calcium(II), Strontium(II), and Barium(II). 2. Bis(1,1,1,3,3,3
hexamethyldisilazanato) bis(tetrahydrofuran)
barium. 3. Ammonium and Barium Salts of the Tris
[1,2
benzenediolate(2
)
O,O']titanium(IV) Dianion. 4. N
Donor Adducts of Dimethylzinc. 5. Arene Chalcogenolato Complexes of Zinc and Cadmium. 6. Arene Thiolato, Selenolato, and Tellurolato Complexes of Mercury. 7. Electronic Grade Alkyls of Group 12 and 13 Elements. 8. Trimethylindium and Trimethylgallium. 9. (N,N
dimethylethanamine) trihydridoafuminum. 10. Tertiary Amine and Phosphine Adducts of Gallium Trihydride. 11. trans
1,1
Di
tert
butyl
2,3
dimethylsilane and 2,2
Di
tert
butyl 1,1,1
triethyldisilane. 12. Tin(II) Sulfide and Tin(II) Selenide. 13. Tin(IV) Fluoride (Tetrafluorostannane). 14. N,N,N'
Tris(trimethylsilyl) Amidines. 15. Homoleptic Bismuth Amides. 16. Cyclo
tetrasulfur(2+) Bis[hexafluoroarsenate(1
)], Cyclo
tetrasulfur(2+)Bis[undecafluorodiantimonate(1
)], Cyclo
tetraselenium(2+)Bis[hexafluroarsenate(1
)] and Cyclo
tetraselenium(2+) Bis[undecafluorodiantimonate(1
)]. 17. Fe2(S2)(CO)6, and Fe3Te2(CO)9,10. Chapter Two LIGANDS AND REAGENTS. 18. 5,10,15,20
Tetrakis (2,6
dihydroxyphenyl)
21H,23H
porphine. 19. Tribenzocycline (TBC) and Tetrabenzocyclyne (QBC). 20. (Chloromethylene)bis[trimethylsilane] [Bis(trimethylsilyl)chloromethane]. 21. S,S
Chiraphos [(S,S)
(
)
(1,2
Dimethyl
1,2
ethandiyl) bis
(diphenylphosphine)]. 22. ²
Ketophosphines: Ligands of Catalytic Relevance. 23. N,N
Diisobutyl
2
(octylphenylphosphinyl) acetamide (CMPO). 24. Aresenic(III) Chloride. 25. Tris(trimethylsilyl)arsine and Lithium Bis(trimethylsilyl)arsenide. 26. Sterically Hindered Arene Chalcogenols. 27. Tris(trimethylsilyl)silyl Lithium Tris(tetrahydrofuran), Lithium Tris(trimethylsilyl)silyltellurolate Bis(tetrahydrofuran), and Tris(trimethylsilyl)silyltellurol. 28. Metal Complexes of the Lacunary Heteropolytungstates [B
±
PW9O34]9
and [±
P2W15O56]12
. 29. Polyoxoanion
Supported, Atomically Dispersed Iridium(I) and Rhodium(I). Chapter Three ORGANOMETALLIC COMPOUNDS. 30. One
Pot Synthesis of Dicarbonyltris(phosphine)iron(0) Complexes from Pentacarbonyliron. 31. Tricarbonylbis(phosphine)iron(0) Complexes. 32. (·5
Pentamethylcyclopentadienyl) (·5
cyclopentadienyl)iron [1,2,3,4,5
pentamethylferrocene]. 33. Pyrazolate
Bridged Ruthenium(I) Carbonyl Complexes. 34. Main Group
Transition Metal Carbonyl Complexes. 35. MnII4(1/44
O)[(CO)9Co3(1/43
CCO2)]6, M = Co, Zn. 36. 1,2,3,4
Tetramethyl
5
(trifluoromethyl)cyclopentadiene (Cp+ H) and Di
1/4
Chlorodichlorobis [·5
tetramethyl
(Trifluoromethyl)Cyclopentadienyl] Dirhodium(III). 37. Acetonitrile
Substituted Derivatives of Rh6(CO)16: Rh6(CO)16
x(NCMe)x(x = 1, 2). 38. Tetraphenylarsonium Carbonyltrichloroplatinate(II). Chapter Four TRANSITION METAL, LANTHANIDE, AND ACTINIDE COMPLEXES. 39. Dichlordioxobis(dimethyl sulphoxide)molybdenum(VI). 40. Metal
Catalyzed Synthesis of cis
[Re(CO)4,LI] [L = P(OMe)3, PMe2Ph, PPh3]. 41. Tris(l,2
bis(dimethylphosphino) ethane)rhenium(1) Trifluoromethanesulfonate, [Re(DMPE)3[CF3SO3]. 42. Tetrahalo Oxorhenate Anions. 43. A Rhenium(I) Dinitrogen Complex Containing a Tertiary Phosphine. 44. Bis(2,4
pentanedionato)iron(II) [Iron(II)Bis(acetylacetonate)]. 45. Synthesis of trans
Tetraammined.ichlorocobalt(III)Chloride. 46. [[3,3'
(1,3
Propanediyldiimino) bis[3
methy
2
butanone]
dioximatel(1
)
N,N',N'',N''']nickel(II), Nioyl. 47. Platinum Complexes Suitable as Precursors for Synthesis in Nonaqueous Solvents. 48. Tetrakis(propanenitrile)platinum(II)Trifluoromethanesulfonate as a Suitable Intermediate in Synthetic Pt(II) Chemistry. 49. [(1,2,5,6
·)
1,5
Cyclooctadiene]dimethylplatinum(II). 50. Bis(2,2,6,6
tetramethyl
3,5
heptanedionato)copper. 51. Lewis Base Adducts of 1,1,1,5,5,5
Hexafluoro
2,4
pentadionato
Copper(I) Compounds. 52. Copper(II) Alkoxides. 53. Pyrazolato Copper(I) Complexes. 54. Tris(2,2,6,6
tetramethyl
3,5
heptanedionato) Yttrium. 55. Lewis Base Adducts of Uranium Triiodide and Tris[bis(trimethylsilyl)amido] uranium. Contributor Index. Subject Index. Formula Index. Chemical Abstracts Service Registry Number Index.