Inorganic Syntheses, Volume 32 (eBook, PDF)

• Format: PDF

Produktbeschreibung

The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.

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Produktdetails

• Verlag: Wiley
• Erscheinungstermin: 22. September 2009
• Englisch
• ISBN-13: 9780470132982
• Artikelnr.: 38202170

Autorenporträt

Dr. Marcetta York Darensbourg is an American inorganic chemist. She is a Distinguished Professor of Chemistry at Texas A&M University. Her current work focuses on iron hydrogenases and iron nitrosyl complexes.

Inhaltsangabe

Chapter One LIGANDS FOR WATER
SOLUBILIZING ORGANOMETALLIC COMPOUNDS. 1. (Meta
Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1). 2. Syntheses of Water
Soluble Phosphines and Their Transition Metal Complexes. 3. Tris[Tris(Sodium m
sulfonatophenyl)phosphino] Palladium(0)
Enneahydrate. 4. Sulfonated Phosphines. 5. (S,S)
2,3
Bis[Di(m
Sodiumsulfonatophenyl)phosphino]butane
(chiraphosTS) and (S,S)
2,4
Bis[di(m
Sodiumsulfonatophenyl)
phosphinolpentane (BDPPTS). 6. 1,3,5
Triaza
7
phosphatricyclo[3.3.1.13,7]decane and Derivatives. Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS. 7. 2.2':6',2"
Terpyridine. 8. Poly(1
pyrazolyl)alkane Ligands. 9 . Tris[N
(3
tert
butyl)pyrazolyl]methane. 10. Tris[2
(1,4
Diisopropylimidazolyl)]phosphine. 11. Tris[(2
pyridyl)methyl]amine (TPA) and (+)
Bis[(2
pyridyl)
methyl]
l
(2
pyridyl)ethylamine (a
MeTPA). 12. C2
Symmetric 1,4
Diisopropyl
7
R
l,4,7
Triazacyclononanes. 13. N
(2
hydroxyethyl)
3,5
Dimethylpyrazole, a Dinuclear Copper Complex, and N
(2
p
Toluenesulfonylethyl)
3,5
dimethy
pyrazole. 14. N
(2
Mercaptoethyl)
3,5
dimethylpyrazole. 15. 1,5
Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N '
Bis(2
Mercaptoethyl)
1,5
Diazacyclooctanato]
nickel(II). 16. Polydentate Thiolate and Selenolate Ligands, RN(CH2,CH2,S(Se)
)2, and Their Dimeric and Mononuclear Ni(II) Complexes. 17. Poly[(methylthio)methyl]borates and Representative Metal Derivative. 18. Polyaza Binucleating Ligands: OBISTREN and OBISDIEN. 19. N,N'.bis(2
hydroxybyl.thylenediamine
N,N'
diacetic acid (HBED). 20. N
Tert
Alkyl
Anilides as Bulky Ancillary Ligands. 21. 1,2
Bis(Dichlorophosphino)
1,2
Dimethylhydrazine and Alkoxy/Aryloxy Derivatives. 22. Tris[(tert
butylamino)
dimethylsilyl]methylsilane and Its Precursors. Chapter Three TRANSITION METAL COMPLEXES AND PRECURSORS. 23. Facile Synthesis of Isomerically Pure. 24. cis
Bis(benzeneacetonitrile)dichloroplatinum(II) and trans
Bis(benzeneacetonitrile)dichloroplatinum(II). 25. Platinum(II) Complexes of Dimethyl Sulfide. 26. (2,2' :6',2"
Terpyridine) Methylplatinurn(II) Chloride and (l,l0
Phenanthroline)methylchloroplatinum(II). 27. (N,N
Chelate)(olefin)platinum(0) Complexes. 28. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes. 29. 2,4
Pentanedionatogold(I) Complexes and 2,4
Pentanedionatothallium. 30. Tetrakis(Pyridine)SiIver(2 + )Peroxydisulfate. 31. One
Pot Synthesis of Tetrahydronium Tris(4,4'
Dicarboxylato
2,2'
Bipyridine)ruthenium(II) Dihydrate. 32. Trichloro[2,2' :6,2"
Terpyridine]ruthenium(III) and Phosphine Ligand Derivatives. 33. Monomeric Tetrahydrofuran
Stabilized Molybdenum(III) Halides. 34. Facial Molybdenum(lI1) Triamine Complexes. 35. High
Valent Mono
(5
Pentamethylcyclopentadienyl)vanadium and Molybdenum Complexes. 36. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV). 37. Labile Copper(I) Chloride Complexes: Preparation and Handling. Chapter Four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS. 38. 7,8
Dicarbaundecaborane(13). 39. Borazine, Polyborazylene, B
Vinylborazine and Poly(B
Vinylborazine). 40. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P2W17 O61] 10
. 41. Bis(Triphenylphosphorany1idene)A mmonium µ
Carbonyl
1kC:2kC
Decacarbonyl
1k3C,2k3,3k4 C
µ
Hydrido
1k:2k
triangubTriruthenate(1
). 42. Dipotassium Undecacarbonyl Trimetallate(2
) Clusters, K2[M3(CO)11] (M = Ru, Os). 43. [PPN]2[Ru3(CO)11] and [PPN]2[OS3(CO)11 ], µ
Nitrido
Bis(Triphenylphosphorus) (1 +) Undecacarbonyltriruthenate (2 
) and Undecacarbonyltriosmate(2 
). 44. Platinum
Ruthenium Carbonyl Cluster Complexes. 45. Tri(µ
carbonyl)nonacarbonyltetrarhodiu. 46. High Nuclearity Hydridodecaruthenium Clusters. Chapter Five MAIN GROUP AND TRANSITION METAL HYDRLDES. 47. Dichlorodihydro(N,N,N',N,
Tetraethyl
1,2
ethanediamine
N,N')silicon. 48. Tricarbonyl(hydrido)[1,2
bis(diphenylphosphino)ethane]
manganese as Precursor to Labile Site Derivatives. 49. Pentahydridobis(tricyclohexylphosphine)iridium(V) and trihydridotris (triphenylphosphine)iridium(III). Chapter Six TITANIUM(1II) CHLORIDE. (A Correction to Inorganic Syntheses, Vol. 24, pp. 181 (1986). 50. An Active Form of Titanium(II1) Chloride. Contributor Index. Subject Index. Formula Index. Chemical Abstracts Service Registry Number Index.