Alexander G. Volkov, David W. Deamer

Liquid-Liquid InterfacesTheory and Methods (eBook, ePUB)

• Format: ePub

Produktbeschreibung

This book provides a modern account of research on liquid-liquid interfaces, with particular emphasis on charge transfer effects. It discusses their applications in biotechnology such as drug delivery, mineral extraction processes, and the manufacture of biosensors.

---

Dieser Download kann aus rechtlichen Gründen nur mit Rechnungsadresse in A, B, BG, CY, CZ, D, DK, EW, E, FIN, F, GR, HR, H, IRL, I, LT, L, LR, M, NL, PL, P, R, S, SLO, SK ausgeliefert werden.

Produktdetails

• Verlag: Taylor & Francis eBooks
• Seitenzahl: 448
• Erscheinungstermin: 26. November 2020
• Englisch
• ISBN-13: 9781000142167
• Artikelnr.: 60723259

Autorenporträt

Alexander G. Volkov, David W. Deamer

Inhaltsangabe

1. Equilibrium electric potential between two immiscible electrolyte solutions /T. Kakiuchi
I. Distribution potential
A. Phase
boundary potential
B. Distribution potential at ITIES
1. Nernst equation
2. Standard ion transfer potential
3. Calculation of distribution potential
4. Distribution potential in the presence of ion pair formation and complex formation reactions
5. Distribution of potential
6. Distribution potential in small systems
II. Polarizability of the liquid
liquid interface
III. Nonpolarized ITIES and reference potentials in organic phases
IV. Free energy of coupling of ion transfer and electron transfer
1. Mixed potential determined by electron transfer and ion transfer at ITIES
2. Partition of indifferent electrolyte ions
3. Relative strength of ion transfer and electron transfer
V. Conclusions
VI. References
2. Volta and surface potentials at liquid /liquid interfaces /Z. Koczorowski
I. Introduction
II. Electrified liquid /liquid interfaces and their electrical potentials
III. Volta potential and voltaic cells
IV. Voltaic cells with water /nonpolar liquid interfaces
V. Voltaic cells with immiscible electrolyte solution interface
VI. Experimental methods of investigation of voltaic cells
VII. Final remarks
VIII. References
3. Ion solvation /Y. Marcus
I. Introduction
II. The relevant properties of ions
III. The relevant properties of solvents
IV. Quantities describing ionic hydration
A. Thermodynamics of ion hydration
B. Methods of investigation
C. Other properties relevant to ion hydration
D. The data
E. Interpretation
V. Transfer of ions into non
aqueous solvents
A. Methods of investigation
B. The data
C. Interpretation
VI. Preferential ion solvation in mixed solvents
VII. References
4. Adsorption isotherms and the structure of oil /water interface /V. S. Markin and A. G. Volkov
I. Introduction
II. Surface solution