Long-lived Nuclear Spin Order (eBook, PDF)

Theory and Applications
Redaktion: Pileio, Giuseppe

• Format: PDF

Produktbeschreibung

The idea that a long-lived form of spin order, namely singlet order, can be prepared from nuclear spin magnetisation first emerged in 2004. The unusual properties of singlet order-its long lifetime and the fact that it is NMR silent but interconvertible into other forms of NMR active order-make it a 'smart tag' that can be used to store information for a long time or through distant space points. It is not unexpected then, that since its first appearance, this idea has caught the attention of research groups interested in exploiting this form of order in different fields of research spanning from biology to materials science and from hyperpolarisation to quantum computing.

This first book on the subject gives a thorough description of the various aspects that affect the development of the topic and details the interdisciplinary applications. The book starts with a section dedicated to the basic theories of long-lived spin order and then proceeds with a description of the state-of-the-art experimental techniques developed to manipulate singlet order. It then concludes by covering the generalization of the concept of singlet order by introducing and discussing other forms of long-lived spin order.

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Produktdetails

• Verlag: Royal Society of Chemistry
• Seitenzahl: 442
• Erscheinungstermin: 7. April 2020
• Englisch
• ISBN-13: 9781788019972
• Artikelnr.: 70074575

Inhaltsangabe

Long-lived States in Nuclear Magnetic Resonance: An Overview
Symmetry and Long-lived Spin Order
Relaxation Theory of Long-lived Spin Order
Design and Synthesis of Molecules Supporting Long-lived Spin Order
Manipulation of Singlet Order by Field-cycling
Manipulating Singlet Order by Chemical Reactions
Manipulating Spin Order by J-synchronised Echo Schemes
Manipulating Singlet Order by Spin-lock Induced Crossing
Manipulating Singlet Order with Adiabatic Pulses
Filters for Long-lived Spin Order
Converting Spin Order from Singlet to Heteronuclear Magnetisation
Long-lived States-based Determination of Ligand Affinity for a Target Protein
Applications of Singlet Order to the Study of Biomolecules and Molecular Interactions
Singlet-assisted Exchange NMR Spectroscopy
Singlet-assisted Diffusion NMR
Q-space Singlet NMR
Long-lived Singlet State: From NMR Quantum Information Perspectives
Singlet Spin Order Originating from Para-H2
Long-lived Spin Order Coupled to SABRE
Long-lived Coherences
Long-lived Spin Order in Methyl Groups
Long-lived Spin Order in CH2D Groups
Singlet Order in Heteronuclear Spin Systems