Materials for Carbon Capture (eBook, ePUB)

Redaktion: Jiang, De-En; Dai, Sheng; Mahurin, Shannon M.

• Format: ePub

Produktbeschreibung

Covers a wide range of advanced materials and technologies for CO2 capture As a frontier research area, carbon capture has been a major driving force behind many materials technologies. This book highlights the current state-of-the-art in materials for carbon capture, providing a comprehensive understanding of separations ranging from solid sorbents to liquid sorbents and membranes. Filled with diverse and unconventional topics throughout, it seeks to inspire students, as well as experts, to go beyond the novel materials highlighted and develop new materials with enhanced separations properties. Edited by leading authorities in the field, Materials for Carbon Capture offers in-depth chapters covering: CO2 Capture and Separation of Metal-Organic Frameworks; Porous Carbon Materials: Designed Synthesis and CO2 Capture; Porous Aromatic Frameworks for Carbon Dioxide Capture; and Virtual Screening of Materials for Carbon Capture. Other chapters look at Ultrathin Membranes for Gas Separation; Polymeric Membranes; Carbon Membranes for CO2 Separation; and Composite Materials for Carbon Captures. The book finishes with sections on Poly(amidoamine) Dendrimers for Carbon Capture and Ionic Liquids for Chemisorption of CO2 and Ionic Liquid-Based Membranes. * A comprehensive overview and survey of the present status of materials and technologies for carbon capture * Covers materials synthesis, gas separations, membrane fabrication, and CO2 removal to highlight recent progress in the materials and chemistry aspects of carbon capture * Allows the reader to better understand the challenges and opportunities in carbon capture * Edited by leading experts working on materials and membranes for carbon separation and capture Materials for Carbon Capture is an excellent book for advanced students of chemistry, materials science, chemical and energy engineering, and early career scientists who are interested in carbon capture. It will also be of great benefit to researchers in academia, national labs, research institutes, and industry working in the field of gas separations and carbon capture.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 376
• Erscheinungstermin: 4. Dezember 2019
• Englisch
• ISBN-13: 9781119091202
• Artikelnr.: 58421338

Autorenporträt

DE-EN JIANG, PHD, is an associate professor in the Department of Chemistry at the University of California, Riverside. He has over 15 years of experience in computer simulation of advanced materials for gas separations. SHANNON M. MAHURIN, PHD, is a Staff Scientist in the Chemical Sciences Division at Oak Ridge National Laboratory in Tennessee. He is an expert in the characterization and testing of novel materials, such gas graphene membranes, for separations. SHENG DAI, PHD, is a Corporate Fellow and Group Leader in the Chemical Sciences Division at Oak Ridge National Laboratory in Tennessee and Professor of Chemistry at the University of Tennessee. He has been working on materials synthesis and discovery for separations for over 20 years, winning the American Chemical Society National Award in Separations Science and Technology in 2019.

Inhaltsangabe

List of Contributors xi

Preface xv

Acknowledgments xvii

1 Introduction 1
De-en Jiang, Shannon M. Mahurin and Sheng Dai

References 3

2 CO2 Capture and Separation of Metal-Organic Frameworks 5
Xueying Ge and Shengqian Ma

2.1 Introduction 5

2.1.1 CO2 Capture Process 7

2.1.2 Introduction to MOFs for CO2 Capture and Separation 7

2.2 Evaluation Theory 8

2.2.1 Isosteric Heat of Adsorption (Qst) 8

2.2.1.1 The Virial Method 1 9

2.2.1.2 The Virial Method 2 9

2.2.1.3 The Langmuir-Freundlich Equation 9

2.2.2 Ideal Adsorbed Solution Theory (IAST) 10

2.3 CO2 Capture Ability in MOFs 10

2.3.1 Open Metal Site 10

2.3.2 Pore Size 11

2.3.3 Polar Functional Group 13

2.3.4 Incorporation 14

2.4 MOFs in CO2 Capture in Practice 14

2.4.1 Single-Component CO2 Capture Capacity 14

2.4.2 Binary CO2 Capture Capacity and Selectivity 16

2.4.3 Other Related Gas-Selective Adsorption 19

2.5 Membrane for CO2 Capture 19

2.5.1 Pure MOF Membrane for CO2 Capture 20

2.5.2 MOF-Based Mixed Matrix Membranes for CO2 Capture 20

2.6 Conclusion and Perspectives 21

Acknowledgments 21

References 21

3 Porous Carbon Materials 29
Xiang-Qian Zhang and An-Hui Lu

3.1 Introduction 29

3.2 Designed Synthesis of Polymer-Based Porous Carbons as CO2 Adsorbents 30

3.2.1 Hard-Template Method 31

3.2.1.1 Porous Carbons Replicated from Porous Silica 31

3.2.1.2 Porous Carbons Replicated from Crystalline Microporous Materials 33

3.2.1.3 Porous Carbons Replicated from Colloidal Crystals 35

3.2.1.4 Porous Carbons Replicated from MgO Nanoparticles 36

3.2.2 Soft-Template Method 38

3.2.2.1 Carbon Monolith 38

3.2.2.2 Carbon Films and Sheets 45

3.2.2.3 Carbon Spheres 48

3.2.3 Template-Free Synthesis 49

3.3 Porous Carbons Derived from Ionic Liquids for CO2 Capture 53

3.4 Porous Carbons Derived from Porous Organic Frameworks for CO2 Capture 56

3.5 Porous Carbons Derived from Sustainable Resources for CO2 Capture 61

3.5.1 Direct Pyrolysis and/or Activation 63

3.5.2 Sol-Gel Process and Hydrothermal Carbonization Method 64

3.6 Critical Design Principles of Porous Carbons for CO2 Capture 67

3.6.1 Pore Structures 67

3.6.2 Surface Chemistry 72

3.6.2.1 Nitrogen-Containing Precursors 72

3.6.2.2 High-Temperature Reaction and Transformation 76

3.6.2.3 Oxygen-Containing or Sulfur-Containing Functional Groups 77

3.6.3 Crystalline Degree of the Porous Carbon Framework 81

3.6.4 Functional Integration and Reinforcement of Porous Carbon 83

3.7 Summary and Perspective 88

References 89

4 Porous Aromatic Frameworks for Carbon Dioxide Capture 97
Teng Ben and Shilun Qiu

4.1 Introduction 97

4.2 Carbon Dioxide Capture of Porous Aromatic Frameworks 98

4.3 Strategies for Improving CO2 Uptake in Porous Aromatic Frameworks 98

4.3.1 Improving the Surface Area 98

4.3.2 Heteroatom Doping 99

4.3.3 Tailoring the Pore Size 102

4.3.4 Post Modification 103

4.4 Conclusion and Perspectives 114

References 114

5 Virtual Screening of Materials for Carbon Capture 117
Aman Jain, Ravichandar Babarao and Aaron W. Thornton

5.1 Introduction 118

5.2 Computational Methods 118

5.2.1 Monte Carlo-Based Simulations 118

5.2