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Metal Nano 3D Superlattices Unique view on producing metal nano 3D superlattices by differing their morphologies, crystalline structures, chemical, and physical properties After presenting an overview on the various factors involved in producing metal 3D superlattices called supracrystals by differing their morphologies, crystalline structures, chemical, physical, and intrinsic properties, Metal Nano 3D Superlattices: Synthesis, Properties, and Applications reveals the existence of new materials with unexpected properties . Readers will gain insight into the various approaches on the…mehr
Unique view on producing metal nano 3D superlattices by differing their morphologies, crystalline structures, chemical, and physical properties
After presenting an overview on the various factors involved in producing metal 3D superlattices called supracrystals by differing their morphologies, crystalline structures, chemical, physical, and intrinsic properties, Metal Nano 3D Superlattices: Synthesis, Properties, and Applications reveals the existence of new materials with unexpected properties. Readers will gain insight into the various approaches on the production and on the specific properties of nanocrystals self-assembled in 3D superlattices also called colloidal crystals, supra or super crystals. These properties open up new avenues of research and potentially aiding in major progress. Overall, the work reviews the progress of and gives perspective on assembled nanocrystals, with a concentrated focus on self-assemblies of metal nanocrystals.
Sample topics covered by the highly qualified and internationally awarded author include:
Syntheses of nanocrystals with low size distribution.
The wide variety of self-assembled nanocrystals in 3D superlattices strongly depends on an impressive number of parameters.
The intrinsic chemical and physical properties of 3D superlattices of nanocrystals opens the way to the discovery of unexpected properties. This concerns growth processes, coherent breathing of in 3D superlattices, electron transport through thick assemblies, etc.
A strong analogy between atomic crystals and 3D superlattices of nanocrystals emerge: incompressible nanocrystals and coating agents act as mechanical springs holding together the nanocrystals and replace respectively, in atomic crystals, atoms and atomic bonds.
The intrinsic chemical and physical properties of nanocrystals and their assemblies depend on their crystalline structures called nanocrystallinity.
Collective properties due to dipolar interactions between nanocrystals are pointed out.
Water soluble suprastructures act as efficient universal nanoheaters. In addition, reconstruction near the cytoplasmic membrane in tumor cells of nanocrystal self-assemblies takes place opening various biomedical applications.
The physical (optical, magnetic, electronic, vibrational) properties of isolated nanocrystals remain present in addition to the intrinsic and collective properties. This allows to benefit from the unique properties of nanocrystals while avoiding their potential size-related risks in future applications.
Metal Nano 3D Superlattices offers a deep dive into their synthesis, chemical and physical properties, and applications and is an essential resource for inorganic chemists, materials scientists, physical chemists, surface chemists, and medicinal chemists conducting research related to or involved in the practical application of the topics covered within.
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Autorenporträt
Marie-Paule Pileni is a Distinguished Professor at University P&M CurieSorbonne University and Senior Researcher in Nuclear and Environmental Center, France. She is a member (1999- at present) and chair (2004-2010) of Institut Universitaire de France, IUF, which favors the development of high-quality research and interdisciplinary projects among French universities. Over her career, she has received significant awards and prizes, such as the Langmuir award of the American Chemical Society, the lecture award of the Japanese Chemical Society, Emila Valori Award, French Academy of Sciences, Descartes-Huygens Prize, Royal Netherlands Academy of Arts and Sciences, Doctor Honoris Causa, Chalmers University, Göteberg, Sweden and the research award of the Alexander von Humboldt Foundation in Germany.
Inhaltsangabe
SYNTHESES OF METAL NANOCRYSTALS Nanocrystal Growth Processes and Control of Size and Distribution Crystalline Structure of Metal Nanocrystals Various Techniques Used to Produce Metal Nanocrystals and Control their Sizes and Distribution Influence of the Coating Agents on the Size Control N-Heterocyclic Carbene Ligands for Au Nanocrystals Stabilization Conclusion
INFLUENCE OF THE NANOPARTICLE CRYSTALLINE STRUCTURES CALLED NANOCRYSTALLINITIES ON VARIOUS PROPERTIES Nano-Kinkerdall Local Surface Plasmon Resonance, LSPR Acoustic Vibrational Modes 3D Superlattice Growth Processes Mechanical Properties Conclusions
AU 3D SUPERLATTICES PRODUCED BY SOLVENT EVAPORATION PROCESS 3D Superlattice Morphology of Au Nanocrystal Coated with Thiol Derivatives Interparticle Distance of Nanocrystals in 3D Superlattices Au 3D Superlattices Coated with N-Heterocyclic Carbene Conclusions
3D SUPERLATTICE GROWTH A THERMODYNAMIC EQUILIBRIUM Homogeneous and Heterogeneous 3D Superlattice Growth Processes Submillimeter Size Single 3D Superlattices of 5nm Au Nanocrystals Conclusions
AG 3D SUPERLATTICES Control of the Crystalline Structure of Ag 3D Superlattices Optical Properties Stability Conclusions
MESOSTRUCTURE OF MAGNETIC NANOCRYSTALS Magnetic Nanocrystals Dispersed in Solution: Ferrofluids Mesostructures of Maghemite Nanocrystals Mesostructures of Cobalt Nanocrystals Conclusions
BINARY 3D SUPERLATTICES Structure of 3D Superlattices Predicted by the Hard Sphere Model Limitation of the Hard Sphere Models Solvent-Mediated Crystallization of Nanocrystal 3D Assemblies of Silver Nanocrystals: Unexpected Superlattice Ripening Collective Properties Involved in Self-Assemblies of Binary Systems Conclusions
ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: CRYSTALLINE STRUCTURE Atomic Crystals, Shaped 3D Superlattices and Minerals Negative 3D Superlattices Vicinal Surfaces Quasi 3D Superlattices Conclusions
ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: PHYSICAL PROPERTIES Magnetic Properties Longitudinal Acoustic Phonons Breathing Modes Conclusions
3D SUPERLATTICE STABILITY Influence of Temperature Edging Process Solvent-Mediated Crystallization of Nanocrystal 3D Assemblies Conclusions
INTRINSIC PROPERTIES RELATED DUE TO THE SELF-ASSEMBLIES OF NANOCRYSTALS Epitaxial Crystal Growth as a Result of the Manocrystal Ordering Unexpected Electronic Properties of Micrometer-Thick 3D Superlattices of Au Nanocrystals Collective Magnetic Properties of Co Nanocrystals Self-Assembled in 3D Superlattices Super-Spin Glass Behavior of FCC 3D Superlattices. Alignment of Magnetic Nanocrystals Co 3D Superlattice Collective Properties of Amorphous Nanoparticles Conclusion
MECHANICAL PROPERTIES OF 3D SUPERLATTICES Measurements of Mechanical Properties using Atomic Force Microscope, AFM 3D Superlattices Produced under Thermodynamic Processes 3D Superlattices Produced through Heteregeneous 3D Superlattice Growth Process Do the Apparent Discrepancies of the Young Moduli Produced with a Large Variety of Metallic Nanocrystals Self-Assembled in fcc Structures Remain Valid or not? Mesoscopic Assemblies of Co Nanocrystals Differing by their Size Distribution: Mechanical Intrinsic Properties. Conclusions
CRACKS IN NANOCRYSTAL FILM Cracks of Nanocrystal Films Cracks in Nature Conclusions
WATER DISPERSIVE HYDROPHOBIC SUPRASTRUCTURES: SPECIFIC PROPERTIES Au and Co "Clustered" Structures. Colloidosomes and Supraballs Nanoheaters Conclusion
NANOCRYSTAL SELF-ASSEMBLY IN CELLS Ferrite Colloidosomes and Supraballs Intracellular Fate of Hydrophobic Nanocrystal Self-Assemblies in Tumor Cell
SYNTHESES OF METAL NANOCRYSTALS Nanocrystal Growth Processes and Control of Size and Distribution Crystalline Structure of Metal Nanocrystals Various Techniques Used to Produce Metal Nanocrystals and Control their Sizes and Distribution Influence of the Coating Agents on the Size Control N-Heterocyclic Carbene Ligands for Au Nanocrystals Stabilization Conclusion
INFLUENCE OF THE NANOPARTICLE CRYSTALLINE STRUCTURES CALLED NANOCRYSTALLINITIES ON VARIOUS PROPERTIES Nano-Kinkerdall Local Surface Plasmon Resonance, LSPR Acoustic Vibrational Modes 3D Superlattice Growth Processes Mechanical Properties Conclusions
AU 3D SUPERLATTICES PRODUCED BY SOLVENT EVAPORATION PROCESS 3D Superlattice Morphology of Au Nanocrystal Coated with Thiol Derivatives Interparticle Distance of Nanocrystals in 3D Superlattices Au 3D Superlattices Coated with N-Heterocyclic Carbene Conclusions
3D SUPERLATTICE GROWTH A THERMODYNAMIC EQUILIBRIUM Homogeneous and Heterogeneous 3D Superlattice Growth Processes Submillimeter Size Single 3D Superlattices of 5nm Au Nanocrystals Conclusions
AG 3D SUPERLATTICES Control of the Crystalline Structure of Ag 3D Superlattices Optical Properties Stability Conclusions
MESOSTRUCTURE OF MAGNETIC NANOCRYSTALS Magnetic Nanocrystals Dispersed in Solution: Ferrofluids Mesostructures of Maghemite Nanocrystals Mesostructures of Cobalt Nanocrystals Conclusions
BINARY 3D SUPERLATTICES Structure of 3D Superlattices Predicted by the Hard Sphere Model Limitation of the Hard Sphere Models Solvent-Mediated Crystallization of Nanocrystal 3D Assemblies of Silver Nanocrystals: Unexpected Superlattice Ripening Collective Properties Involved in Self-Assemblies of Binary Systems Conclusions
ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: CRYSTALLINE STRUCTURE Atomic Crystals, Shaped 3D Superlattices and Minerals Negative 3D Superlattices Vicinal Surfaces Quasi 3D Superlattices Conclusions
ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: PHYSICAL PROPERTIES Magnetic Properties Longitudinal Acoustic Phonons Breathing Modes Conclusions
3D SUPERLATTICE STABILITY Influence of Temperature Edging Process Solvent-Mediated Crystallization of Nanocrystal 3D Assemblies Conclusions
INTRINSIC PROPERTIES RELATED DUE TO THE SELF-ASSEMBLIES OF NANOCRYSTALS Epitaxial Crystal Growth as a Result of the Manocrystal Ordering Unexpected Electronic Properties of Micrometer-Thick 3D Superlattices of Au Nanocrystals Collective Magnetic Properties of Co Nanocrystals Self-Assembled in 3D Superlattices Super-Spin Glass Behavior of FCC 3D Superlattices. Alignment of Magnetic Nanocrystals Co 3D Superlattice Collective Properties of Amorphous Nanoparticles Conclusion
MECHANICAL PROPERTIES OF 3D SUPERLATTICES Measurements of Mechanical Properties using Atomic Force Microscope, AFM 3D Superlattices Produced under Thermodynamic Processes 3D Superlattices Produced through Heteregeneous 3D Superlattice Growth Process Do the Apparent Discrepancies of the Young Moduli Produced with a Large Variety of Metallic Nanocrystals Self-Assembled in fcc Structures Remain Valid or not? Mesoscopic Assemblies of Co Nanocrystals Differing by their Size Distribution: Mechanical Intrinsic Properties. Conclusions
CRACKS IN NANOCRYSTAL FILM Cracks of Nanocrystal Films Cracks in Nature Conclusions
WATER DISPERSIVE HYDROPHOBIC SUPRASTRUCTURES: SPECIFIC PROPERTIES Au and Co "Clustered" Structures. Colloidosomes and Supraballs Nanoheaters Conclusion
NANOCRYSTAL SELF-ASSEMBLY IN CELLS Ferrite Colloidosomes and Supraballs Intracellular Fate of Hydrophobic Nanocrystal Self-Assemblies in Tumor Cell
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