Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations (eBook, PDF)

Redaktion: Meunier, B.

• Format: PDF

Produktbeschreibung

This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world's renowned experts.

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Produktdetails

• Verlag: Springer Berlin Heidelberg
• Seitenzahl: 323
• Erscheinungstermin: 4. September 2003
• Englisch
• ISBN-13: 9783540465928
• Artikelnr.: 53102603

Inhaltsangabe

Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerism with Water-Soluble Metalloporphyrins.- Nucleophilicity of Iron-Peroxo Porphyrin Complexes.- Characterization of High-Valent Oxo-Metalloporphyrins.- Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase.- Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution.- Characterization and Properties of Non-Heme Iron Peroxo Complexes.- Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases.- Rhenium-Oxo and Rhenium-Peroxo Complexes in Catalytic Oxidations.- Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes.- Nature of Activated Bleomycin.