Micro-Mesoporous Metallosilicates (eBook, ePUB)

Synthesis, Characterization, and Catalytic Applications
Redaktion: Wu, Peng; Xu, Hao

• Format: ePub

Produktbeschreibung

Micro-Mesoporous Metallosilicates

Up-to-date and in-depth text bridging the technology gap between fundamental research and industry-scale applications of porous materials for catalysis

Micro-Mesoporous Metallosilicates: Synthesis, Characterization, and Catalytic Applications comprehensively introduces the chemistry and catalytic technologies of metallosilicates, an important family of microporous crystalline zeolite and heteroatom-containing mesoporous materials, with a primary focus on design synthesis, characterization, theoretical studies, and catalytic applications of titanosilicates, tin-silicates, germanosilicates and Ti-mesosilica, and more.

The text covers recent advances in the synthesis of titanosilicates, including hydrothermal synthesis, dry-gel conversion, fluoride-assisted synthesis, and post-synthesis methods, along with the synthesis of metallosilicates with two-dimensional lamellar structures and their structural modifications as well as applications in selective oxidation reactions.

The text also discusses synthesis of germanosilicates with specially designed organic structure-directing agents, synthesis and catalytic applications of heteroatom-containing mesoporous silica, and dendritic mesoporous silica nanoparticles with unique wrinkled center-radial structures.

Overall, every important porous metallosilicate and its synthesis, characterization, pore engineering, catalytic application, and industrial technique and process are covered.

Specific sample topics discussed in Micro-Mesoporous Metallosilicates include:

• Chemical post-modifications of titanosilicates, in terms of the effects on transfer, adsorption/desorption, and surface reactions
• X-Ray based techniques, ultraviolet-visible-near infrared spectroscopy, Raman spectroscopy, and solid-state NMR spectroscopy
• Theoretical calculation as an effective tool and supplement to understand the catalytic active center, structural character, and Brønsted/Lewis acidity
• Titanosilicates in the liquid-phase epoxidation reaction of propylene and propylene chloride to corresponding epoxides
• Effects of particle sizes, oxidation state, and location sites of Au nanoparticles, and epoxidation performance of Ti-containing materials

Delivering cutting-edge research and bridging the technology gap between fundamental research and industrial applications, Micro-Mesoporous Metallosilicates is a valuable resource for chemists, materials scientists, chemical engineers, and experienced researchers in related fields.

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Produktdetails

• Verlag: Wiley-VCH
• Seitenzahl: 886
• Erscheinungstermin: 5. März 2024
• Englisch
• ISBN-13: 9783527839377
• Artikelnr.: 70207242

Autorenporträt

Peng Wu, PhD, is a Professor in School of Chemistry and Molecular Engineering at East China Normal University. His research interests focus on design, functionalization, and catalytic applications of novel zeolites. Hao Xu, PhD, is a Professor in School of Chemistry and Molecular Engineering at East China Normal University. Her research interests focus on the design and synthesis of novel zeolite catalysts via post modifications

Inhaltsangabe

Chapter 1 Synthesis of Titanosilicates
Chapter 2 Layered Heteroatom-Containing Zeolites
Chapter 3 Synthesis and Catalytic Applications of Sn- and Zr-Zeolites
Chapter 4: Synthesis of Germanosilicates
Chapter 5 Structural Modifications on Germanosilicates
Chapter 6 Heteroatom-Containing Dendritic Mesoporous Silica Nanoparticles
Chapter 7 Chemical Post-Modifications of Titanosilicates
Chapter 8 Spectroscopic Characterization of Heteroatom-Containing Zeolites
Chapter 9 Theoretical Calculations of Heteroatom Substituted Zeolites
Chapter 10 Catalytic Ammoximation of Ketones or Aldehydes Using Titanosilicates
Chapter 11 Titanosilicate-Based Alkene Epoxidation Catalysis
Chapter 12 Propylene Epoxidation with Cumene Hydroperoxide/Titanosilicates
Chapter 13 Hydroxylation of Benzene and Phenol on Zeolite Catalysts
Chapter 14 Bifunctional Titanosilicate Systems for the Gas-Phase Catalytic Propylene Epoxidation with Hydrogen and Oxygen
Chapter 15 Zeolites Containing Heteroatoms/Metal Nanoparticles for Catalytic Conversion of Light Alkanes
Chapter 16 Design and Applications of Single-Site Photocatalysts Using Metallosilicates