Multiple Electron Resonance Spectroscopy (eBook, PDF)

Redaktion: Dorio, M. M.

• Format: PDF

Produktbeschreibung

Abragam and Bleaney/H) and others.o6---19) Basically, this volume deals with those spectroscopic techniques that use EPR as a detection method. Chapters 2 through 5 cover the experimental and theoretical aspects of multiple resonance spectroscopy. Chapters 6 through 12 are systems-oriented and deal with the multiple resonance techniques applied to crystals, glasses, bioproteins, polymers, and triplets. The concepts of the first five chapters illustrate the strength of MERS to solve a broad range of problems. Chapters 13 and 14 are rather detailed introductions to two of the latest new applications: TRIPLE resonance and optical perturbations in EPR. The latter is to be distinguished from the OMDR (optical magnetic double resonance) techniques, in which the optical system is the detection method. References 1. E. J. Zavoisky, J. Phys. U.S.S.R. 9, 211 (1945). 2. J. S. Hyde, Ann. Rev. Phys. Chern. 25, 407 (1974). 3. N. M. Atherton, Electron Spin Resonance (Specialist Periodical Reports, The Chemical Society, London) 1, 32 (1972); 2, 35 (1974). 4. J. H. Freed, Ann. Rev. Phys. Chern. 23, 265 (1972). 5. J. E. Wertz and J. R. Bolton, Electron Spin Resonance, Elementary Theory and Practical Applications, p. xii, McGraw-Hill Book Co., New York (1972). 6. G. Feher, Phys. Rev. 103,834 (1956). 7. P. P. Sorokin, G. J. Lasher, and I. L. Gelles, Phys. Rev. 118, 939 (1960). 8. N. Bloembergen, S. Shapiro, P. S. Pershan, and J. O. Artman, Phys. Rev. 114,445 (1959).

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Produktdetails

• Verlag: Springer US
• Seitenzahl: 512
• Erscheinungstermin: 6. Dezember 2012
• Englisch
• ISBN-13: 9781468434415
• Artikelnr.: 43994480

Inhaltsangabe

1. Multiple Electron Resonance Spectroscopy: An Introduction.- 2. Instrumentation and Experimental Methods in Double Resonance.- 1. endor.- 2. eldor.- References.- 3. Theory of Multiple Resonance and esr Saturation in Liquids and Related Media.- 1. Introduction to Saturation.- 2. eldor.- 3. endor.- 4. Transition Probabilities.- 5. Heisenberg Spin Exchange and Chemical Exchange.- 6. General Approach.- 7. Average endor and eldor.- 8. Saturation and Double Resonance in the Slow-Tumbling Region.- Appendix. General Properties of the Transition Probability Matrix W.- References.- 4. Solution endor.- 1. Introduction.- 2. Analysis of endor Frequencies.- 3. Analysis of endor Intensities and Linewidths.- 4. Conclusion.- References.- 5. Modulation Effects in Multiple Electron Resonance Spectroscopy.- 1. Introduction.- 2. Theory.- 3. Examples of Zeeman Modulation Effects.- References.- 6. Disordered Matrices.- 1. endor in Disordered Matrices.- 2. eldor in Disordered Matrices.- References.- 7. Crystalline Systems.- 1. Introduction.- 2. Determination of Anisotropic Hyperfine Splitting Tensors.- 3. Unique Role Played by endor.- 4. Unique Role Played by eldor.- 5. Complementary Role Played by endor and eldor.- References.- 8. endor on Hemes and Hemoproteins.- 1. Introduction.- 2. endor Technique Applied to Heme Systems.- 3. endor Measurements on Hemes and Hemoproteins.- 4. Summary.- References.- 9. endor and eldor on Iron-Sulfur Proteins.- 1. Introduction.- 2. Theory.- 3. Instrumentation.- 4. Iron-Sulfur Proteins-endor and eldor.- 5. Summary.- References.- 10. Radiation Biophysics.- 1. Introduction.- 2. Indirect Effects.- 3. Nucleic Acid Constituents.- 4. Protein Constituents.- 5. Conclusion.- References.- 11. Polymer Studies.- 1. Introduction.- 2. Irradiated Polymers.- 3. SpinProbes within Polymeric Matrices.- 4. Spin-Labeled Polymers.- 5. Concluding Remarks.- References.- 12. endor of Triplet State Systems in Solids.- 1. Introduction.- 2. Nature of Triplet States of Organic Molecules.- 3. Spin Hamiltonian.- 4. Examples of Systems Studied.- 5. Summary.- References.- 13. Principles and Applications of Optical Perturbation-Electron Paramagnetic Resonance (opepr).- 1. Introduction.- 2. Experimental Technique.- 3. Theoretical Treatment of opepr Experiments.- 4. Examples and Applications.- 5. Concluding Remarks.- References.- 14. Electron-Nuclear-Nuclear triple Resonance of Radicals in Solutions.- 1. Introduction.- 2. Experimental Aspects.- 3. Theoretical Aspects.- 4. Comparison between Theory and Experiment.- 5. Applications of triple-in-Solution.- 6. Conclusion.- References.