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Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to…mehr
Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations.
Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors' first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book's nineteen chapters offer a broad perspective, covering:
Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions
Nanocatalysis for various organic transformations in fine chemical synthesis
Nanocatalysis for oxidation, hydrogenation, and other related reactions
Nanomaterial-based photocatalysis and biocatalysis
Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels
Nanocatalysts and nano-biocatalysts in the chemical industry
Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance.
Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.
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Autorenporträt
VIVEK POLSHETTIWAR, PhD, is Reader heading the Nanocatalysis Laboratory in the Department of Chemical Sciences at the Tata Institute of Fundamental Research. His research examines advanced nanomaterials, catalysis, and green chemistry. TEWODROS ASEFA, PhD, is Associate Professor in the Department of Chemistry and Chemical Biology and the Department of Chemical and Biochemical Engineering at Rutgers University. Dr. Asefa is also Interim Director of the Rutgers Catalysis Research Center.
Inhaltsangabe
Foreword vii Graham Hutchings Preface ix List of Contributors xiii 1 Introduction to Nanocatalysis 1 Vivek Polshettiwar and Tewodros Asefa 2 Nanocatalysts for the Heck Coupling Reactions 11 T. Asefa, A. V. Biradar, S. Das, K. K. Sharma, and R. Silva 3 Nanocatalysts for the Suzuki Coupling Reactions 51 Liane M. Rossi, Natalia J. S. Costa, Jones Limberger, and Adriano L. Monteiro 4 Sonogashira Reactions Using Nanocatalysts 89 Rafael Chinchilla and Carmen Nájera 5 Nanocatalysts for Hiyama, Stille, Kumada, and Negishi C-c Coupling Reactions 133 Abhinandan Banerjee and Robert W. J. Scott 6 Aryl Carbon-heteroatom Coupling Reactions Using Nanometal Catalyst 189 Brindaban C. Ranu, Debasree Saha, Debasish Kundu, and Nirmalya Mukherjee 7 Nanostructured Catalysts for the Aldol, Knoevenagel, and Henry Reactions 221 T. Asefa, A. V. Biradar, S. Das, and R. Silva 8 Nanocatalysts for Rearrangement Reactions 251 Joaquín García-Álvarez, Sergio E. García-Garrido, and Victorio Cadierno 9 Oxidation of Alcohols Using Nanocatalysts 287 Takato Mitsudome and Kiyotomi Kaneda 10 Tuning the Morphology of Metal Oxides for Catalytic Applications 333 Yong Li and Wenjie Shen 11 Nanocatalysts for Hydrogenation Reactions 405 Radha Narayanan 12 Hydrogenolysis Reactions Using Nanocatalysts 443 Aziz Fihri and Vivek Polshettiwar 13 Nanomaterial-based Photocatalysts 469 Biswajit Mishra and Deepa Khushalani 14 Nanocatalysts for Water Splitting 495 Xu Zong, Gaoqing Lu, and Lianzhou Wang 15 Properties of Nanocatalytic Materials for Hydrogen Production From Renewable Resources 561 Zhong He and Xianqin Wang 16 Nanocatalysts for Biofuels 595 Vitaliy Budarin, Peter S. Shuttleworth, Brigid Lanigan, and James H. Clark 17 Nanomaterial-based Biocatalyst 615 Jin Hyung Lee, Soo Youn Lee, Zhi-Kang Xu, and Jeong Ho Chang 18 Role of Nanocatalysis in Chemical Industry 643 Anirban Ghosh, K. S. Nagabhushana, Debabrata Rautaray, and Rajiv Kumar 19 Nanocatalysis: Activation of Small Molecules And Conversion Into Useful Feedstock 679 Suresh Babu Kalidindi and Balaji R. Jagirdar Index 713
Foreword vii Graham Hutchings Preface ix List of Contributors xiii 1 Introduction to Nanocatalysis 1 Vivek Polshettiwar and Tewodros Asefa 2 Nanocatalysts for the Heck Coupling Reactions 11 T. Asefa, A. V. Biradar, S. Das, K. K. Sharma, and R. Silva 3 Nanocatalysts for the Suzuki Coupling Reactions 51 Liane M. Rossi, Natalia J. S. Costa, Jones Limberger, and Adriano L. Monteiro 4 Sonogashira Reactions Using Nanocatalysts 89 Rafael Chinchilla and Carmen Nájera 5 Nanocatalysts for Hiyama, Stille, Kumada, and Negishi C-c Coupling Reactions 133 Abhinandan Banerjee and Robert W. J. Scott 6 Aryl Carbon-heteroatom Coupling Reactions Using Nanometal Catalyst 189 Brindaban C. Ranu, Debasree Saha, Debasish Kundu, and Nirmalya Mukherjee 7 Nanostructured Catalysts for the Aldol, Knoevenagel, and Henry Reactions 221 T. Asefa, A. V. Biradar, S. Das, and R. Silva 8 Nanocatalysts for Rearrangement Reactions 251 Joaquín García-Álvarez, Sergio E. García-Garrido, and Victorio Cadierno 9 Oxidation of Alcohols Using Nanocatalysts 287 Takato Mitsudome and Kiyotomi Kaneda 10 Tuning the Morphology of Metal Oxides for Catalytic Applications 333 Yong Li and Wenjie Shen 11 Nanocatalysts for Hydrogenation Reactions 405 Radha Narayanan 12 Hydrogenolysis Reactions Using Nanocatalysts 443 Aziz Fihri and Vivek Polshettiwar 13 Nanomaterial-based Photocatalysts 469 Biswajit Mishra and Deepa Khushalani 14 Nanocatalysts for Water Splitting 495 Xu Zong, Gaoqing Lu, and Lianzhou Wang 15 Properties of Nanocatalytic Materials for Hydrogen Production From Renewable Resources 561 Zhong He and Xianqin Wang 16 Nanocatalysts for Biofuels 595 Vitaliy Budarin, Peter S. Shuttleworth, Brigid Lanigan, and James H. Clark 17 Nanomaterial-based Biocatalyst 615 Jin Hyung Lee, Soo Youn Lee, Zhi-Kang Xu, and Jeong Ho Chang 18 Role of Nanocatalysis in Chemical Industry 643 Anirban Ghosh, K. S. Nagabhushana, Debabrata Rautaray, and Rajiv Kumar 19 Nanocatalysis: Activation of Small Molecules And Conversion Into Useful Feedstock 679 Suresh Babu Kalidindi and Balaji R. Jagirdar Index 713
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