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An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts…mehr
An accessible and step-by-step exploration of organic reaction mechanisms
In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions.
Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization.
Along with sections covering aromaticity and the chemistry of intermediates, the book includes:
A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects
Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions
Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination
In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes
Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms.
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Autorenporträt
Metin Balci is Professor Emeritus of the Middle East Technical University in Ankara. He received his Ph.D. degree in 1976 from the University of Cologne, where he worked with Professor Emanuel Vogel. He did post-doctoral work with Professors Harald Günther (Siegen, Germany), Waldemar Adam (Puerto Rico) and W. M. Jones (Florida). In 1980 he joined the Department of Chemistry at the Atatürk University and he has been a full professor there since 1987. In 1997 he moved to the Middle East Technical University in Ankara upon reputation. Metin Balci has received several prices: In 1983 "Junior Research Prize" and "Scientific Prize" in 1989 from the Scientific and Technical Research Council of Turkey and the Best Teacher Award in 2000, 2003, 2004 at the Middle East Technical University (METU). Furthermore, he received METU "Academic Achievement Award", (2000-2015). His main research interest include synthesis of cyclitols, endoperoxides, cyclic strained compounds, bromine chemistry, and heterocyclic compounds. He has published 280 scientific papers and he retired in 2015.
Inhaltsangabe
BASIC CONCEPTS Covalent Bonding and Hybridization Electrophiles and Nucleophiles Inductive and Mesomeric Effects Formal Charge And Oxidation Number Acids And Bases Reaction Kinetics And Energy Diagrams
NUCLEOPHILIC SUBSTITUTION REACTIONS Unimolecular Substitution Reactions SN1 Stereochemistry in SN1 Reactions Optical Activity Bimolecular Substitution Reactions SN2 Stereochemistry of SN2 Reactions Nucleophilic Substitution On Allylic Systems: Allylic Rearrangement Internal Nucleophilic Substitution Reaction SNi Neighboring Group Participation in Nucleophilic Substitution Reactions Ambident Nucleophiles Various Nucleophilic Substitution Reactions
ADDITION REACTIONS Halogen Addition To Double Bonds: Halogenation Addition of Hydrogen Halides to Double Bonds: Markovnikov?s Rule Anti-Markovnikov Addition of Hydrogen Halides to Alkenes Addition of Water to Alkenes Oxymercuration and Demercuration Hydroboration of Alkenes: Anti-Markovnikov Hydration Epoxidation of the Alkenes Vicinal cis-Dihydroxylation Dihydroxylation via PIFA Enzymatic Dihydroxylation Ozonolysis: Oxidative Cleavage of Alkenes Reduction of Alkenes Addition to Conjugated Dienes
CARBONYL COMPOUNDS AND THEIR REACTIONS Structure-Reactivity Relationships Reactions of Carbonyl Compounds Carbonyl Addition Reactions Umpolung: Polarity Inversion of Aldehyde Carbonyl Group Reactions of Aldehydes and Ketones with Amines Reduction of Carbonyl Groups Reaction of Carbonyl Groups with Organometallic Compounds Reaction of Carbonyl Groups with Ylides Phosphonium Ylides and Wittig Reaction Reactivity of alpha-Carbon Atom Keto-Enol Tautomerism Proton-Deuterium Exchange alpha-Halogenation of Ketones and Aldehydes: Haloform Reaction Hell-Volhard-Zelinsky Reaction alpha-Alkylation of Carbonyl Compounds Enolates Derived from 1,3-Dicarbonyl Compounds Condensation Reactions of Carbonyl Compounds Typical Reactions of Acids and Esters Transesterification
AROMATIC COMPOUNDS Structure of Benzene Aromatic, Antiaromatic, and Nonaromatic Compounds Determination of the Molecular orbitals of Aromatic Compounds What are the criteria for aromaticity? How does one quantify aromaticity? Homoaromaticity Möbius Aromaticity Aromatic Ions Annulenes Aromaticity in Fused Systems Aromaticity in Heterocyclic Compounds Electrophilic Aromatic Substitution: Chemistry of Benzene Reactivity of Monosubstituted Benzene Derivatives Directing Effects of Substituents: Activating Groups Electrophilic Aromatic Substitution on Disubstituted Benzenes Functionalization of the Side Chain Substituents of Benzene Nucleophilic Aromatic Substitution Reactions Polycyclic Aromatic Compounds Benzenoid Aromatic Compounds
REACTIVE INTERMEDIATES Carbocations Carbanions Carbenes Nitrenes Radicals Singlet Oxygen
PERICYCLIC REACTIONS Woodward Hoffmann Rules Frontier Orbitals Electrocyclic Reactions Application of Woodward Hoffmann Rules Correlation Diagrams Cycloaddition Reactions Secondary Orbital Interaction Orbital Coefficients Sigmatropic Reactions Cope and Claisen Rearrangement
BASIC CONCEPTS Covalent Bonding and Hybridization Electrophiles and Nucleophiles Inductive and Mesomeric Effects Formal Charge And Oxidation Number Acids And Bases Reaction Kinetics And Energy Diagrams
NUCLEOPHILIC SUBSTITUTION REACTIONS Unimolecular Substitution Reactions SN1 Stereochemistry in SN1 Reactions Optical Activity Bimolecular Substitution Reactions SN2 Stereochemistry of SN2 Reactions Nucleophilic Substitution On Allylic Systems: Allylic Rearrangement Internal Nucleophilic Substitution Reaction SNi Neighboring Group Participation in Nucleophilic Substitution Reactions Ambident Nucleophiles Various Nucleophilic Substitution Reactions
ADDITION REACTIONS Halogen Addition To Double Bonds: Halogenation Addition of Hydrogen Halides to Double Bonds: Markovnikov?s Rule Anti-Markovnikov Addition of Hydrogen Halides to Alkenes Addition of Water to Alkenes Oxymercuration and Demercuration Hydroboration of Alkenes: Anti-Markovnikov Hydration Epoxidation of the Alkenes Vicinal cis-Dihydroxylation Dihydroxylation via PIFA Enzymatic Dihydroxylation Ozonolysis: Oxidative Cleavage of Alkenes Reduction of Alkenes Addition to Conjugated Dienes
CARBONYL COMPOUNDS AND THEIR REACTIONS Structure-Reactivity Relationships Reactions of Carbonyl Compounds Carbonyl Addition Reactions Umpolung: Polarity Inversion of Aldehyde Carbonyl Group Reactions of Aldehydes and Ketones with Amines Reduction of Carbonyl Groups Reaction of Carbonyl Groups with Organometallic Compounds Reaction of Carbonyl Groups with Ylides Phosphonium Ylides and Wittig Reaction Reactivity of alpha-Carbon Atom Keto-Enol Tautomerism Proton-Deuterium Exchange alpha-Halogenation of Ketones and Aldehydes: Haloform Reaction Hell-Volhard-Zelinsky Reaction alpha-Alkylation of Carbonyl Compounds Enolates Derived from 1,3-Dicarbonyl Compounds Condensation Reactions of Carbonyl Compounds Typical Reactions of Acids and Esters Transesterification
AROMATIC COMPOUNDS Structure of Benzene Aromatic, Antiaromatic, and Nonaromatic Compounds Determination of the Molecular orbitals of Aromatic Compounds What are the criteria for aromaticity? How does one quantify aromaticity? Homoaromaticity Möbius Aromaticity Aromatic Ions Annulenes Aromaticity in Fused Systems Aromaticity in Heterocyclic Compounds Electrophilic Aromatic Substitution: Chemistry of Benzene Reactivity of Monosubstituted Benzene Derivatives Directing Effects of Substituents: Activating Groups Electrophilic Aromatic Substitution on Disubstituted Benzenes Functionalization of the Side Chain Substituents of Benzene Nucleophilic Aromatic Substitution Reactions Polycyclic Aromatic Compounds Benzenoid Aromatic Compounds
REACTIVE INTERMEDIATES Carbocations Carbanions Carbenes Nitrenes Radicals Singlet Oxygen
PERICYCLIC REACTIONS Woodward Hoffmann Rules Frontier Orbitals Electrocyclic Reactions Application of Woodward Hoffmann Rules Correlation Diagrams Cycloaddition Reactions Secondary Orbital Interaction Orbital Coefficients Sigmatropic Reactions Cope and Claisen Rearrangement
