Science of Synthesis: Stereoselective Synthesis Vol. 2 (eBook, ePUB)

Stereoselective Reactions of Carbonyl and Imino Groups

• Format: ePub

Produktbeschreibung

Carbonyl and imino groups are two of the most integral functional groups employed in organic synthesis. Specific topics discussed: reduction, alkylation, alkenylation, and arylation of these groups, as well as asymmetric aldol, Mannich, and Morita-Bayliss-Hillman reactions.

This volume is part of a 3-volume set: Science of Synthesis Stereoselective Synthesis Workbench Edition

Further information about Stereoselective Synthesis (including sample pages and the table of contents)

Produktdetails

• Verlag: Thieme
• Seitenzahl: 1052
• Erscheinungstermin: 14. Mai 2014
• Englisch
• ISBN-13: 9783131789518
• Artikelnr.: 40848169

Inhaltsangabe

<p>2.1 Reduction of Carbonyl Groups: Hydrogenation<br>2.2 Reduction of Carbonyl Groups: Transfer Hydrogenation, Hydrosilylation, Catalytic Hydroboration, and Reduction with Borohydrides, Aluminum Hydrides, or Boranes<br>2.3 Enzymatic Reduction of Carbonyl Groups<br>2.4 Oxidative Deracemization<br>2.5 Stereoselective Reduction of Imino Groups<br>2.6 Epoxidation and Aziridination of Carbonyl Groups and Imines<br>2.7 Alkylation of Carbonyl and Imino Groups<br>2.8 Allylation of Carbonyl and Imino Groups<br>2.9 Arylation and Alkenylation of Carbonyl and Imino Groups<br>2.10.1 Enantioselective Addition of Acetylide Nucleophiles to Carbonyl Compounds<br>2.10.2 Enantioselective Addition of Metal Alkynylides to Imino Groups<br>2.11 Hydrocyanation, Cyanosilylation, and Hydrophosphonylation of Carbonyl and Imino Groups<br>2.12 Asymmetric Mukaiyama Aldol Reaction<br>2.13 Direct Aldol Reactions<br>2.14 Enzymatic Direct Aldol Additions<br>2.15 Asymmetric Morita&#8211;Baylis&#8211;Hillman Reaction and Its Aza Analogue<br>2.16 Mannich Reaction<br>2.17 Asymmetric Benzoin and Stetter Reactions<br>2.18 Asymmetric Synthesis of Spiroketals, Bisspiroketals, and Spiroaminals</p>