Zefeng Ren

State-to-State Dynamical Research in the F+H2 Reaction System (eBook, PDF)

• Format: PDF

Produktbeschreibung

This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.

Produktdetails

• Verlag: Springer Berlin
• Erscheinungstermin: 9. November 2013
• Englisch
• ISBN-13: 9783642397561
• Artikelnr.: 43802600

Inhaltsangabe

Introduction.- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus.- Dynamical Resonances in F+H ₂ Reactions.- The Non-Adiabatic Effects in F( ²P)+D ₂→DF+D.

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Introduction.- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus.- Dynamical Resonances in F+H₂ Reactions.- The Non-Adiabatic Effects in F(²P)+D₂ DF+D.