Studies on Rhodium-Catalyzed (5+2) Cocyclization Rections (eBook, PDF)

• Format: PDF

Produktbeschreibung

The first part of this thesis dealt with the a new kind of precursors for transition metalcatalyzed cocyclization reactions containing a vinylbicyclopropyl unit, their synthesis and their behavior in cocyclization reactions. By introducing a second cyclopropane the catalyst might open this ring as well after insertion into the first cyclopropane ring. The ’basic’ formal [5+2] cycloaddition reaction would be extended to a [5+2+3] cocyclization reaction to form ten-membered rings. In addition to the importance as a new synthetic tool valuable insights into the mechanism of transition metal-catalyzed cocyclization reactions of vinylcyclopropanes are gained.

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Produktdetails

• Verlag: Cuvillier Verlag
• Seitenzahl: 140
• Erscheinungstermin: 20. September 2004
• Deutsch
• ISBN-13: 9783736912090
• Artikelnr.: 49029644