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Supramolecular Catalysis Provides a timely and detailed overview of the expanding field of supramolecular catalysis The subdiscpline of supramolecular catalysis has expanded in recent years, benefiting from the development of homogeneous catalysis and supramolecular chemistry. Supramolecular catalysis allows chemists to design custom-tailored metal and organic catalysts by devising non-covalent interactions between the various components of the reaction. Edited by two world-renowned researchers, Supramolecular Catalysis: New Directions and Developments summarizes the most…mehr
Provides a timely and detailed overview of the expanding field of supramolecular catalysis
The subdiscpline of supramolecular catalysis has expanded in recent years, benefiting from the development of homogeneous catalysis and supramolecular chemistry. Supramolecular catalysis allows chemists to design custom-tailored metal and organic catalysts by devising non-covalent interactions between the various components of the reaction.
Edited by two world-renowned researchers, Supramolecular Catalysis: New Directions and Developments summarizes the most significant developments in the dynamic, interdisciplinary field. Contributions from an international panel of more than forty experts address a broad range of topics covering both organic and metal catalysts, including emergent catalysis by self-replicating molecules, switchable catalysis using allosteric effects, supramolecular helical catalysts, and transition metal catalysis in confined spaces. This authoritative and up-to-date volume:
Covers ligand-ligand interactions, assembled multi-component catalysts, ligand-substrate interactions, and supramolecular organocatalysis and non-classical interactions
Presents recent work on supramolecular catalysis in water, supramolecular allosteric catalysis, and catalysis promoted by discrete cages, capsules, and other confined environments
Highlights current research trends and discusses the future of supramolecular catalysis
Includes full references and numerous figures, tables, and color illustrations
Supramolecular Catalysis: New Directions and Developments is essential reading for catalytic chemists, complex chemists, biochemists, polymer chemists, spectroscopists, and chemists working with organometallics.
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Autorenporträt
Piet W.N.M. van Leeuwen worked at the Koninklijke Shell Laboratorium Amsterdam (1968-1994) heading the homogeneous catalysis group, he is emeritus professor of homogeneous catalysis of the University of Amsterdam (1989-2007) and the Eindhoven University of Technology (2001-2006), the Netherlands, he was Group leader in ICIQ, Tarragona, Spain (2004-2015), and had an IDEX Chair at LPCNO in INSA-Toulouse, France (2015-2020). Matthieu Raynal is a researcher at Sorbonne Université, Paris, France. His current research focuses on the development of supramolecular helical catalysts, the design of functional chiral assemblies, and the structure-property relationship of supramolecular polymers.
Inhaltsangabe
Preface Introduction LIGAND-LIGAND INTERACTIONS Supramolecular Construction of Bidentate Ligands through Self-assembly by Hydrogen Bonding Self-Assembled bidentate ligands in transition metal catalysis; from fundamental invention to commercial application SELF-ASSEMBLED NANOSTRUCTURES AND MULTI-COMPONENT ASSEMBLIES Assembled Ionic Molecular Catalysts and Ligands Self-Amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics Interlocked Molecules in Asymmetric Catalysis Catalytic Supramolecular Gels Supramolecular helical catalysts Self-Assembled multi-component supramolecular catalysts for asymmetric reactions LIGAND-SUBSTRATE INTERACTIONS Harnessing non-covalent interactions for control of site-selectivity in transition metal-catalyzed C-H activation and cross-coupling Supramolecular interactions in distal C-H activation of (hetero)arenes Transition metal-catalyzed, site- and enantioselective oxygen and nitrogen transfer enabled by lactam hydrogen bonds Supramolecular substrate orientation as strategy to control selectivity in transition metal catalysis Phosphine Ligands with Acylguanidinium Groups as Substrate-directing Unit Chemical reactions controlled by remote Zn...N interactions between substrates and catalysts CATALYSIS PROMOTED BY DISCRETE CAGES, CAPSULES AND OTHER CONFINED ENVIRONMENTS Artificial Enzymes Created Through Molecular Imprinting of Cross-Linked Micelles Bioinspired catalysis using innately polarized Pd2L4 coordination cages Supramolecular catalysis with a cubic coordination cage: contributions from cavity and external-surface binding Transition metal catalysis in confined spaces Catalysis by Metal Organic Cages: A Computational Perspective N-heterocyclic carbene (NHC)-capped Cyclodextrins for cavity-controlled catalysis Supramolecular Catalysis by Metallohosts Based on Glycoluril Catalysis inside the hexameric resorcinare capsule: Towards addressing current challenges in synthetic organic chemistry Supramolecular Organocatalysis Within the Nanospace of Resorcinarene Capsule Resorcin[4]arene hexamer: from nanocontainer to nanocatalyst SUPRAMOLECULAR ORGANOCATALYSIS AND NON-CLASSICAL INTERACTIONS The Aryl-Pyrrolidine-tert-Leucine Motif as a New Privileged Chiral Scaffold: The Role of Non-Covalent Stabilizing Interactions Chiral Triazole Foldamers in Enantioselective Anion-Binding Catalysis Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades Exploration of halogen bonding for the catalysis of organic reactions Chalcogen-Bonding Catalysis Asymmetric Supramolecular Organocatalysis: the Fourth Pillar of Catalysis SUPRAMOLECULAR CATALYSIS IN WATER Metal Catalysis in Micellar Media Surfactant assemblies as nanoreactors for organic transformations Compartmentalized polymers for catalysis in aqueous media Phosphines modified by cyclodextrins for supramolecular catalysis in water Water-Soluble Yoctoliter Reaction Flasks Chemical catalyst-promoted regioselective histone acylation Protein-substrate supramolecular interactions for the shape selective hydroformylation of long chain a-olefins Supramolecular assembly of DNA- and protein-based artificial metalloenzymes SUPRAMOLECULAR ALLOSTERIC CATALYSTS AND REPLICATORS Switchable Catalysis Using Allosteric Effects Supramolecularly regulated enantioselective catalysts Emergent catalysis by self-replicating molecules
Preface Introduction LIGAND-LIGAND INTERACTIONS Supramolecular Construction of Bidentate Ligands through Self-assembly by Hydrogen Bonding Self-Assembled bidentate ligands in transition metal catalysis; from fundamental invention to commercial application SELF-ASSEMBLED NANOSTRUCTURES AND MULTI-COMPONENT ASSEMBLIES Assembled Ionic Molecular Catalysts and Ligands Self-Amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics Interlocked Molecules in Asymmetric Catalysis Catalytic Supramolecular Gels Supramolecular helical catalysts Self-Assembled multi-component supramolecular catalysts for asymmetric reactions LIGAND-SUBSTRATE INTERACTIONS Harnessing non-covalent interactions for control of site-selectivity in transition metal-catalyzed C-H activation and cross-coupling Supramolecular interactions in distal C-H activation of (hetero)arenes Transition metal-catalyzed, site- and enantioselective oxygen and nitrogen transfer enabled by lactam hydrogen bonds Supramolecular substrate orientation as strategy to control selectivity in transition metal catalysis Phosphine Ligands with Acylguanidinium Groups as Substrate-directing Unit Chemical reactions controlled by remote Zn...N interactions between substrates and catalysts CATALYSIS PROMOTED BY DISCRETE CAGES, CAPSULES AND OTHER CONFINED ENVIRONMENTS Artificial Enzymes Created Through Molecular Imprinting of Cross-Linked Micelles Bioinspired catalysis using innately polarized Pd2L4 coordination cages Supramolecular catalysis with a cubic coordination cage: contributions from cavity and external-surface binding Transition metal catalysis in confined spaces Catalysis by Metal Organic Cages: A Computational Perspective N-heterocyclic carbene (NHC)-capped Cyclodextrins for cavity-controlled catalysis Supramolecular Catalysis by Metallohosts Based on Glycoluril Catalysis inside the hexameric resorcinare capsule: Towards addressing current challenges in synthetic organic chemistry Supramolecular Organocatalysis Within the Nanospace of Resorcinarene Capsule Resorcin[4]arene hexamer: from nanocontainer to nanocatalyst SUPRAMOLECULAR ORGANOCATALYSIS AND NON-CLASSICAL INTERACTIONS The Aryl-Pyrrolidine-tert-Leucine Motif as a New Privileged Chiral Scaffold: The Role of Non-Covalent Stabilizing Interactions Chiral Triazole Foldamers in Enantioselective Anion-Binding Catalysis Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades Exploration of halogen bonding for the catalysis of organic reactions Chalcogen-Bonding Catalysis Asymmetric Supramolecular Organocatalysis: the Fourth Pillar of Catalysis SUPRAMOLECULAR CATALYSIS IN WATER Metal Catalysis in Micellar Media Surfactant assemblies as nanoreactors for organic transformations Compartmentalized polymers for catalysis in aqueous media Phosphines modified by cyclodextrins for supramolecular catalysis in water Water-Soluble Yoctoliter Reaction Flasks Chemical catalyst-promoted regioselective histone acylation Protein-substrate supramolecular interactions for the shape selective hydroformylation of long chain a-olefins Supramolecular assembly of DNA- and protein-based artificial metalloenzymes SUPRAMOLECULAR ALLOSTERIC CATALYSTS AND REPLICATORS Switchable Catalysis Using Allosteric Effects Supramolecularly regulated enantioselective catalysts Emergent catalysis by self-replicating molecules
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