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The Earth's natural resources are finite and easily compromised by contamination from industrial chemicals and byproducts from the degradation of consumer products. The growing field of green and sustainable chemistry seeks to address this through the development of products and processes that are environmentally benign while remaining economically viable. Inorganic chemistry plays a critical role in this endeavor in areas such as resource extraction and isolation, renewable energy, catalytic processes, waste minimization and avoidance, and renewable industrial feedstocks. Sustainable…mehr
The Earth's natural resources are finite and easily compromised by contamination from industrial chemicals and byproducts from the degradation of consumer products. The growing field of green and sustainable chemistry seeks to address this through the development of products and processes that are environmentally benign while remaining economically viable. Inorganic chemistry plays a critical role in this endeavor in areas such as resource extraction and isolation, renewable energy, catalytic processes, waste minimization and avoidance, and renewable industrial feedstocks. Sustainable Inorganic Chemistry presents a comprehensive overview of the many new developments taking place in this rapidly expanding field, in articles that discuss fundamental concepts alongside cutting-edge developments and applications. The volume includes educational reviews from leading scientists on a broad range of topics including: inorganic resources, sustainable synthetic methods, alternative reaction conditions, heterogeneous catalysis, photocatalysis, sustainable nanomaterials, renewable and clean fuels, water treatment and remediation, waste valorization and life cycle sustainability assessment.The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry.
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Autorenporträt
David Atwood joined the chemistry department at the University of Kentucky faculty as an Associate Professor in 1998. He has over 160 publications, 10 patents, and serves on numerous editorial boards, including the Encyclopedia of Inorganic and Bioinorganic Chemistry. He is the founding editor and editor-in-chief of the journal Main Group Chemistry. His research interests include detection and removal of heavy metal contaminants such as mercury, cadmium and lead, from the environment, the preparation of nanoparticulate metal oxides, prevention of aluminum alloy oxidation, and the synthesis of new Lewis acid compounds to effect new reactions, such as the breaking of phosphate esters bonds like those found in nerve gas agents and pesticides and the destruction of methyl-t-butyl ether (MTBE) a widespread water contaminant.
Inhaltsangabe
Contributors XI
Series Preface XVII
Volume Preface XIX
Recovery of Gold from Incinerated Sewage Sludge 1 Katsuyasu Sugawara
Rare Earth Recycling from NdFeB 9 Zhongsheng Hua
Life Cycle Sustainability Assessments 25 Anthony Halog and Yosef Manik
Trends in Food and Agricultural Waste Valorization 43 Anand Burange, James H. Clark and Rafael Luque
Toxicity Assessment of Molecular Rhenium(VII) Epoxidation Catalysts 53 Mirza Cokoja, Fritz E. Kühn, Marta Markiewicz and Stefan Stolte
Challenges in Green Analytical Chemistry 67 Salvador Garrigues, Sergio Armenta and Miguel de la Guardia
Mobile Apps for Green Chemistry 77 Alex M. Clark, Antony J. Williams and Sean Ekins
Renewable Plant-Based Raw Materials for Industry 87 Divya Bajpai Tripathy and Anuradha Mishra
Sustainable Synthesis of Fine Chemicals from Aliphatic Nitro Compounds 105 Roberto Ballini and Alessandro Palmieri
Sustainable Production of Glycerol 119 Rosaria Ciriminna and Mario Pagliaro
Production of Biopropylene Using Biomass-Derived Sources 129 Efterpi S. Vasiliadou and Angeliki A. Lemonidou
Methylethers from Alcohols and Dimethyl Carbonate 143 Fabio Aricò and Pietro Tundo
Sustainable Surfactants Based on Amino Acids 159 Lourdes Pérez, M. Rosa Infante and Aurora Pinazo
Sustainable Biosurfactants 175 Divya Bajpai Tripathy and Anuradha Mishra
Solvent Systems for Sustainable Chemistry 193 Francesca M. Kerton
Fluorous Hydrocarbon Oxidation 211 Gianluca Pozzi and Silvio Quici
Ionic Liquids: Industrial Applications 221 Geeta Durga and Anuradha Mishra
Ionic Liquids: Enzymatic Hydrolysis of Lignocellulose 235 Ronny M. Wahlström and Anna K. Suurnäkki
Ionic Liquids: Applications by Computational Design 249 Arunprakash T. Karunanithi, Reza Farahipour and Kamila Dilmurat
Ionic Liquids: Recycling 263 Evangelos Sklavounos, Jussi K.J. Helminen, Ilkka Kilpeläinen, Alistair W.T. King and Lasse Kyllönen
Ionic Liquids: Bacterial Degradation in Wastewater Treatment Plants 279 Elena Diaz, Victor Monsalvo, Jose Palomar and Angel F. Mohedano
Water Treatment by Electrocoagulation 293 Ville V. Kuokkanen
Sustainable Water Remediation 305 Anjali Gupta and Anuradha Mishra
Dimethylcarbonate for the Catalytic Upgrading of Amines and Bio-Based Derivatives 321 Maurizio Selva, Alvise Perosa, Sandro Guidi and Lisa Cattelan
Sustainable Syntheses with Microwave Irradiation 333 Tanvi Vats and Anuradha Mishra
Radical Reactions, beta-Cyclodextrin and Chitosan and Aqueous Media: From Fundamental Reactions to Potential Applications 351 Victoria T. Perchyonok
Catalytic Epoxidation of Organics from Vegetable Sources 373 Matteo Guidotti and Chiara Palumbo
Catalytic Cyclic Carbonate Synthesis with Sustainable Metals 385 James W. Comerford, Ian D.V. Ingram, Michael North and Xiao Wu
Solid Catalysts for Epoxidation with Dilute Hydrogen Peroxide 399 José M. Fraile
TiO2-Based Heterogeneous Catalysis for Photocatalytic Hydrogen Generation and Photodegradation 409 Jing Wang, Wei Li Ong, Minmin Gao, Liangliang Zhu and Ghim Wei Ho
Photocatalytic Production of Hydrogen with Earth-Abundant Metal Catalysts 439 Shunichi Fukuzumi and Yusuke Yamada
Multifunctional MOF-Based Photocatalysis 451 Dengrong Sun and Zhaohui Li
Recovery of Gold from Incinerated Sewage Sludge 1 Katsuyasu Sugawara
Rare Earth Recycling from NdFeB 9 Zhongsheng Hua
Life Cycle Sustainability Assessments 25 Anthony Halog and Yosef Manik
Trends in Food and Agricultural Waste Valorization 43 Anand Burange, James H. Clark and Rafael Luque
Toxicity Assessment of Molecular Rhenium(VII) Epoxidation Catalysts 53 Mirza Cokoja, Fritz E. Kühn, Marta Markiewicz and Stefan Stolte
Challenges in Green Analytical Chemistry 67 Salvador Garrigues, Sergio Armenta and Miguel de la Guardia
Mobile Apps for Green Chemistry 77 Alex M. Clark, Antony J. Williams and Sean Ekins
Renewable Plant-Based Raw Materials for Industry 87 Divya Bajpai Tripathy and Anuradha Mishra
Sustainable Synthesis of Fine Chemicals from Aliphatic Nitro Compounds 105 Roberto Ballini and Alessandro Palmieri
Sustainable Production of Glycerol 119 Rosaria Ciriminna and Mario Pagliaro
Production of Biopropylene Using Biomass-Derived Sources 129 Efterpi S. Vasiliadou and Angeliki A. Lemonidou
Methylethers from Alcohols and Dimethyl Carbonate 143 Fabio Aricò and Pietro Tundo
Sustainable Surfactants Based on Amino Acids 159 Lourdes Pérez, M. Rosa Infante and Aurora Pinazo
Sustainable Biosurfactants 175 Divya Bajpai Tripathy and Anuradha Mishra
Solvent Systems for Sustainable Chemistry 193 Francesca M. Kerton
Fluorous Hydrocarbon Oxidation 211 Gianluca Pozzi and Silvio Quici
Ionic Liquids: Industrial Applications 221 Geeta Durga and Anuradha Mishra
Ionic Liquids: Enzymatic Hydrolysis of Lignocellulose 235 Ronny M. Wahlström and Anna K. Suurnäkki
Ionic Liquids: Applications by Computational Design 249 Arunprakash T. Karunanithi, Reza Farahipour and Kamila Dilmurat
Ionic Liquids: Recycling 263 Evangelos Sklavounos, Jussi K.J. Helminen, Ilkka Kilpeläinen, Alistair W.T. King and Lasse Kyllönen
Ionic Liquids: Bacterial Degradation in Wastewater Treatment Plants 279 Elena Diaz, Victor Monsalvo, Jose Palomar and Angel F. Mohedano
Water Treatment by Electrocoagulation 293 Ville V. Kuokkanen
Sustainable Water Remediation 305 Anjali Gupta and Anuradha Mishra
Dimethylcarbonate for the Catalytic Upgrading of Amines and Bio-Based Derivatives 321 Maurizio Selva, Alvise Perosa, Sandro Guidi and Lisa Cattelan
Sustainable Syntheses with Microwave Irradiation 333 Tanvi Vats and Anuradha Mishra
Radical Reactions, beta-Cyclodextrin and Chitosan and Aqueous Media: From Fundamental Reactions to Potential Applications 351 Victoria T. Perchyonok
Catalytic Epoxidation of Organics from Vegetable Sources 373 Matteo Guidotti and Chiara Palumbo
Catalytic Cyclic Carbonate Synthesis with Sustainable Metals 385 James W. Comerford, Ian D.V. Ingram, Michael North and Xiao Wu
Solid Catalysts for Epoxidation with Dilute Hydrogen Peroxide 399 José M. Fraile
TiO2-Based Heterogeneous Catalysis for Photocatalytic Hydrogen Generation and Photodegradation 409 Jing Wang, Wei Li Ong, Minmin Gao, Liangliang Zhu and Ghim Wei Ho
Photocatalytic Production of Hydrogen with Earth-Abundant Metal Catalysts 439 Shunichi Fukuzumi and Yusuke Yamada
Multifunctional MOF-Based Photocatalysis 451 Dengrong Sun and Zhaohui Li